公开(公告)号：US5977202A

公开(公告)日：1999-11-02

申请号：US935059

申请日：1997-09-22

Applicant: Chander P. Chawla ,  Paul E. Snowwhite ,  Edward P. Zahora

Inventor： Chander P. Chawla ,  Paul E. Snowwhite ,  Edward P. Zahora

IPC: C03C25/10 ,  C08F2/46 ,  C09D201/10

CPC classification number: C03C25/106 ,  C03C25/1065 ,  C09D201/10 ,  Y10T428/2938

Abstract: A radiation-curable composition for use as an optical fiber material or coating comprising the combination of the following pre-mixture ingredients:(A) about 5 wt. % to about 95 wt. % of one or more radiation-curable oligomers,(B) about 5 wt. % to about 95 wt. % of one or more monomer diluents,(C) optionally, one or more photoinitiators,(D) about 0.1 wt. % to about 30 wt. % of one or more adhesion promoters represented by:(R.sup.1 --L).sub.4-X --Si(OR.sup.2).sub.Xwherein R.sup.1 is a group comprising an ethylenically unsaturated radiation-curable group; and said three R.sup.2 groups independently of each other are C.sub.1 -C.sub.10 groups; wherein X=1-3; and L is a linking group which comprises one or more alkoxy or branched propoxy groups.

Abstract translation: 用作光纤材料或涂层的可辐射固化组合物，其包含以下预混合物成分的组合：（A）约5重量％ ％至约95wt。 ％的一种或多种可辐射固化的低聚物，（B）约5wt。 ％至约95wt。 ％的一种或多种单体稀释剂，（C）任选的一种或多种光引发剂，（D）约0.1wt。 ％至约30wt。 ％的一种或多种粘合促进剂由（R1-L）4-X-Si（OR2）X表示，其中R1是包含烯属不饱和辐射固化基团的基团; 并且所述三个R2基彼此独立地为C1-C10基团; 其中X = 1-3; L是包含一个或多个烷氧基或支链丙氧基的连接基团。

公开(公告)号：US5827922A

公开(公告)日：1998-10-27

申请号：US808113

申请日：1997-02-28

Applicant: Ming J. Chen ,  Frederick D. Osterholtz

Inventor： Ming J. Chen ,  Frederick D. Osterholtz

IPC: C08K5/5415 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10 ,  C08L83/00

CPC classification number: C08K5/5415 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10

Abstract: Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organotin catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance. Particular catalysts for use herein include mercaptoalcohol, mercaptide and sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond, and include dibutyltin dimercaptide and dibutyltin bis(1-thioglycerol).

Abstract translation: 包含稳定的水分散性可固化聚合物的可固化组合物，其含有占总组合物重量百分比为0.1-75重量％的空间位阻烷氧基化硅烷基团; 水分散或水溶性，水解稳定的有机锡催化剂，占总组合物的0.1至10重量％ 并且在本文中教导了总组合物的99.8至24.9重量％的水。 这些组合物可用作粘合剂，密封剂和油漆。 该组合物具有改进的性能，包括耐溶剂性，粘合性，硬度，耐磨性和耐擦伤性。 用于本文的具体催化剂包括具有Sn-S或Sn = S键的二有机锡的巯基醇，硫醇盐和硫化物形式，并且包括二辛基二锡和二丁基锡双（1-硫代甘油）。

公开(公告)号：US5686523A

公开(公告)日：1997-11-11

申请号：US540142

申请日：1995-10-06

Applicant: Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

Inventor： Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

IPC: C08L83/06 ,  C08J3/215 ,  C08J3/24 ,  C08K5/5415 ,  C08L43/04 ,  C08L101/10 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10

CPC classification number: C09D143/04 ,  C08K5/5415 ,  C09D167/00 ,  C09D201/10

Abstract: Stable alkoxy silane containing compositions and methods for the preparation of a stable silane containing compositions comprising: (I) a water insoluble or slightly soluble alkoxy silane; (II) emulsifier; (III) water; and (IV) water dispersible or emulsified polymer containing an alkoxy silane functional group. Also provided are two part systems such that an alkoxy silane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components, (V), such as catalysts and pH buffers may be added.

