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公开(公告)号：US5002859A
公开(公告)日：1991-03-26
申请号：US512059
申请日：1990-04-19
CPC分类号： G03C7/421 , G03C7/3022
摘要： A method for forming photographic color images is disecond closed, in which a silver halide color photographic light-sensitive material is rapidly processed with low replenishment of processing solutions. The images improved in lowered yellow stain can be obtained. The processing comprises steps of color developing, bleaching immediately after the developing step, and treating with a bath having a fixing capability following the bleaching step. The steps of bleaching and treating with a solution having a fixing capability are carried out for a time of not more than 3 minutes 45 seconds at a temperature of from 20.degree. to 45.degree. C. The light-sensitive material comprises silver halide emulsion layers each containing silver bromide and/or silver boromoiodide grains and satsifies at least one of the following requirements (1) and (2); (1) a blue light-sensitive emulsion layer included in the silver halide emulsion layers has a silver density d of not less than 4.0.times.10.sup.-1 g/cm.sup.3. (2) a green light-sensitive emulsion layer included in the silver halide emulsion layers has a silver density d of not less than 6.0.times.10.sup.-1 g/cm.sup.3.
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公开(公告)号：US5028517A
公开(公告)日：1991-07-02
申请号：US353686
申请日：1989-05-18
CPC分类号： G03C7/3022 , G03C7/413
摘要： A method for processing a silver halide color photographic light-sensitive material is disclosed. Fogging caused by the color developer contaminated by heavy metal ions is surpressed by the processing method. The processing method is excellent in the point that stable photographic propertied can be obtained for long while of running. The processing method comprises a step for developing with a color developer an imagewise exposed light-sensitive material which comprises a support and a photographic layer being provided on the support and including at least one silver halide emulsion layer, wherein the photographic layer has a swelling ratio within the range of from 1.5 to 3.5 and the silver halide emulsion layer comprises a silver halide emulsion having a silver chloride content of not less than 90 mole %, and the developing step is performed for a time of not less than 90 seconds with a color developer containing a compound represented by the following Formula (1): ##STR1## wherein R.sub.1 and R.sub.2 are each a hydrogen atom or an alkyl group provided that R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, and R.sub.1 and R.sub.2 may be combined to form a ring.
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3.发明授权Method for processing light-sensitive silver halide color photographic material which contains a high speed reactive yellow coupler by processing, after fixings, with a sulfite-containing solution and without substantial washing 失效用于处理感光卤化银彩色照相材料的方法，其含有高速反应性黄色成色剂，在固定之后，用含亚硫酸盐的溶液进行加工并且没有实质洗涤
公开(公告)号：US4687731A
公开(公告)日：1987-08-18
申请号：US794642
申请日：1985-11-04
申请人： Masao Ishikawa , Shigeharu Koboshi , Satoru Kuse
发明人： Masao Ishikawa , Shigeharu Koboshi , Satoru Kuse
CPC分类号： G03C7/3046
摘要： A method of processing a light-sensitive silver halide color photographic material comprising color developing an imagewise exposed light-sensitive silver halide color photographic material comprising a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer on a base, said blue-sensitive silver halide emulsion layer containing a high speed reactive yellow coupler having a relative coupling reaction rate of not less than 0.3, followed by processing with a processing solution having a fixing ability and then processing with a stabilizing solution without a substantial washing step, said stabilizing solution containing a sulfite in an amount of at least 1.times.10.sup.-3 mole per 1 liter of said stabilizing solution. The processed photographic material has superior stability of the dye image.
