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公开(公告)号:US20220388919A1
公开(公告)日:2022-12-08
申请号:US17775366
申请日:2020-11-13
Applicant: Yara International ASA
Inventor: Filip COLPAERT , Ellen DONKERS , Ruud VAN BELZEN , Tom VAN DE WALLE , Paul VAN ELSLANDE
Abstract: The invention relates to a solid, particulate, urea-based blend composition comprising a urea-based compound in particulate form, a component comprising an ammonium source in particulate form, a urease inhibitor of the type phosphoric triamide, an alkaline or alkaline-forming inorganic or organic compound that is able to interact with the component comprising an ammonium source in particulate form, selected from the group consisting of metal oxides, metal carbamates, metal hydroxides, metal acetates and any mixtures thereof, or from the group of organic bases consisting of ammonia, amines, amides, adenines, amidines, guanidines, anilines, carbamates, thiazoles, triazoles, pyridines; imidazoles, benzimidazoles, histidines, phosphazenes, and any mixture thereof, wherein the urea-based blend composition further comprises a cation source, different from the alkaline or alkaline-forming inorganic or organic compound, comprising a cation selected from the group consisting of Fe2+, Fe3+, Mn2+, Zn2+, Cu+, Cu2+, Ni2+, Ag+, Pt2+, Ru2+, Co3+ and Cr3+.
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公开(公告)号:US20220298085A1
公开(公告)日:2022-09-22
申请号:US17629922
申请日:2020-08-12
Applicant: YARA INTERNATIONAL ASA
Inventor: Filip COLPAERT , Ruud VAN BELZEN
Abstract: The invention relates to a solid, particulate, homogeneous urea-based composition comprising urea in particulate form and 0.0001 to 1 weight % of a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), wherein the urea-based composition is further characterized in that it comprises a magnesium sulfate. The composition according to the invention has been stabilized against the degradation of a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT) in the presence of urea. The invention further relates to a method for the manufacture of the claimed solid, particulate, homogeneous urea-based composition.
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3.
公开(公告)号:US20240300864A1
公开(公告)日:2024-09-12
申请号:US18268109
申请日:2021-12-21
Applicant: Yara International ASA
Inventor: Ruud VAN BELZEN , Filip COLPAERT , Francois LEDOUX
Abstract: A method is disclosed for the manufacture of a homogeneous, solid, particulate, urea-based composition comprising urea and an additive in a urea production plant comprising at least an evaporator section and a particulation section, further comprising one or more of a mixing section, an effluent gas treatment section and a scrubber solution storage section, comprising the steps of:
(i) concentrating a urea melt of about 80 weight % to about 95 to 99 weight % of urea;
(ii) particulating a urea or urea-based melt into a urea or urea-based composition;
(iii) mixing the urea melt of about 95 to 99 weight % with other fertilizer components to produce a urea-based melt;
(iv) treating the effluent gas from the particulation section comprising urea-based dust particles and ammonia gas with water to produce a scrubber solution; and
(v) storing the scrubber solution from the effluent gas treatment section.-
公开(公告)号:US20210070669A1
公开(公告)日:2021-03-11
申请号:US17053330
申请日:2019-05-09
Applicant: YARA INTERNATIONAL ASA
Inventor: Ruud VAN BELZEN , Filip COLPAERT
Abstract: The invention relates to a particulate urea-based blend composition comprising a urea-based compound in particulate form and one or more components in particulate form, selected from the group of nitrates, phosphates, sulphates and chlorides, and a urease inhibitor of the type phosphoric triamide, and a magnesium sulphate, wherein the urea-based blend composition is further characterized in that it comprises an alkaline or alkaline-forming compound, selected from the group of calcium oxide, zinc oxide, magnesium oxide, calcium carbonate, and mixtures thereof. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer. The invention further relates to a method for the manufacture of said urea-based blend composition, as well as to a composition of kit of parts comprising an amount of a) magnesium sulphate; b) a urease inhibitor of the type phosphoric triamide, preferably N-(n-butyl) thiophosphoric triamide (nBTPT); c) an alkaline or alkaline-forming compound, selected from the group of calcium oxide, zinc oxide, magnesium oxide, calcium carbonate, and mixtures thereof, and d) optionally, one or more anti-caking and/or moisture-repellent and/or anti-dust compounds.
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5.
