公开(公告)号：US07462407B2

公开(公告)日：2008-12-09

申请号：US10737875

申请日：2003-12-18

申请人： Takao Maeda ,  Hajime Nakano ,  Satoshi Shima

发明人： Takao Maeda ,  Hajime Nakano ,  Satoshi Shima

IPC分类号： B32B9/00

CPC分类号： C23C30/00 ,  C23C4/04 ,  C23C24/04 ,  C23C30/005 ,  Y10T428/31678

摘要： A Group IIIA element fluoride-containing coating comprising a Group IIIA element fluoride phase which contains at least 50% of a crystalline phase of the orthorhombic system belonging to space group Pnma is formed on a member for imparting corrosion resistance so that the member may be used in a corrosive halogen species-containing atmosphere. When the state of a crystalline phase is properly controlled, the coating experiences only a little color change by corrosion. A Group IIIA element fluoride-containing coating having a micro-Vickers hardness Hv of at least 100 is minimized in weight loss by-corrosion.

摘要翻译： 包含含有属于空间群Pnma的正交系的至少50％的结晶相的IIIA族元素氟化物相的IIIA族元素氟化物涂层形成在用于赋予耐腐蚀性的构件上，使得可以使用该构件 在含卤素物质的腐蚀性气体中。 当结晶相的状态被适当地控制时，涂层仅经受腐蚀的一点颜色变化。 具有至少100的微维氏硬度Hv的IIIA族元素含氟化物涂层在减重腐蚀中被最小化。

公开(公告)号：US06300010B1

公开(公告)日：2001-10-09

申请号：US09626587

申请日：2000-07-27

申请人： Hajime Nakano ,  Noriaki Hamaya ,  Satoshi Shima

发明人： Hajime Nakano ,  Noriaki Hamaya ,  Satoshi Shima

IPC分类号： H01M438

CPC分类号： H01M4/0416 ,  H01M4/04 ,  H01M4/0404 ,  H01M4/043 ,  H01M4/0433 ,  H01M4/383 ,  H01M4/624 ,  H01M2004/021 ,  Y10S420/90

摘要： An object of the present invention is to provide a hydrogen absorbing alloy powder for use in the negative electrodes of alkaline rechargeable batteries which has excellent initial characteristics and a high rate discharge property, exhibits satisfactory life characteristics, and is hence very beneficial from a practical point of view, as well as a process for producing the same. Specifically, the present invention provides a hydrogen absorbing alloy powder for use in the negative electrodes of alkaline rechargeable batteries which has an average particle diameter of 5 to 20 &mgr;m and an oxygen content of 2,000 to 6,000 ppm and, moreover, wherein the oxygen on the surfaces of hydrogen absorbing alloy particles is present in the form of hydroxyl groups.

摘要翻译： 本发明的目的是提供一种用于碱性可再充电电池的负极中的吸氢合金粉末，其具有优异的初始特性和高放电特性，表现出令人满意的寿命特性，因此从实用点非常有益 的观点，以及其生产过程。 具体地说，本发明提供一种用于碱性可再充电电池的负极中的吸氢合金粉末，其中平均粒径为5〜20μm，氧含量为2,000〜6,000ppm，此外， 吸氢合金颗粒的表面以羟基的形式存在。

公开(公告)号：US06387148B1

公开(公告)日：2002-05-14

申请号：US09626956

申请日：2000-07-27

申请人： Hajime Nakano ,  Noriaki Hamaya ,  Satoshi Shima

发明人： Hajime Nakano ,  Noriaki Hamaya ,  Satoshi Shima

IPC分类号： C22C1900

CPC分类号： H01M4/622 ,  H01M4/242 ,  H01M4/30 ,  H01M10/345

摘要： The present invention provides a hydrogen absorbing alloy compact for use as the negative electrode of an alkaline rechargeable battery which is made without the aid of a current-collecting support, contains a binder dispersed in the interstices formed by mutual contact of hydrogen absorbing alloy particles and on the alloy surfaces, and has a bulk density of 3.5 to 6.0 g/cm3. The present invention also provides a compact electrode which is made by forming a porous hydrogen absorbing alloy compact containing neither current-collecting support nor binder, impregnating the compact with an aqueous solution (or solvent solution) of a binder, and then drying the compact to remove the water (or solvent) alone, so that the strength of the compact is increased and good electrical contact between alloy particles is established.