摘要翻译： 一种处理感光卤化银彩色照相材料的方法，包括彩色显影成像曝光的感光卤化银彩色照相材料，其包含感蓝卤化银乳剂层，感绿卤化银乳剂层和红敏感 所述感蓝卤化银乳剂层含有相对偶联反应速率不小于0.3的高速反应性黄色偶合剂，然后用具有定影能力的处理溶液进行处理，然后用 没有实质洗涤步骤的稳定溶液，所述稳定溶液含有至少1×10-3摩尔/ 1升所述稳定溶液的亚硫酸盐。 经处理的照相材料具有优异的染料图像稳定性。
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4.发明授权
公开(公告)号：US4983503A
公开(公告)日：1991-01-08
申请号：US488473
申请日：1990-02-26
CPC分类号： G03C7/42 , G03C7/3225
摘要： There are disclosed a method for processing a light-sensitive silver halide color photographic material by subjecting a light-sensitive silver halide color photographic material after color developing to bleach-fixing processing, characterized in that the light-sensitive silver halide color photographic material contains at least one cyan coupler represented by the formula (A), (B) or (C) as specified in the specification, or contains at least one magenta coupler represented by the formula (M-1), the bleach-fixing processing step is a step which is a counter-current system uses two or more tanks of continuous bleach-fixing tanks, and the silver concentration in the bleach-fixing solution in a final tank of the bleach-fixing tanks is maintained at 80% or lower of the silver concentration in a bleach-fixing solution in a first tank, and a method for processing a light-sensitive silver halide color photographic material by subjecting a light-sensitive silver halide color photographic material after color developing to bleach-fixing processing and then to stabilizing processing substituted for water washing, characterized in that the light-sensitive silver halide color photographic material has at least one light-sensitive emulsion layer containing a silver halide emulsion containing 0.5 mole % or more of silver iodide, the bleach-fixing processing step is a step which is a counter-current system by use of an organic acid metal complex as the oxidizing agent and uses two or more tanks of continuous bleach-fixing tanks, and the silver concentration in a final tank of the bleach-fixing tanks is maintained at 80% or lower of the silver concentration in the bleach-fixing solution in a first tank.
摘要翻译： 公开了一种通过在彩色显影之后对感光卤化银彩色照相材料进行漂白定影处理来处理感光卤化银彩色照相材料的方法，其特征在于，感光卤化银彩色照相材料含有 至少一种由说明书中规定的式（A），（B）或（C）表示的青色成色剂，或含有至少一种由式（M-1）表示的品红成色剂，漂白剂固定处理步骤为 使用两个或更多个连续漂白固定槽的逆流系统的步骤，并且漂白定影罐的最终罐中漂白剂固定液中的银浓度保持在银浓度的80％以下 在第一罐中的漂白固定溶液中，以及通过使感光卤化银彩色照相纸经受感光卤化银彩色照相材料的处理方法 在漂白定影处理彩色显影之后，然后进行代替水洗的稳定处理，其特征在于感光卤化银彩色照相材料具有至少一个含有0.5摩尔％或更少的卤化银乳剂的感光乳剂层， 更多的碘化银，漂白定影处理步骤是通过使用有机酸金属络合物作为氧化剂的逆流系统并使用两个或更多个连续漂白固定槽， 漂白剂固定槽的最终罐保持在第一罐中漂白剂固定液中银浓度的80％以下。
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5.发明授权Method for processing a light-sensitive silver halide color photographic material using at least one silver halide emulsion layer and at least one of a cyan coupler and magneta coupler 失效使用至少一个卤化银乳剂层和青色成色剂和磁性耦合器中的至少一种来处理感光卤化银彩色照相材料的方法
公开(公告)号：US4837139A
公开(公告)日：1989-06-06
申请号：US77336
申请日：1987-07-24
IPC分类号： G03C7/407
CPC分类号： G03C7/407
摘要： There are disclosed a processing solution of a light-sensitive silver halide color photographic material, which comprises containing a compound represented by the formula (I) shown below, and a processing method of the same, which comprises subjecting a light-sensitive silver halide color photographic material having at least one layer of silver halide emulsion layer on a support to imagewise exposure and then applying processing including at least a color developing processing, characterized in that the color developing solution to be used in the color developing processing contains a compound represented by the formula (I) shown below: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.2 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or an alkyl group having 1 to 5 carbon atoms substituted with an alkoxy group, and R.sub.1 and R.sub.2 may be bonded with each other to form a ring containing an oxygen atom.
