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公开(公告)号:US20220254569A1
公开(公告)日:2022-08-11
申请号:US17589206
申请日:2022-01-31
Applicant: TDK CORPORATION
Inventor: Takuma ARIIZUMI , Taku MURAKAMI , Nobuto MORIGASAKI , Toshihiko KANEKO , Yasuhiro ITO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: A dielectric composition includes a main phase and segregation phases each including RE (at least one rare earth element). The main phase includes a main component having a perovskite crystal structure of ABO3 (A is one or more selected from Ba, Sr, and Ca, and B is one or more selected from Ti, Zr, and Hf). The segregation phases are classified into first segregation phases whose atomic ratio of Si to RE is 0 or more and 0.20 or less and second segregation phases whose atomic ratio of Si to the RE is more than 0.20. 0≤S1/S2≤0.10 is satisfied on a cross section of the dielectric composition, where S1 is an area ratio of the first segregation phases, and S2 is an area ratio of the second segregation phases. An atomic ratio of Si to RE in the second segregation phases is 0.80 or less on average.
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公开(公告)号:US20210304966A1
公开(公告)日:2021-09-30
申请号:US17195366
申请日:2021-03-08
Applicant: TDK CORPORATION
Inventor: Taku MURAKAMI , Nobuto MORIGASAKI , Dan SAKURAI , Takuma ARIIZUMI , Toshihiko KANEKO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: A dielectric ceramic composition includes a barium titanate, an oxide of an R element, an oxide of an M element, and an oxide containing Si. The R element is one or more elements selected from Eu, Gd, Tb, Dy, Y, Ho, and Yb. The M element is one or more elements selected from Mg, Ca, Mn, V, and Cr. A ratio of an amount of the oxide of the R element in terms of R2O3 to an amount of the oxide containing Si in terms of SiO2 is 0.8:1 to 2.2:1. A ratio of an amount of the oxide of the M element in terms of MO to the amount of the oxide containing Si in terms of SiO2 is 0.2:1 to 1.8:1.50% or more of the number of dielectric particles constituting the dielectric ceramic composition is core-shell dielectric particles having a core-shell structure.
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公开(公告)号:US20140378295A1
公开(公告)日:2014-12-25
申请号:US14310212
申请日:2014-06-20
Applicant: TDK Corporation
Inventor: Toshihiko KANEKO , Saori TAKEDA , Yuki YAMASHITA , Junichi YAMAZAKI
IPC: C04B35/057 , C04B35/465 , C04B35/49
CPC classification number: C04B35/49 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/6562 , H01L28/40
Abstract: The present invention aims to provide an amorphous dielectric film and an electronic component in which the relative permittivity and the temperature coefficient of electrostatic capacitance can be maintained and the withstand voltage can be increased even if the dielectric film is further thinned. The amorphous dielectric film of the present invention is characterized in that it is a dielectric film composed of an amorphous composition with A-B—O as the main component, wherein A contains at least two elements selected from the group consisting of Ba, Ca and Sr, and B contains Zr. When the main component of the dielectric film is represented by (BaxCaySrz)α—B—O, x, y and z meet the conditions of 0≦x≦1, 0≦y≦1, 0≦z≦1, respectively, x+y+z=1 and at least any two of x, y and z are 0.1 or more. When A/B is represented by α, 0.5≦α≦1.5.
Abstract translation: 本发明的目的在于提供一种非晶介质膜和电子元件,其中可以保持相对介电常数和静电电容的温度系数,并且即使电介质膜进一步薄化也可以提高耐电压。 本发明的非晶质介电体膜的特征在于,由作为主成分的无定形组合物构成的电介质膜,其中,A含有选自Ba,Ca,Sr中的至少2种以上的元素, B含有Zr。 当电介质膜的主要成分由(BaxCaySrz)α-B-O表示时,x,y和z分别满足0≦̸ x≦̸ 1,0,nlE; y≦̸ 1,0和nlE; z≦̸ 1的条件x + y + z = 1,x,y和z中的至少任意两个为0.1以上。 当A / B由α表示时,0.5≦̸α≦̸ 1.5。
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公开(公告)号:US20220254570A1
公开(公告)日:2022-08-11
申请号:US17590541
申请日:2022-02-01
Applicant: TDK CORPORATION
Inventor: Takuma ARIIZUMI , Taku MURAKAMI , Nobuto MORIGASAKI , Toshihiko KANEKO , Yasuhiro ITO
IPC: H01G4/12 , H01G4/30 , C04B35/468
Abstract: A dielectric composition includes a main phase, first segregation phases, and second segregation phases. The main phase includes a main component having a perovskite crystal structure of ABO3 (A is one or more selected from Ba, Sr, and Ca, and B is one or more selected from Ti, Zr, and Hf). The first segregation phases include RE (one or more selected from rare earth elements), A, Si, Ti, and O. The second segregation phases include RE, A, Ti, and O and do not substantially include Si. 0.10
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公开(公告)号:US20220194859A1
公开(公告)日:2022-06-23
申请号:US17551633
申请日:2021-12-15
Applicant: TDK CORPORATION
Inventor: Dan SAKURAI , Yasuhiro ITO , Nobuto MORIGASAKI , Toshihiko KANEKO , Toshihiro IGUCHI
IPC: C04B35/47
Abstract: A dielectric ceramic composition contains dielectric particles containing a main component represented by a composition formula (Ba1-x-ySrxCay)m(Ti1-zZrz)O3 and grain boundaries present between the dielectric particles. The values of m, x, y, and z in the composition formula are all molar ratios. In the composition formula, 0.9≤m≤1.4, 0≤x
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公开(公告)号:US20190237264A1
公开(公告)日:2019-08-01
申请号:US16250911
申请日:2019-01-17
Applicant: TDK CORPORATION
Inventor: Dan SAKURAI , Toshihiko KANEKO , Nobuto MORIGASAKI , Toshinari TAKAHASHI , Yasuhiro ITO
CPC classification number: H01G4/30 , H01G4/008 , H01G4/1245
Abstract: The object of the present invention is to provide the multilayer ceramic capacitor having no deterioration of dielectric properties even in case an inhibitor of an internal electrode layer is pushed out to a dielectric layer when sintering. The multilayer ceramic capacitor 1 including a capacitor element body 10 comprising a dielectric layer 2 and an internal electrode layer 3 stacked in an alternating manner, wherein when Za represents Zr concentration of an dielectric particle in a center part 6 of the dielectric layer 2 and Zb represents Zr concentration of a dielectric particle near the internal electrode layer, 0
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7.
