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    Catalytic dewaxing process
    2.
    发明授权
    Catalytic dewaxing process 失效
    催化脱蜡工艺

    公开(公告)号：US4921593A

    公开(公告)日：1990-05-01

    申请号：US87198

    申请日：1987-08-20

    申请人： Fritz A. Smith

    发明人： Fritz A. Smith

    IPC分类号： C10G65/04

    CPC分类号： C10G65/043

    摘要： A lubricant dewaxing process which is useful with difficult feeds, especially highly waxy feeds having paraffin contents in excess of 25 weight percent of feeds with high nitrogen levels, employs two-step dewaxing in which the first stage is carried out under relatively mild conditions to obtain extended catalyst cycle life between successive reactivations with a constant temperature for the duration of each dewaxing cycle. The second stage dewaxing is carried out under conditions which maintain the target pour point for the product with a progressively increasing temperature during each dewaxing cycle. More than one preliminary dewaxing stage may be provided in order to reduce severity in each stage with mild conditions and constant temperature being maintained in the preliminary steps. Using this process, extended catalyst cycle lives may be obtained with difficult feeds.

    摘要翻译： 用于难加工的润滑剂脱蜡方法，特别是具有超过25重量％的具有高氮含量的进料的石蜡含量的高度蜡质的进料采用两步脱蜡，其中第一阶段在相对温和的条件下进行以获得 在每个脱蜡循环的持续时间内，在恒定温度下连续反应之间延长催化剂循环寿命。 第二阶段脱蜡在每个脱蜡循环期间保持产品的目标倾点温度逐渐升高的条件下进行。 可以提供多于一个初步脱蜡阶段，以便在初步步骤中保持温和条件和恒定温度的各个阶段中减轻严重性。 使用该方法，可以通过困难的进料获得延长的催化剂循环寿命。

    Method for enhancing catalytic activity
    3.
    发明授权
    Method for enhancing catalytic activity 失效
    增强催化活性的方法

    公开(公告)号：US4358363A

    公开(公告)日：1982-11-09

    申请号：US225294

    申请日：1981-01-15

    申请人： Fritz A. Smith

    发明人： Fritz A. Smith

    IPC分类号： C10G45/64 ,  C10G67/02 ,  C10G67/06 ,  C10G73/38 ,  C10G45/12

    CPC分类号： C10G67/06

    摘要： A waxy fuel oil that contains a catalytically deleterious contaminant is treated with a crystalline zeolite under sorption conditions followed by catalytic dewaxing with a crystalline zeolite exemplified by ZSM-5 to produce dewaxed fuel oil and high octane gasoline.

    摘要翻译： 含有催化有害污染物的蜡状燃料油在吸附条件下用结晶沸石处理，然后用ZSM-5示例的结晶沸石进行催化脱蜡以产生脱蜡燃料油和高辛烷值汽油。

    Catalytic reactor system
    4.
    发明授权
    Catalytic reactor system 失效
    催化反应器系统

    公开(公告)号：US4743433A

    公开(公告)日：1988-05-10

    申请号：US434664

    申请日：1982-10-15

    申请人： Fritz A. Smith

    发明人： Fritz A. Smith

    IPC分类号： B01J4/00 ,  B01D19/00 ,  B01J8/00 ,  B01J8/02 ,  B01J8/04 ,  C10G49/00 ,  B01J3/02

    CPC分类号： B01J8/0453 ,  B01D19/0047 ,  B01J8/0278 ,  C10G49/002

    摘要： A fixed bed catalytic reactor having a porous bed of catalyst particles contained in a closed reactor shell, comprising inlet means for introducing a downwardly flowing mixed stream of gas and liquid reactants; phase separator means for receiving said mixed stream and directing liquid onto the porous catalyst bed, said separator means being disposed within the reactor shell between said inlet means and said porous catalytic bed; said separator means comprising an upper foraminous wall having a series of gas outlets permitting a substantially-gaseous phase to escape outwardly from the separator means into an upper reactor portion, and lower liquid distribution means for receiving a stream of substantially liquid phase and dividing said liquid phase into a plurality of spaced-apart liquid streams directed toward the porous catalyst bed; and means for recovering gaseous and liquid reaction products from the reactor shell. The phase separator-distributor is particularly useful for retrofitting a reactor to accommodate mixed flow without requiring welding internal structures onto the reactor shell. In a petrochemical complex, such separation and distribution system is advantageous in converting a reactor system for hydrotreating of a hydrocarbon distillate, such as dewaxing.