摘要翻译： 公开了一种感光卤化银彩色照相材料的处理溶液，其包含含有下述式（I）表示的化合物及其加工方法，其包括使感光卤化银颜色 在成像曝光的支持体上具有至少一层卤化银乳剂层的照相材料，然后施加包括至少彩色显影处理的处理，其特征在于，用于彩色显影处理中的显色溶液含有由 下式（I）：其中R 1表示碳原子数1〜5的烷基，被烷氧基取代，R 2表示氢原子，碳原子数为1〜5的烷基或 被烷氧基取代的具有1至5个碳原子的烷基，并且R 1和R 2可以彼此键合以形成含有氧原子的环。
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6.发明授权Method for color-developing a silver halide photographic light-sensitive material with a color developer containing an n-hydroxyalkyl-p-phenylenediamine derivative 失效用含有正羟基烷基 - 对苯二胺衍生物的彩色显影剂对卤化银照相感光材料进行彩色显影的方法
公开(公告)号：US4738917A
公开(公告)日：1988-04-19
申请号：US863604
申请日：1986-05-15
CPC分类号： G03C7/4136
摘要： A method for processing a silver halide photographic material by processing a silver halide color photographic light-sensitive material containing at least a silver halide emulsion layer comprising a silver halide grain essentially consisting of silver chlorobromide and a binder having a swelling rate of T 1/2 of 2 sec. to 30 sec. The color developer contains a n-hydroxyalkyl-p-phenylenediamine derivative at a temperature not less than 30.degree. C. for a time not more than 150 sec. The time and temperature are effective to process the silver halide color photographic light-sensitive material without decreasing the stability of the resulting dye image.
摘要翻译： 一种通过加工卤化银彩色照相感光材料来处理卤化银照相材料的方法，所述卤化银彩色照相感光材料至少含有卤化银乳剂层，该卤化银乳剂层包含基本上由氯溴化银组成的卤化银颗粒和溶胀率为T 1/2的粘合剂 2秒 至30秒 彩色显影剂在不低于30℃的温度下持续不超过150秒的n-羟基烷基 - 对苯二胺衍生物。 时间和温度对卤化银彩色照相感光材料的处理是有效的，而不降低所得染料图像的稳定性。
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7.发明授权Method for processing silver halide color photographic light-sensitive materials 失效用于处理银色彩色摄影感光材料的方法
公开(公告)号：US5063140A
公开(公告)日：1991-11-05
申请号：US508786
申请日：1990-04-12
CPC分类号： G03C7/3022 , G03C7/421
摘要： A method for forming color photographic images is disclosed. The method comprises steps ofimagewise exposing to light a silver halide color photographic light-sensitive materialdeveloping the light-sensitive material with a color developer,bleaching, immediately after the step of developing, the light-sensitive material with a bleacing solution, andtreating the bleached light-sensitive material with a solution having fixing capablility, whereinthe light-sensitive material comprises a support and hydrophilic colloid layers including a silver halide emulsion layer provided on a side of the support, and a total dry thickness of the hydrophilic colloid layers is not more than 17 .mu.m, andthe bleaching solution contains a ferric complex salt of a compound represented by the following formula in an amount of within the range of from 0.002 mole to 9.4 mole per liter of the bleaching solution; ##STR1## wherein A.sub.1, through A.sub.4 are each a --CH.sub.2 OH group, a --COOM, or a --PO.sub.3 M.sup.1 M.sup.2. Color photographic images can be obtained, which is excellent in image sharpness and improved in bleach-fog desilvering property and preservcapability, with diminished amount of developer replenishing.