公开(公告)号:US20240051888A1
公开(公告)日:2024-02-15
申请号:US18265351
申请日:2021-12-21
Applicant: YARA INTERNATIONAL ASA
Inventor: Ruud VAN BELZEN , Filip COLPAERT , Francois LEDOUX
Abstract: A method is disclosed for the manufacture of a homogeneous, solid, particulate, urea-based composition comprising urea and an additive in a urea production plant comprising at least an evaporator section and a particulation section, further comprising one or more of a mixing section, an effluent gas treatment section and a scrubber solution storage section, comprising the steps of:
(i) concentrating a urea melt of about 80 weight % to about 95 to 99 weight % of urea;
(ii) particulating a urea or urea-based melt into a urea or urea-based composition;
(iii) mixing the urea melt of about 95 to 99 weight % with other fertilizer components to produce a urea-based melt;
(iv) treating the effluent gas from the particulation section comprising urea-based dust particles and ammonia gas with water to produce a scrubber solution; and
(v) storing the scrubber solution from the effluent gas treatment section.-
公开(公告)号:US20230202939A1
公开(公告)日:2023-06-29
申请号:US17919822
申请日:2021-05-07
Applicant: Yara International ASA
Inventor: Filip COLPAERT , Ruud VAN BELZEN
IPC: C05C3/00
CPC classification number: C05C3/005
Abstract: The present disclosure is related to a solid, particulate urea ammonium sulfate-based composition, the particles comprising a core comprising urea ammonium sulfate, and a coating layer surrounding and contacting the core, comprising from about 95 weight % to about 99.9 weight % of urea and a urease inhibitor. The composition displays a higher stability of the urease inhibitor. The present disclosure also provides a method to manufacture the solid, particulate urea ammonium sulfate-based composition.
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公开(公告)号:US20220388918A1
公开(公告)日:2022-12-08
申请号:US17775170
申请日:2020-11-13
Applicant: Yara International ASA
Inventor: Filip COLPAERT , Ellen DONKERS , Ruud VAN BELZEN , Tom VAN DE WALLE , Paul VAN ELSLANDE
Abstract: This present disclosure relates to a solid, particulate, urea ammonium sulphate-based composition, further comprising one or more alkaline or alkaline-forming inorganic or organic compounds that are able to interact with ammonium sulphate, a urease inhibitor of the type phosphoric triamide, and a cation source comprising a cation selected from the group consisting of Fe2+, Fe3+, Mn2+, Zn2+, Cu+, Cu2+, Ni2+, Ag+, Pt2+, Ru2+, Co3+ and Cr3+. The invention further relates to a method for the manufacture of a solid, particulate urea ammonium sulphate-based composition comprising urea, ammonium sulphate, a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), one or more alkaline or alkaline-forming inorganic or organic compounds and a cation source. The product is in particular suitable for use as a fertilizer.
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8.
公开(公告)号:US20210261475A1
公开(公告)日:2021-08-26
申请号:US17053334
申请日:2019-05-10
Applicant: YARA INTERNATIONAL ASA
Inventor: Ruud VAN BELZEN , Filip COLPAERT
Abstract: The invention relates to a particulate urea-based composition comprising elemental sulphur and a urease inhibitor of the type phosphoric triamide, wherein the urea-based composition comprising elemental sulphur is further characterized in that it comprises a magnesium sulphate. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer. The invention further relates to a method for the manufacture of a particulate urea-based composition comprising urea, elemental sulphur and a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), as well as to a composition of kit of parts comprising a magnesium sulphate.
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公开(公告)号:US20210230080A1
公开(公告)日:2021-07-29
申请号:US17053325
申请日:2019-05-07
Applicant: YARA INTERNATIONAL ASA
Inventor: Ruud VAN BELZEN , Filip COLPAERT
Abstract: The invention relates to a homogeneous, solid, particulate, urea ammonium sulphate (UAS)-based composition comprising urea ammonium sulphate, a urease inhibitor of the type phosphoric triamide and magnesium sulphate, characterized in that the UAS-based composition comprises 0.02 to 1 weight % of magnesium sulphate, 0.0001 to 1 weight % of the urease inhibitor and about 5 to about 30 weight % of ammonium sulphate. The composition according to the invention has improved properties for reducing ammonia loss by urease activity in the soil and is in particular suitable as a fertilizer. The invention further relates to a method for the manufacture of a homogeneous, solid, particulate urea ammonium sulphate-based composition comprising urea, ammonium sulphate and a urease inhibitor of the type phosphoric triamide, in particular N-(n-butyl) thiophosphoric triamide (nBTPT), as well as to a composition of kit of parts comprising an amount of a) magnesium sulphate; b) a urease inhibitor of the type phosphoric triamide, preferably N-(n-butyl) thiophosphoric triamide (nBTPT); c) optionally, an alkaline or alkaline-forming compound, selected from the group of calcium oxide, zinc oxide, magnesium oxide, calcium carbonate, and mixtures thereof, and d) optionally, one or more anti-caking and/or moisture-repellent and/or anti-dust compounds.
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