    摘要翻译： 一种具有包含在封闭反应器壳体中的催化剂颗粒多孔床的固定床催化反应器，包括用于引入向下流动的气体和液体反应物流的混合流的入口装置; 相分离器装置，用于接收所述混合流并将液体引导到多孔催化剂床上，所述分离器装置设置在所述入口装置和所述多孔催化床之间的反应器壳体内; 所述分离器装置包括具有一系列气体出口的上部多孔壁，其允许基本上气相从分离器装置向外逸出到上部反应器部分中;以及下部液体分配装置，用于接收基本上液相的流并将所述液体 相进入朝向多孔催化剂床的多个间隔开的液体流; 以及用于从反应器壳体回收气态和液体反应产物的装置。 相分离器分配器特别适用于改装反应器以适应混合流动，而不需要将内部结构焊接到反应器壳体上。 在石化复合物中，这种分离和分配系统有利于转化用于烃馏出物加氢处理的反应器系统，例如脱蜡。

    Integrated lubricant upgrading process
    6.
    发明授权
    Integrated lubricant upgrading process 有权
    综合润滑油升级过程

    公开(公告)号：US06569312B1

    公开(公告)日：2003-05-27

    申请号：US09711597

    申请日：2000-11-13

    申请人： Michael B. Carroll ,  Fritz A. Smith ,  John C. Bixel

    发明人： Michael B. Carroll ,  Fritz A. Smith ,  John C. Bixel

    IPC分类号： C10G5700

    CPC分类号： C10G45/64 ,  C10G65/12 ,  C10G2400/04 ,  C10G2400/10

    摘要： A process for upgrading oil feedstock wherein the feedstock is hydrocracked, flashed and/or distilled. The bottoms are then vacuum distilled to adjust viscosity and volatility. The refined feed is then dewaxed under high pressure by a medium pore molecular sieve. The dewaxed material is then cascaded to a hydrofinishing step, where it is contacted with an aromatics saturation catalyst having a metal hydrogenation function in order to produce, after appropriate flashing and distillation, lubricant products having high Viscosity Index, low aromatics content, low volatility and excellent stability to light in the presence of oxygen.

    摘要翻译： 一种用于升级油原料的方法，其中原料被加氢裂化，闪蒸和/或蒸馏。 然后将塔底物真空蒸馏以调节粘度和挥发性。 然后将精制的进料通过中孔分子筛在高压下脱蜡。 然后将脱蜡的材料级联至加氢精制步骤，其中其与具有金属氢化功能的芳族化合物饱和催化剂接触，以在适当的闪蒸和蒸馏后产生具有高粘度指数，低芳族化合物含量，低挥发性的润滑剂产品，以及 在氧气存在下对光的稳定性极好。

    Multiphase catalytic process with improved liquid distribution
    7.
    发明授权
    Multiphase catalytic process with improved liquid distribution 失效
    具有改善液体分布的多相催化过程

    公开(公告)号：US4579647A

    公开(公告)日：1986-04-01

    申请号：US732021

    申请日：1985-05-08

    申请人： Fritz A. Smith

    发明人： Fritz A. Smith

    IPC分类号： B01J8/02 ,  B01J8/04 ,  C10G49/00 ,  C10G47/16

    CPC分类号： C10G49/002 ,  B01J8/0278 ,  B01J8/0453

    摘要： A fixed bed catalytic reactor having a porous bed of catalyst particles contained in a closed reactor shell, comprisinginlet means for introducing a downwardly flowing mixed stream of gas and liquid reactants;phase separator means for receiving said mixed stream and directing liquid onto the porous catalyst bed, said separator means being disposed within the reactor shell between said inlet means and said porous catalytic bed;said separator means comprising an upper foraminous wall having a series of gas outlets permitting a substantially-gaseous phase to escape outwardly from the separator means into an upper reactor portion, and lower liquid distribution means for receiving a stream of substantially liquid phase and dividing said liquid phase into a plurality of spaced-apart liquid streams directed toward the porous catalyst bed; andmeans for recovering gaseous and liquid reaction products from the reactor shell.The phase separator-distributor is particularly useful for retrofitting a reactor to accommodate mixed flow without requiring welding internal structures onto the reactor shell. In a petrochemical complex, such separation and distribution system is advantageous in converting a reactor system for hydrotreating of a hydrocarbon distillate, such as dewaxing.