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8.发明授权
公开(公告)号：US5206119A
公开(公告)日：1993-04-27
申请号：US908775
申请日：1992-07-01
CPC分类号： G03C7/3924 , G03C7/3046 , Y10S430/164
摘要： Disclosed is a method of processing a light-sensitive silver halide color photographic material subjected to imagewise exposure, substantially through a color developing step, a bleach-fixing step and a stabilizing step in this order, wherein at least one layer of the light-sensitive silver halide color photographic material comprises a silver halide containing not less than 80 mol % of silver chloride, the washing-substitutive stabilizing step is carried out in a processing time of not more than 45 seconds, and a washing-substitutive stabilizing solution used in the washing-substitutive stabilizing step has a salt concentration of at least 1,000 ppm. Disclosed are also a washing-substitutive stabilizing solution and a kit of a stabilizer used for the method of this invention. According to this invention, processing of a light-sensitive material that have better prevented the bluing at exposed areas of color photographic papers and also have suppressed the generation of mildew or bacteria on a processed light-sensitive material, moreover that have been improved in paper jam and the like due to incompleteness of drying and also can conduct rapid processing is enabled.
摘要翻译： 公开了基本上通过彩色显影步骤，漂白定影步骤和稳定步骤依次处理经受成像曝光的感光卤化银彩色照相材料的方法，其中至少一层光敏 卤化银彩色照相材料包含含有不小于80mol％氯化银的卤化银，洗涤代用稳定步骤在不超过45秒的处理时间内进行，洗涤代用稳定溶液用于 洗涤代用稳定步骤的盐浓度至少为1000ppm。 本发明还公开了洗涤代用稳定溶液和用于本发明方法的稳定剂试剂盒。 根据本发明，对感光材料进行处理，其更好地防止了彩色相纸的曝光区域的蓝色，并且还抑制了加工感光材料上的霉菌或细菌的产生，而且已经改进了纸张 由于干燥不完整等原因，也可以进行快速加工。
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公开(公告)号：US4797351A
公开(公告)日：1989-01-10
申请号：US856779
申请日：1986-04-25
CPC分类号： G03C7/44
摘要： A replenishing process for use in the development of an image-wise exposed silver halide color photographic light-sensitive material in which a color developer replenisher containing 0-3.0.times.10.sup.-3 mole of bromide is added to a color developer in a volume of between 0.5 and 9 ml per 100 cm.sup.2 of silver halide color photographic light-sensitive material.
摘要翻译： 用于开发成像曝光的卤化银彩色照相感光材料的补充方法，其中将含有0-3.0×10 -3摩尔溴的显色剂补充剂以0.5倍体积的量加入到显色剂中 和9ml / 100cm 2的卤化银彩色照相感光材料。
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公开(公告)号：US4623613A
公开(公告)日：1986-11-18
申请号：US810413
申请日：1985-12-18
申请人： Masao Ishikawa , Shigeharu Koboshi , Satoru Kuse
发明人： Masao Ishikawa , Shigeharu Koboshi , Satoru Kuse
CPC分类号： G03C7/3046
摘要： In a method of processing a light-sensitive silver halide photographic material by processing the light-sensitive silver halide photographic material with a processing solution having fixing ability and subsequently processing it with a water washing-substitutive stabilizing solution substantially without carrying out water washing, the improvement wherein the concentration of a sulfite in said water washing-substitutive stabilizing solution is controlled to be 1.0.times.10.sup.-5 mole/liter or more when the concentration of silver compounds in said water washing-substitutive stabilizing solution is from 1/2 to 1/1000-fold of the concentration of silver compounds in the preceding bath. According to the method of this invention, generation of sulfiding and mold or bacteria can be prevented, whereby dye images without drop out portion can be obtained.
摘要翻译： 在通过用感光卤化银照相材料加工具有定影能力的处理溶液并随后用基本上不进行水洗的水洗替代稳定溶液处理感光卤化银照相材料的方法中， 改进，其中当所述水洗替代稳定溶液中的银化合物的浓度为1/2至1 /℃时，将所述水洗替代稳定溶液中的亚硫酸盐的浓度控制在1.0×10-5摩尔/升以上， 上一个浴中银化合物浓度的1000倍。 根据本发明的方法，可以防止产生硫化和霉菌或细菌，从而可以获得没有脱落部分的染料图像。
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