公开(公告)号：US11634552B2

公开(公告)日：2023-04-25

申请号：US16753064

申请日：2017-12-05

Applicant: Shandong University of Technology

Inventor： Gehua Bi ,  Yusui Bi

IPC: C08J9/08 ,  C07C213/08 ,  C08J9/14 ,  C07C215/06

Abstract: Disclosed is an organic amine salt foaming agent, that is, a composite polyurethane foaming agent, comprising: 1) hexafluorobutene; and 2) an alkanolamine salt mixture (MAA), the alkanolamine salt mixture (MAA) contains an organic amine salt compound having the following general formula (I): An−[Bm+]p (I); wherein An− is one or two or three selected from the following anions: (b) carbonate: CO32−; (c) formate: HCOO−; (d) bicarbonate: HO—COO−. A polyurethane foaming method using carbon dioxide and an organic amine in combination is also disclosed, in which carbon dioxide is added to a polyurethane composition for foaming. A method for preparing an alkanolamine carbonate salt with low water content from ammonium carbonate and an epoxide is additionally disclosed, in which a liquid alkanolamine salt mixture is used as a dispersion medium or as a solvent for reaction raw material.

公开(公告)号：US20190152899A1

公开(公告)日：2019-05-23

申请号：US16306031

申请日：2017-05-11

Applicant: Shandong University of Technology

Inventor： Gehua Bi ,  Yusui Bi

IPC: C07C271/12 ,  C07C215/08 ,  C07C215/12 ,  C07C69/96 ,  C08G18/08 ,  C08G18/42 ,  C08G18/48

Abstract: A foaming agent comprising organic amine salt compounds of the following general formula An− [Bm+]p (I) is disclosed, wherein An− is a CO2-donating anion with a valence of −n, wherein n=1, 2 or 3; each Bm+ comprises: ammonium ion and/or organic amine (B) cation, wherein m = 1  -10;   0

公开(公告)号：US20200291199A1

公开(公告)日：2020-09-17

申请号：US16753064

申请日：2017-12-05

Applicant: Shandong University of Technology

Inventor： Gehua Bi ,  Yusui Bi

IPC: C08J9/08 ,  C08J9/14 ,  C07C213/08

Abstract: Disclosed is an organic amine salt foaming agent, that is, a composite polyurethane foaming agent, comprising: 1) hexafluorobutene; and 2) an alkanolamine salt mixture (MAA), the alkanolamine salt mixture (MAA) contains an organic amine salt compound having the following general formula (I): An−[Bm+]p (I); wherein An− is one or two or three selected from the following anions: (b) carbonate: CO32−; (c) formate: HCOO−; (d) bicarbonate: HO—COO−. A polyurethane foaming method using carbon dioxide and an organic amine in combination is also disclosed, in which carbon dioxide is added to a polyurethane composition for foaming. A method for preparing an alkanolamine carbonate salt with low water content from ammonium carbonate and an epoxide is additionally disclosed, in which a liquid alkanolamine salt mixture is used as a dispersion medium or as a solvent for reaction raw material.

公开(公告)号：US11261153B2

公开(公告)日：2022-03-01

申请号：US16063889

申请日：2017-05-11

Applicant: SHANDONG UNIVERSITY OF TECHNOLOGY

Inventor： Gehua Bi ,  Yusui Bi

IPC: C07C213/04 ,  C08J9/08 ,  C07C271/02 ,  C08G18/16 ,  C08G18/48 ,  C08G18/20 ,  C07C211/14 ,  C08G18/24 ,  C07C269/06 ,  C08G18/40 ,  C08G18/42 ,  C08G18/76

Abstract: An organic amine salt compounds of general formula An−[Bm+]p (I) is disclosed, wherein An− is a CO2-donating anion with a valence of −n, wherein n=1, 2 or 3; each Bm+ comprises: ammonium ion, hydrazinium ion and/or organic amine B cation; wherein m = 1 ⁢ - ⁢ 10 ; 0