公开(公告)号:US20160268045A1
公开(公告)日:2016-09-15
申请号:US15064431
申请日:2016-03-08
Applicant: TDK CORPORATION
Inventor: Toshihiko KANEKO , Tatsuya FUJINO , Nobuto MORIGASAKI , Yasuhiro ITO
IPC: H01G4/12 , C04B35/468
CPC classification number: H01G4/1227 , C04B35/4682 , C04B35/488 , C04B35/49 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3225 , C04B2235/3236 , C04B2235/3239 , C04B2235/3249 , C04B2235/3262 , C04B2235/3418 , C04B2235/5454 , C04B2235/6025 , C04B2235/6562 , C04B2235/6565 , C04B2235/6567 , C04B2235/6584 , C04B2235/6588 , C04B2235/768 , C04B2235/79 , C04B2235/80 , C04B2237/346 , C04B2237/68 , H01G4/30
Abstract: A dielectric ceramic composition including a main component having a perovskite crystal structure expressed by general formula ABO3, a first sub-component of an oxide of a rare earth element, and a second sub-component of an oxide of Si, and at least dielectric particles having a core-shell structure and segregated particles, in which a concentration of the rare earth element in the segregated particles is two or more times an average concentration of the rare earth element in a shell portion of the dielectric particles having the core-shell structure, and an area of the region occupied by the segregated particles is 5.0% or less and an average of cross-sectional areas of the respective segregated particles is 0.075 μm2 or less in a cross-section obtained by cutting the dielectric ceramic composition.
Abstract translation: 一种电介质陶瓷组合物,其包含具有由通式ABO 3表示的钙钛矿晶体结构的主要成分,稀土元素的氧化物的第一亚成分和Si的氧化物的第二子成分,至少介电粒子 具有核 - 壳结构和偏析粒子,其中分离粒子中的稀土元素的浓度是具有核 - 壳结构的电介质粒子的壳部中的稀土元素的平均浓度的两倍或更多倍 ,并且由偏析粒子占据的区域的面积为5.0%以下,在通过切断电介质陶瓷组合物而得到的截面中,各偏析粒子的截面积的平均值为0.075μm2以下。
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公开(公告)号:US20220384107A1
公开(公告)日:2022-12-01
申请号:US17739482
申请日:2022-05-09
Applicant: TDK CORPORATION
Inventor: Takuya IMAEDA , Takashi MORITA , Masashi HATANAKA , Toshihiko KANEKO
Abstract: An element body of a multilayer capacitor has a plurality of first electrodes and a plurality of second electrodes. At least one of the first electrodes is curved such that a first main body portion is located on an outer side of a first extending portion in a first direction, and at least one of the second electrodes is curved such that a second main body portion is located on an outer side of a second extending portion in the first direction. The following expressions (1) to (6) are satisfied for lengths L0 to L4 in a second direction and distances TL1 to TL3 between main surfaces. 0.03≤L1/L0≤0.1 (1) 0.1≤L2/L0≤0.25 (2) 0.75≤L3/L0≤0.9 (3) 0.9≤L4/L0≤0.97 (4) 0≤(TL1−TL2)/TL1≤0.02 (5) 0≤(TL1−TL3)/TL1≤0.02 (6)
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公开(公告)号:US20220254567A1
公开(公告)日:2022-08-11
申请号:US17588511
申请日:2022-01-31
Applicant: TDK CORPORATION
Inventor: Taku MURAKAMI , Nobuto MORIGASAKI , Takuma ARIIZUMI , Toshihiko KANEKO , Yasuhiro ITO
Abstract: A dielectric composition includes a main-phase particle and segregation particles. The main-phase particle includes a main component having a perovskite crystal structure represented by a general formula of ABO3. The dielectric composition includes RA, RB, M, and Si. Each of A, B, RA, RB, and M is one or more elements selected from a specific element group. Each of an RA content CRA to the main component, an RB content CRB to the main component, an M content to the main component, and a Si content to the main component is within a predetermined range. 0.50
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10.
公开(公告)号:US20200035414A1
公开(公告)日:2020-01-30
申请号:US16589884
申请日:2019-10-01
Applicant: TDK Corporation
Inventor: Shogo MUROSAWA , Toshihiko KANEKO
Abstract: A multilayer ceramic electronic device comprising: a ceramic element body, in which a plurality of dielectric layers and a plurality of internal electrode layers are alternately stacked, and at least a pair of external electrodes which are connected to the internal electrode layers on surfaces of the ceramic element body; a thickness of the dielectric layers is 0.4 μm or less, a width (W0) of the ceramic element body along a width-direction is 0.59 mm or less, a gap (Wgap) between an outer face of the ceramic element body and an end of the internal electrode layers along width-direction of the ceramic element body is 0.010 to 0.025 mm, and a ratio (Wgap/W0) of the gap with respect to the width is 0.025 or more.
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