摘要:
A method of operating a high temperature fuel cell system containing a plurality of fuel cell stacks includes operating one or more of the plurality of fuel cell stacks at a first output power while operating another one or more of the plurality of the fuel cell stacks at a second output power different from the first output power.
摘要:
A flow battery includes a first liquid-porous electrode, a second liquid-porous electrode spaced apart from the first liquid-porous electrode, and an ion-exchange membrane arranged between the first liquid-porous electrode and the second liquid-porous electrode. First and second flow fields are adjacent to the respective first liquid-porous electrode and second liquid-porous electrode. Each of the flow fields includes first channels having at least partially blocked outlets and second channels having at least partially blocked inlets. The second channels are interdigitated with the first channels. The flow fields provide a configuration and method of operation for relatively thin electrodes with moderate pressure drops and forced convective flow through the liquid-porous electrodes.
摘要:
A vanadium redox battery is a battery capable of charging and discharging utilizing an oxidation-reduction reaction of vanadium as an active material. The vanadium redox battery includes a cathode and an anode. The vanadium redox battery includes an auxiliary electrode that is provided in at least one of the cathode and the anode.
摘要:
The invention concerns electrodes suitable for use in a redox flow battery, the electrode comprising a plurality of perforations ranging in diameter from 100 μm to 10 cm. The introduction of such perforations is correlated to at least a 10% increase in the power density of the redox flow battery. The invention also concerns methods of making such electrodes and flow batteries having at least one such electrode.
摘要:
This secondary battery type fuel cell system is provided with: fine particles of a fuel generator which can generate a fuel gas through oxidation and be regenerated through reduction; a gas-permeable insulating material which covers each of the fine particles; and a solid oxide fuel cell unit which includes a fuel electrode and which has a power generation function of generating power through a reaction between an oxygen-containing oxidizer gas and a fuel gas fed from the fuel generator and an electrolysis function of electrolyzing a product of the reduction, said product being fed from the fuel generator in regenerating the fuel generator. The fine particles covered with the gas-permeable insulating material are distributed in the fuel electrode.
摘要:
An electrochemical device includes a plurality of electrode assemblies that define a plurality of electrochemically active areas. A non-electrically-conductive manifold includes a common manifold passage and a plurality of branch passages that extend, respectively, between the electrochemically active areas and the common manifold passage. Each of the branch passages includes a first region and a second region that differ in surface area.
摘要:
An electro-chemical energy conversion and storage device includes an enclosure, a first electrode operatively connected to the enclosure, a second electrode operatively connected to the enclosure, a nanofluid or particle suspension in the enclosure, a heat transfer unit, and a circulation system for circulating the nanofluid or particle suspension to the heat transfer unit. The nanofluid includes nanoparticles plus a dielectric or ionic fluid. The particle suspension includes particles plus a dielectric or ionic fluid. A wide range of nanoparticles or particles can be used. For example the following nanoparticles or particles can be used: metal and metal alloy particles for anodic dissolution and thermal transport; hydrides as source of hydrogen ions; lithium and lithium alloys; intercalated graphite and carbon aerogel as Li source (anodic material); intercalated transition metal oxide as Li sink (cathodic material); and semiconductors for photovoltaic conversion in photo-electrochemical or hybrid electrochemical cell.
摘要:
A secondary battery type fuel cell system comprising: a fuel generating member, a power generation electrolysis portion that has a power generating function and an electrolysis function, a gas flow path that circulates a gas between the fuel generating member and the power generation electrolysis portion, a gas moving device that sends an oxidant gas to the power generation electrolysis portion, and a gas moving device controller that controls an amount of gas-flow produced by the gas moving device. The gas moving device controller performs control such that an amount of gas-flow produced by the gas moving device at a time when the power generation electrolysis portion is performing electrolysis becomes less than an amount of gas-flow produced by the gas moving device at a time when the power generation electrolysis portion is performing power generation.
摘要:
The fundamental charge storage mechanisms in a number of currently studied high energy redox couples are based on intercalation, conversion, or displacement reactions. With exception to certain metal-air chemistries, most often the active redox materials are stored physically in the electrochemical cell stack thereby lowering the practical gravimetric and volumetric energy density as a tradeoff to achieve reasonable power density. In a general embodiment, a mediated redox flow battery includes a series of secondary organic molecules that form highly reduced anionic radicals as reaction mediator pairs for the reduction and oxidation of primary high capacity redox species ex situ from the electrochemical cell stack. Arenes are reduced to stable anionic radicals that in turn reduce a primary anode to the charged state. The primary anode is then discharged using a second lower potential (more positive) arene. Compatible separators and solvents are also disclosed herein.
摘要:
A method of forming a redox couple bed for a solid oxide redox flow battery is described. The method includes mixing together carbon and metal oxide. The method further includes heating the mixture while feeding an inert gas into the mixture, the inert gas removing gas products CO and CO2. The metal oxide is reduced to a metal resulting in formation of a redox couple bed.