Abstract translation: 含有稳定的烷氧基硅烷的组合物和制备含硅烷的组合物的方法，包括：（I）水不溶性或微溶性烷氧基硅烷; （II）乳化剂; （三）水; 和（IV）含有烷氧基硅烷官能团的水分散性或乳化性聚合物。 还提供了两部分系统，使得包含组分（I） - （III）的烷氧基​​硅烷乳液合并，并且组分（IV）可以在使用组分（I）至（III）时加入。 此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。

公开(公告)号：US5663215A

公开(公告)日：1997-09-02

申请号：US634221

申请日：1996-04-18

Applicant: Brian D. Milligan

Inventor： Brian D. Milligan

IPC: C09D5/16 ,  C09D183/04 ,  C09D201/10 ,  C09D143/04

CPC classification number: C09D183/04 ,  C09D201/10 ,  C09D5/1675 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31663

Abstract: A composition suitable for the production of an antifouling coating which comprises: (A) a polymer carrying pendent and/or terminal curable functional groups, at least a major proportion of the repeating units in the polymer (A) being other than siloxane units and (B) a curable organohydrogen polysiloxane or polydiorganosiloxane, the curable functional groups in component (A) being capable of undergoing a condensation curing reaction with component (B). The composition provides antifouling coating having good adhesion and mechanical durability and are used in aquatic or marine environments.

Abstract translation: 一种适于生产防污涂料的组合物，其包括：（A）携带侧链和/或末端可固化官能团的聚合物，聚合物（A）中至少大部分重复单元不是硅氧烷单元和（ B）可固化的有机氢聚硅氧烷或聚二有机硅氧烷，组分（A）中的可固化官能团能够与组分（B）进行缩合固化反应。 该组合物提供具有良好粘附性和机械耐久性的防污涂料，并用于水生或海洋环境中。

公开(公告)号：US5654360A

公开(公告)日：1997-08-05

申请号：US572614

申请日：1995-12-14

Applicant: Peter David Palasz

Inventor： Peter David Palasz

IPC: C09D133/04 ,  C09D133/06 ,  C09D143/04 ,  C09D163/00 ,  C09D167/00 ,  C09D175/00 ,  C09D201/10 ,  C08K5/04 ,  C08K5/05 ,  C08L43/04 ,  C08L63/02

CPC classification number: C09D143/04 ,  C09D133/06 ,  C09D133/068 ,  C09D201/10

Abstract: The invention provides a water-based coating composition in two pack form comprising:i) in a first pack a substantially non-aqueous solution of a silicon-containing polymer which is soluble in water miscible organic solvents and essentially soluble in aqueous media, the silicon groups on the polymer being of formula (1):--SiR.sup.1.sub.a R.sub.3-a (1) in which a is 0 to 2, R.sup.1 is Cl-6 alkyl and R is OH or a hydrolysable group, andii) in a second pack a polymer in dispersion in an aqueous liquid carrier for the composition,where the non-volatile binder solids content of the composition is at least 5% by weight and the molar concentration of silicon in the composition is greater than 0 and less than 0.5.

Abstract translation: 本发明提供了两种包装形式的水性涂料组合物，其包括：i）在第一包装中，基本上是含水聚合物的非水溶液，其可溶于水可混溶的有机溶剂并且基本上可溶于含水介质中，所述硅 聚合物上具有式（1）的基团：-SiR1aR3-a（1）其中a是0-2，R1是C1-6烷基，R是OH或可水解基团，和ii）在第二个包装中，聚合物 在组合物的水性液体载体中分散，其中组合物的非挥发性粘合剂固体含量为至少5重量％，组合物中硅的摩尔浓度大于0且小于0.5。

公开(公告)号：US4826904A

公开(公告)日：1989-05-02

申请号：US124237

申请日：1987-11-23

Applicant: Shoichi Matsumura ,  Toshiro Nanbu ,  Hisao Furukawa

Inventor： Shoichi Matsumura ,  Toshiro Nanbu ,  Hisao Furukawa

IPC: C09D137/00 ,  C09D143/04 ,  C09D157/06 ,  C09D201/02 ,  C09D201/10 ,  C08K5/11

CPC classification number: C09D157/06 ,  C09D143/04 ,  C09D201/10

Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use as automotive refinishing paints and industrial coatings.

Abstract translation: 一种涂料组合物，其包含：（A）100重量份在每个聚合物分子上在主聚合物链末端或其侧链上含有至少一个含有可水解基团的硅原子的甲硅烷基的乙烯基聚合物， 乙烯基聚合物的主链基本上由乙烯基单体的聚合物组成，（B）0至10重量份的固化催化剂，（C）0至10重量份的可水解的酯化合物，和（D） 0.5〜100重量份具有式（1）的二元酸二烷基酯：（1）本发明的涂料组合物与涂层下的粘合性优异，因此适用于汽车修补 涂料和工业涂料。