公开(公告)号：US5210177A

公开(公告)日：1993-05-11

申请号：US837136

申请日：1992-02-19

申请人： Eit Drent

发明人： Eit Drent

IPC分类号： B01J31/18 ,  C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02

摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting the carbon monoxide and hydrocarbon under polymerization conditions in the presence of a reaction diluent and a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bis(diethylphosphino)alkane.

公开(公告)号：US5206342A

公开(公告)日：1993-04-27

申请号：US808832

申请日：1991-12-17

申请人： Eit Drent ,  Eric Kragtwijk

发明人： Eit Drent ,  Eric Kragtwijk

IPC分类号： C07F9/6568 ,  C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02 ,  C07F9/65683

摘要： Linear alternating polymers of carbon monoxide, non-conjugated alkenylbenzene compound and optionally ethylene are produced by contacting the monomeric reactants under polymerization conditions in the presence of an inert reaction diluent and a catalytic quantity of a catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid having a pKa less than 2 and a bis(dialkylphosphino)alkane. The polymer products are thermoplastics and have utility as engineering thermoplastics.

公开(公告)号：US5106952A

公开(公告)日：1992-04-21

申请号：US520304

申请日：1990-05-07

申请人： Eit Drent

发明人： Eit Drent

IPC分类号： C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02

摘要： An improved process for the production of linear alternating polymers of carbon monoxide and norbornene-type compounds wherein substantially all of the moieties originating from the carbon monoxide are in a spiroketal structure which comprises contacting the carbon monoxide and norbornene compound in a liquid reaction diluent at a temperature below 55.degree. C. in the presence of a catalyst composition formed from a compound of palladium, the anion of a non-hydrohalogenic acid having a pKa below 2, a bidentate ligand of nitrogen and an organic oxidant, the molar ratio of the bidentate ligand to the anion being at least 4.

公开(公告)号：US5103043A

公开(公告)日：1992-04-07

申请号：US672209

申请日：1991-03-18

申请人： Eit Drent ,  Petrus H. M. Budzelaar

发明人： Eit Drent ,  Petrus H. M. Budzelaar

IPC分类号： B01J31/24 ,  C07C51/14 ,  C07C67/38 ,  C07F9/58 ,  C07F15/00

CPC分类号： B01J31/2409 ,  C07C51/14 ,  C07C67/38 ,  C07F15/0013 ,  C07F15/0066 ,  C07F9/587 ,  B01J2231/321 ,  B01J2531/824

摘要： A catalyst system which comprises:a) a group VIII metal compound, andb) a monophosphine of formula ##STR1## wherein R.sup.1 represents an aliphatic hydrocarbyl group, R.sup.2 represents an optionally substituted aromatic heterocyclic group having 5 or 6 ring atoms of which at least one is nitrogen, which may form part of an optionally substituted larger condensed ring structure, and R.sup.3 independently has the meaning of R.sup.2 or represents an optionally substituted aryl group or an acid addition salt thereof, and their use in the carbonylation of unsaturated compounds.

公开(公告)号：US5101077A

公开(公告)日：1992-03-31

申请号：US668844

申请日：1991-03-13

申请人： Eit Drent

发明人： Eit Drent

IPC分类号： C07C45/51 ,  C07C49/543 ,  C11B9/00

CPC分类号： C07C45/512 ,  C07C49/543 ,  C11B9/0003

摘要： A process is provided for the preparation of unsaturated carbonyl compounds having at least one cycloalkenic moiety in the molecule, which comprises contacting an allylic type unsaturated alcohol and a conjugated diene in the presence of a catalyst system obtainable by combining a Group VIII metal compound and a ligand containing one or more donor atoms selected from Group V A and VI A elements.

