Abstract:
A method for coating a substrate includes suspension plasma spraying of a size distribution of a ceramic powder of essentially uniform chemical composition to form a first ceramic layer. The size distribution has a trough spanning a transition size for powder behavior of gas-flow trajectories of smaller particles and ballistic trajectories of larger particles.
Abstract:
In one aspect, a calcium-magnesium alumino-silicate (CMAS)-resistant coating includes an outer coating having a plurality of columnar structures formed during material deposition due to preferential material accumulation and a plurality of generally vertically-oriented gaps separating adjacent columnar structures. The columnar structures include a plurality of randomly-oriented particle splats and a CMAS-reactive material and have a total porosity of less than five percent. The plurality of generally vertically-oriented gaps extend from an outermost surface of the outer coating to a first depth of the outer coating equal to or less than a total thickness of the outer coating. The vertically-oriented gaps have a median gap width of less than five micrometers.
Abstract:
An environmental barrier coating, comprising a substrate containing silicon; an environmental barrier layer applied to said substrate; said environmental barrier layer comprising a rare earth composition.
Abstract:
A strain-tolerant coating for use in gas turbine engines can include a plurality of dense, generally vertically-oriented columnar structures formed during deposition by preferential material accumulation, and a plurality of inter-columnar gaps separating the columnar structures. The columnar structures can include a plurality of randomly-oriented particle splats and can have a porosity of less than four percent.
Abstract:
In one aspect, a calcium-magnesium alumino-silicate (CMAS)-resistant coating includes an outer coating having a plurality of columnar structures formed during material deposition due to preferential material accumulation and a plurality of generally vertically-oriented gaps separating adjacent columnar structures. The columnar structures include a plurality of randomly-oriented particle splats and a CMAS-reactive material and have a total porosity of less than five percent. The plurality of generally vertically-oriented gaps extend from an outermost surface of the outer coating to a first depth of the outer coating equal to or less than a total thickness of the outer coating. The vertically-oriented gaps have a median gap width of less than five micrometers.
Abstract:
An article includes a substrate, a ceramic barrier coating, and a layer of networked ceramic nanofibers. The ceramic barrier coating is disposed on the substrate and has a porous columnar microstructure. The layer of networked ceramic nanofibers is disposed on the ceramic barrier layer and seals the pores of the porous columnar microstructure.
Abstract:
In accordance with the present disclosure, there is provided a process for limiting a critical stabilizer content in coatings comprising placing a source coating material in a crucible of a vapor deposition apparatus having a coating chamber, the source coating material having compositional range of LnO1.5 comprising a single cation mol % of 30-50% relative to zirconia (ZrO2), where Ln=La, Pr, Nd, Sm, Eu, Gd, and Tb and combinations thereof; energizing the source coating material with an electron beam that delivers a power density to the material in the crucible forming a vapor cloud from the source coating material; and depositing the source coating material as a coating system onto a surface of a work piece.
Abstract:
A process for coating a component and a coating system including a bond coat on a superalloy substrate. A thermal barrier material may be applied to the bond coat and a rare earth apatite may be applied to the thermal barrier material via one of Suspension Plasma Spray (SPS) and Solution Precursor Plasma Spray (SPPS) to form an exposed surface. The rare earth apatite may be formed as Ca2+yRE8+x(SiO4)6O2+3x/2+y in which −2
Abstract:
An article includes a substrate, a ceramic barrier coating, and a layer of networked ceramic nanofibers. The ceramic barrier coating is disposed on the substrate and has a porous columnar microstructure. The layer of networked ceramic nanofibers is disposed on the ceramic barrier layer and seals the pores of the porous columnar microstructure.