摘要翻译： 本发明提供一种用作碱性可再充电电池的负极的氢吸收合金成型体，其不经集电支撑而制成，其包含分散在由吸氢合金粒子相互接触形成的间隙中的粘合剂 在合金表面上，堆积密度为3.5〜6.0g / cm 3。 本发明还提供一种紧凑型电极，其通过形成不含集电支撑体或粘合剂的多孔吸氢合金成形体，用粘合剂的水溶液（或溶剂溶液）浸渍压块，然后将其干燥至 单独去除水（或溶剂），使得压块的强度增加，并且建立合金颗粒之间良好的电接触。

公开(公告)号：US20050168908A1

公开(公告)日：2005-08-04

申请号：US11052229

申请日：2005-02-08

申请人： Takao Maeda ,  Satoshi Shima ,  Yuko Shima

发明人： Takao Maeda ,  Satoshi Shima ,  Yuko Shima

IPC分类号： C23C4/10 ,  B32B9/00 ,  H01B3/12 ,  H02H1/00

CPC分类号： H02H1/00 ,  C23C4/11 ,  C23C24/04

摘要： An electrostatic chuck is provided in which a lower oxide coating, an electrode, and an upper oxide coating are formed on a substrate. The lower oxide coating is formed by spraying an oxide of Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu and has a dielectric strength of 15-50 kV/mm.

摘要翻译： 提供一种静电卡盘，其中在基板上形成较低的氧化物涂层，电极和上部氧化物涂层。 通过喷射Gd，Tb，Dy，Ho，Er，Tm，Yb或Lu的氧化物形成低氧化物涂层，其介电强度为15-50kV / mm。

公开(公告)号：US06733724B1

公开(公告)日：2004-05-11

申请号：US09631491

申请日：2000-08-03

申请人： Takao Maeda ,  Satoshi Shima ,  Naofumi Shinya

发明人： Takao Maeda ,  Satoshi Shima ,  Naofumi Shinya

IPC分类号： C22C1903

CPC分类号： H01M4/385 ,  H01M4/383 ,  H01M10/345 ,  Y10S420/90

摘要： An object of the present invention is to provide a hydrogen absorbing alloy which can improve a high rate discharge property while suppressing particle size reduction, exhibits cycle life characteristics equal to or higher than those of conventional alloys even when its cobalt content is decreased, and has a high capacity. Specifically, the present invention provides a hydrogen absorbing alloy having a CaCu5 type crystal structure in its principal phase, wherein the La content in the alloy is in the range of 24 to 33% by weight and the Mg or Ca content in the alloy is in the range of 0.1 to 1.0% by weight, as well as the aforesaid alloy wherein the Co content in the alloy is not greater than 9% by weight.

摘要翻译： 本发明的目的是提供一种吸氢合金，即使在其钴含量降低的同时，也能够抑制粒径的降低，同时具有等于或高于常规合金的循环寿命特性，并且具有 高容量。 具体地说，本发明提供一种在其主相中具有CaCu5型晶体结构的吸氢合金，其中合金中的La含量在24〜33重量％的范围内，合金中的Mg或Ca含量在 0.1〜1.0重量％的范围，以及合金中Co含量不大于9重量％的上述合金。

公开(公告)号：US5910379A

公开(公告)日：1999-06-08

申请号：US009501

申请日：1998-01-20

申请人： Masaki Kasashima ,  Noriaki Hamaya ,  Naofumi Shinya ,  Satoshi Shima

发明人： Masaki Kasashima ,  Noriaki Hamaya ,  Naofumi Shinya ,  Satoshi Shima

IPC分类号： H01M4/02 ,  H01M4/24 ,  H01M4/38 ,  H01M4/62 ,  H01M10/44 ,  H01M10/34

CPC分类号： H01M4/622 ,  H01M4/242 ,  H01M4/383 ,  H01M10/446 ,  H01M2004/027 ,  H01M4/621 ,  Y10S420/90

摘要： Provided is a hydrogen absorbing alloy suitable for a negative electrode of an Ni--hydrogen storage battery effective at low temperature, more specifically, a R--Ni type of hydrogen absorbing alloy represented by a general formula RNi.sub.a Co.sub.b Al.sub.c M.sub.d, and with Mo content of 50 to 500 ppm wherein R expresses not less than 18 wt % Pr and one or more metals other than Pr, Ni, Co, Al and M, and M expresses one or more metals selected from the group consisting of Fe, Cr, Cu, and Mn, and a to d expresses positive numbers in the specified range Moreover, the above alloy further containing trace amounts of Mg, Ti, Pb, oxygen, carbon, and/or sulfur is provided.