摘要翻译： 提供了一种制备在分子中具有至少一个环烯基部分的不饱和羰基化合物的方法，该方法包括在烯烃型不饱和醇和共轭二烯的存在下，通过将VIII族金属化合物和 配体，其含有选自组VA和VI A元素的一个或多个供体原子。

公开(公告)号：US5070184A

公开(公告)日：1991-12-03

申请号：US522701

申请日：1990-05-14

申请人： Pui K. Wong ,  Eit Drent

发明人： Pui K. Wong ,  Eit Drent

IPC分类号： C08G67/02

CPC分类号： C08G67/02

摘要： The relative average stereoregular character of a stereoregular linear alternating polymer of carbon monoxide and aliphatic .alpha.-olefin of at least 3 carbon atoms is enhanced by contacting a stereoregular linear alternating polymer with certain selective solvents and obtaining as a residue of such contacting a polymer of enhanced average stereoregular character.

摘要翻译： 具有至少3个碳原子的一氧化碳和脂肪族α-烯烃的立体规则线性交替聚合物的相对平均有规立构特征通过使立构规整线性交替聚合物与某些选择性溶剂接触而得到增强，并获得增强的聚合物的残留物 平均立体规律性

公开(公告)号：US5061785A

公开(公告)日：1991-10-29

申请号：US474953

申请日：1990-02-05

申请人： Eit Drent

发明人： Eit Drent

IPC分类号： B01J31/04 ,  B01J31/22 ,  B01J31/24 ,  C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02 ,  B01J31/2404 ,  B01J2531/824 ,  B01J31/2208

摘要： An improved process for the production of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a halide-free compound of palladium, a non-hydrohalogenic acid having a pKa below 1 and a tertiary aliphatic monophosphine. The linear alternating polymers are useful as engineering thermoplastics.

公开(公告)号：US5030712A

公开(公告)日：1991-07-09

申请号：US432826

申请日：1989-11-07

申请人： Johannes A. van Doorn ,  Eit Drent ,  Leonard E. H. Gerards

发明人： Johannes A. van Doorn ,  Eit Drent ,  Leonard E. H. Gerards

IPC分类号： B01J31/18 ,  C08G67/00 ,  C08G67/02

CPC分类号： C08G67/02 ,  B01J31/1875 ,  B01J2531/80 ,  B01J2531/824

摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting the carbon monoxide and hydrocarbon under polymerization conditions in the presence of a catalyst composition formed from a palladium compound, an anion of a strong non-hydrohalogenic acid and an aryl phosphine sulfide having at least 2 phosphorus atoms.

公开(公告)号：US5028734A

公开(公告)日：1991-07-02

申请号：US303596

申请日：1989-01-27

申请人： Eit Drent

发明人： Eit Drent

IPC分类号： B01J31/24 ,  B01J31/00 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C57/02 ,  C07C57/03 ,  C07C67/00 ,  C07C67/38 ,  C07C69/52 ,  C07C69/533

CPC分类号： C07C69/52

摘要： A process for the selective carbonylation of a conjugated diene by contacting with carbon monoxide in the presence of a hydroxyl-group-containing compound such as water, alcohol, phenol or carboxylic acid in liquid phase using a catalyst system formed by the combination of:(a) a palladium compound and(b) at least one organic bidentate phosphine.

公开(公告)号：US4975404A

公开(公告)日：1990-12-04

申请号：US442264

申请日：1989-11-28

申请人： Eit Drent ,  Willem W. Jager ,  Swan T. Sie

发明人： Eit Drent ,  Willem W. Jager ,  Swan T. Sie

IPC分类号： B01J31/04 ,  C07B61/00 ,  C07C29/149 ,  C07C29/156 ,  C07C31/04

CPC分类号： C07C29/149 ,  C07C29/156 ,  Y02P20/52

摘要： A process for the production of methanol comprising contacting a gaseous mixture of carbon monoxide and hydrogen with a catalytic system, obtainable by combination of:component (a): a substantially dry nickel formate,component (b): water in a predetermined amount in relation to the nickel formate amount and,component (c): an alcoholate derived from an alkali metal or from an alkaline earth metal, and activation the combined components,and a catalyst system to be used in this process.Preferably the molar ratio between nickel formate and water is in the rate from 1:3.5 to 1:1 and more preferably from 1:3.0 to 1:1.5.