    摘要翻译： 一种具有包含在封闭反应器壳体中的催化剂颗粒多孔床的固定床催化反应器，包括用于引入向下流动的气体和液体反应物流的混合流的入口装置; 相分离器装置，用于接收所述混合流并将液体引导到多孔催化剂床上，所述分离器装置设置在所述入口装置和所述多孔催化床之间的反应器壳体内; 所述分离器装置包括具有一系列气体出口的上部多孔壁，其允许基本上气相从分离器装置向外逸出到上部反应器部分中;以及下部液体分配装置，用于接收基本上液相的流并将所述液体 相进入朝向多孔催化剂床的多个间隔开的液体流; 以及用于从反应器壳体回收气态和液体反应产物的装置。 相分离器分配器特别适用于改装反应器以适应混合流动，而不需要将内部结构焊接到反应器壳体上。 在石化复合物中，这种分离和分配系统有利于转化用于烃馏出物加氢处理的反应器系统，例如脱蜡。

    Integrated lubricant upgrading process
    9.
    发明授权
    Integrated lubricant upgrading process 有权
    综合润滑油升级过程

    公开(公告)号：US06517704B1

    公开(公告)日：2003-02-11

    申请号：US09711605

    申请日：2000-11-13

    申请人： Michael B. Carroll ,  Fritz A. Smith ,  John C. Bixel

    发明人： Michael B. Carroll ,  Fritz A. Smith ,  John C. Bixel

    IPC分类号： C10G2500

    CPC分类号： C10G65/12 ,  C10G2400/04

    摘要： A process for upgrading oil feedstock wherein the feedstock is hydrocracked, and flasked and/or distilled. A distillate fraction boiling in the diesel range is isolated and dewaxed under high pressure by a medium pore molecular sieve. The dewaxed material is then cascaded to a hydrofinishing step, where it is contacted with an aromatics saturation catalyst having a metal hydrogenation function in order to produce diesel fuels having low aromatics content.

    摘要翻译： 一种用于升级油原料的方法，其中原料被加氢裂化，并且被烧瓶和/或蒸馏。 通过中孔分子筛在柴油范围内沸腾的馏出物馏分在高压下分离和脱蜡。 然后将脱蜡的材料级联到加氢精制步骤，在那里与具有金属加氢功能的芳族化合物饱和催化剂接触，以生产具有低芳族化合物含量的柴油燃料。

    Catalytic dewaxing process using binder-free zeolite
    10.
    发明授权
    Catalytic dewaxing process using binder-free zeolite 失效
    催化脱蜡工艺使用无粘结剂的沸石

    公开(公告)号：US4908120A

    公开(公告)日：1990-03-13

    申请号：US87199

    申请日：1987-08-20

    申请人： Emmerson Bowes ,  Fritz A. Smith

    发明人： Emmerson Bowes ,  Fritz A. Smith

    IPC分类号： C10G65/04

    CPC分类号： C10G65/043

    摘要： A lubricant dewaxing process which is useful with difficult feeds, especially highly waxy feeds having paraffin contents in excess of 25 weight percent or feeds with high nitrogen levels, employs two-step dewaxing in which the first stage is carried out under relatively mild conditions using a binder-free zeolite dewaxing catalyst to obtain extended catalyst cycle life between successive reactivations with a constant temperature for the duration of each dewaxing cycle. The second stage dewaxing is also carried out with a binder-free catalyst under conditions which maintain the target pour point for the product with a progressively increasing temperature during each dewaxing cycle. More than one preliminary dewaxing stage may be provided in order to reduce severity in each stage with mild conditions and constant temperature being maintained in the preliminary steps. Using this process, extended catalyst cycle lives may be obtained with difficult feeds.

    摘要翻译： 用于难加工的润滑剂脱蜡方法，特别是具有超过25重量％的石蜡含量或高氮水平进料的高度蜡质进料采用两步脱蜡，其中第一阶段在相对温和的条件下进行，使用 无粘结剂的沸石脱蜡催化剂，以在每个脱蜡循环的持续时间内在恒定温度下连续反应之间获得延长的催化剂循环寿命。 在每个脱蜡循环期间，对于具有逐渐升高的温度的产品的目标倾点的条件下，还可以用无粘合剂的催化剂进行第二阶段脱蜡。 可以提供多于一个初步脱蜡阶段，以便在初步步骤中保持温和条件和恒定温度的各个阶段中减轻严重性。 使用该方法，可以通过困难的进料获得延长的催化剂循环寿命。