摘要翻译： 本发明提供一种适用于在低温下有效的Ni氢蓄电池的负极的吸氢合金，更具体地说，是由通式RNiaCobAlcMd表示的R-Ni型吸氢合金，Mo含量为50〜500 ppm，其中R表示不小于18重量％的Pr和除Pr，Ni，Co，Al和M以外的一种或多种金属，M表示一种或多种选自Fe，Cr，Cu和Mn的金属， 并且a至d表示指定范围内的正数。此外，还提供了还含有痕量Mg，Ti，Pb，氧，碳和/或硫的上述合金。

公开(公告)号：US06235130B1

公开(公告)日：2001-05-22

申请号：US09265657

申请日：1999-03-10

申请人： Yukihiro Kuribayashi ,  Hiroto Sugahara ,  Masatoshi Ishii ,  Satoshi Shima

发明人： Yukihiro Kuribayashi ,  Hiroto Sugahara ,  Masatoshi Ishii ,  Satoshi Shima

IPC分类号： H01M404

CPC分类号： H01M4/385 ,  H01M4/383 ,  H01M10/30 ,  Y02E60/124 ,  Y10S420/90

摘要： Provided is a hydrogen absorbing alloy powder for use in nickel-metal hydride storage batteries having a high capacity, excellent initial characteristics and a long life. Specifically provided is a process for the production of a hydrogen absorbing alloy powder which includes the steps of treating a hydrogen absorbing alloy powder with an acid solution, and subsequently treating the hydrogen absorbing alloy powder with a solution containing a condensed phosphoric acid having 2 to 20 phosphorus atoms per molecule and/or phytic acid, as well as an electrode formed of the hydrogen absorbing alloy powder produced by the above process. Also provided is a hydrogen absorbing alloy powder of the AB5 type in which A is exothermic metal and B is endothermic metal, the hydrogen absorbing alloy powder being obtained by providing a hydrogen absorbing alloy in which A comprises a mixture composed of 20 to 50% by weight of Ce, 20 to 50% by weight of La, and the balance comprising rare earth elements other than Ce and La and inclusive of Y (yttrium), treating the hydrogen absorbing alloy powder with an acid solution, and further treating the hydrogen absorbing alloy powder with a solution containing a phosphorus compound, as well as an electrode formed of this hydrogen absorbing alloy powder.

摘要翻译： 提供一种用于具有高容量，优异的初始特性和长寿命的镍氢蓄电池的氢吸收合金粉末。 具体地提供一种制备吸氢合金粉末的方法，其包括用酸溶液处理吸氢合金粉末的步骤，随后用含有2〜20的缩合磷酸的溶液处理吸氢合金粉末 每分子磷原子和/或植酸，以及由通过上述方法制备的吸氢合金粉末形成的电极。 还提供了一种AB5型的吸氢合金粉末，其中A是放热金属，B是吸热金属，该吸氢合金粉末是通过提供一种吸氢合金而获得的，其中A包含由20〜50％ Ce的重量，20〜50重量％的La，余量包含Ce和La以外的稀土元素，并且包含Y（钇），用酸溶液处理吸氢合金粉末，进一步处理吸氢 合金粉末与含有磷化合物的溶液，以及由该吸氢合金粉末形成的电极。

公开(公告)号：US06063524A

公开(公告)日：2000-05-16

申请号：US9502

申请日：1998-01-20

申请人： Masaki Kasashima ,  Noriaki Hamaya ,  Naofumi Shinya ,  Satoshi Shima

发明人： Masaki Kasashima ,  Noriaki Hamaya ,  Naofumi Shinya ,  Satoshi Shima

IPC分类号： B22F3/11 ,  H01M4/38 ,  H01M4/52 ,  H01M10/30

CPC分类号： H01M4/385 ,  B22F3/114 ,  H01M4/383

摘要： The object is to provide a hydrogen absorbing alloy suitable for the negative electrode of a Ni-hydrogen storage battery which is effective at low temperatures. The object can be attained by a LaNi.sub.5 type hydrogen absorbing alloy, wherein the content of Mg in the hydrogen absorbing alloy is 50 to 500 ppm, and it is represented by a general formula RNi.sub.a Co.sub.b Al.sub.c M.sub.d, wherein R comprises not less than 77 wt % La and 23 wt % or less of one or more metals other than La, Ni, Co, Al and M, M comprises at least one kind of metals selected from the group consisting of Fe, Cr, Cu and Mn, and a to d denote a positive number within a predetermined range. In addition, it is important to contain a small amount of Ti, Pb, oxygen, carbon and/or sulfur in said alloy.

摘要翻译： 本发明的目的是提供一种适用于在低温下有效的镍氢蓄电池的负极的吸氢合金。 该目的可以通过LaNi5型吸氢合金实现，其中储氢合金中的Mg含量为50〜500ppm，由通式RNiaCobAlcMd表示，其中R包含不小于77wt％的La和 除La，Ni，Co，Al和M，M以外的一种以上的金属的23重量％以下，M包含选自Fe，Cr，Cu和Mn中的至少一种金属，a至d表示 正数在预定范围内。 此外，重要的是在所述合金中含有少量的Ti，Pb，氧，碳和/或硫。