Fireproof polyester composition
    91.
    发明授权
    Fireproof polyester composition 失效
    耐火涤纶组合物

    公开(公告)号:US4046724A

    公开(公告)日:1977-09-06

    申请号:US533067

    申请日:1974-12-16

    CPC分类号: C08G79/04 C08L67/02

    摘要: A polyester composition having high fireproofness is obtained by blending a copolymerized polyester comprising a polyalkylene terephthalate containing in the main chain thereof binding units of the formula: ##STR1## (WHEREIN, Y denotes -O-, an alkylidene radical having 1 to 6 carbon atoms or a cycloalkylidene radical having 3 to 6 carbon atoms) with a high molecular weight organic phosphorus compound of the formula: ##STR2## (WHEREIN, R.sub.1 denotes a monovalent hydrocarbon radical of 1 to 18 carbon atoms having or not having one or more substituents, R.sub.2 denotes a divalent hydrocarbon radical of 2 to 20 carbon atoms having or not having one or more substituents, x and z each denote 0 or 1 and n denotes an integer having the value of not less than 3) in an amount corresponding to 0.05 to 1.0% by weight of phosphorus atoms.

    摘要翻译: 通过将包含主链的聚对苯二甲酸亚烷基对苯二甲酸酯的共聚聚酯与下式结合单元(其中,Y表示-O-,具有1至6个碳原子的亚烷基)混合,得到具有高耐火性的聚酯组合物 或具有3至6个碳原子的环烷叉基)与具有下式的高分子量有机磷化合物反应:(其中R 1表示具有或不具有一个或多个取代基的1至18个碳原子的一价烃基, R2表示具有或不具有一个或多个取代基的2至20个碳原子的二价烃基,x和z各自表示0或1,n表示不小于3的整数),其量相当于0.05至 1.0重量%的磷原子。

    Process for preparing 4-amino-3-methyl-N-substituted or unsubstituted
alkylanilines
    92.
    发明授权
    Process for preparing 4-amino-3-methyl-N-substituted or unsubstituted alkylanilines 失效
    制备4-氨基-3-甲基-N-取代或未取代的亚苄基胺的方法

    公开(公告)号:US4009205A

    公开(公告)日:1977-02-22

    申请号:US513787

    申请日:1974-10-10

    CPC分类号: C07D209/48

    摘要: A process for the preparation of 4-amino-3-methyl-N-substituted or unsubstituted alkylanilines comprising acylating and/or sulfonylating 4-amino-3-methyl-nitro-benzene having the formula (I) ##STR1## with an acylation or sulfonylation agent to obtain a compound having the general formula (II) ##STR2## wherein R.sub.1 represents a hydrogen atom or an acyl group, R.sub.2 represents an acyl group or a sulfonyl group, or R.sub.1 and R.sub.2 can combine as a difunctional acyl group; reducing the nitro group of the compound having the general formula (II) with hydrogen in the presence of a metal hydrogenation catalyst to obtain a compound having the general formula (III) ##STR3## wherein R.sub.1 and R.sub.2 are as above defined; alkylating the amino group of the compound having the general formula (III) with an alkylation agent selected from the group consisting of an alkyl halide, a substituted alkyl halide and an alkylene oxide to obtain a compound having the general formula (IV) ##STR4## wherein R.sub.1 and R.sub.2 are as above defined, R.sub.3 represents an alkyl group or a substituted alkyl group and R.sub.4 represents a hydrogen atom, an alkyl group or a substituted alkyl group; and hydrolyzing the compound having the general formula (IV) to obtain a compound having the general formula (V) ##STR5## wherein R.sub.3 and R.sub.4 are as above defined.