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1.发明授权Composition of epoxysilane emulsion additives in water based reactive polymer dispersions and methods of preparation 失效环氧硅烷乳液添加剂在水性反应性聚合物分散体中的组成及制备方法
公开(公告)号：US5714532A
公开(公告)日：1998-02-03
申请号：US735055
申请日：1996-11-07
IPC分类号： C08K5/54 , C08K5/15 , C08K5/5435 , C08L83/06 , C08L101/00 , C09D133/06 , C09D183/06 , C09D201/00
CPC分类号： C08K5/5435 , C09D133/064 , C09D183/06
摘要： The present invention provides stable epoxy silane emulsions and methods for the preparation of a stable epoxy-silane emulsions comprising: (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components (V), such as catalysts and pH buffers may be added. Said compositions may be used for, among other things, coatings, adhesives and sealants. The water dispersible or slightly soluble epoxy functional silane for use herein are of the general structure R.sup.1.sub.a R.sup.2.sub.b Si(OR.sup.3).sub.4-a-b where R.sup.1 is an epoxy substituted alkyl or aralkyl group, where the alkyl may have from four to thirty carbon atoms, R.sup.3 is an alkyl or alkoxy-substituted alkyl, aryl or aralkyl group having from two to ten carbon atoms, R.sup.2 is an alkyl group or alkoxy substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, a is one to three, and b is zero to two, with the proviso that a+b is 1, 2, or 3. R.sup.1, R.sup.2, and R.sup.3 group may be cyclic, branched or linear.
摘要翻译： 本发明提供稳定的环氧硅烷乳液和制备稳定的环氧硅烷乳液的方法，包括：（I）水不溶性或微溶环氧硅烷; （II）乳化剂; （三）水; 和（IV）含有具有活性氢的官能团的水分散性聚合物。 还提供了两部分系统，使得包含组分（I） - （III）的环氧硅烷乳液组合，并且组分（IV）可以在使用组分（I）至（III）时加入。 此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。 除其他外，所述组合物可用于涂料，粘合剂和密封剂。 用于本文的水分散性或微溶性环氧官能化硅烷具有通式结构R1aR2bSi（OR3）4-ab，其中R1是环氧取代的烷基或芳烷基，其中烷基可以具有4至30个碳原子，R 3是 烷基或烷氧基取代的烷基，具有2至10个碳原子的芳基或芳烷基，R 2是烷基或烷氧基取代的烷基，具有1至10个碳原子的芳基或芳烷基，a是1至3，b是 0至2，条件是a + b为1,2或3.R 1，R 2和R 3基团可以是环状，支链或直链的。
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公开(公告)号：US4645816A
公开(公告)日：1987-02-24
申请号：US749785
申请日：1985-06-28
CPC分类号： C09K3/1021 , C08G18/10 , Y10S528/906
摘要： Room-temperature curable isocyanate terminated polyurethane polymers whose terminal isocyanate groups have been reacted with a silane monomer having at least one dialkoxy silane group and an organo-functional group with at least one active hydrogen. The polymers crosslink to produce elastomeric polymers with improved elongation and flexibility.
摘要翻译： 其末端异氰酸酯基已经与具有至少一个二烷氧基硅烷基团的硅烷单体和有机官能团与至少一个活性氢反应的室温可固化的异氰酸酯封端的聚氨酯聚合物。 聚合物交联以产生具有改进的伸长率和柔性的弹性体聚合物。
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公开(公告)号：US06627682B1
公开(公告)日：2003-09-30
申请号：US09650035
申请日：2000-08-29
IPC分类号： C08K320
CPC分类号： C09D133/064 , C08K5/5435 , C08L83/06 , C09D183/06 , C08L2666/04 , C08L2666/28
摘要： The present invention is directed to fast reacting epoxy compositions employing select unidentate and chelated Ti(IV) and Sn(II) curing catalysts.
摘要翻译： 本发明涉及使用选择的单齿和螯合的Ti（IV）和Sn（II）固化催化剂的快速反应环氧组合物。
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4.发明授权Compositions of epoxysilane and reactive polymer with cure catalyst and methods of preparation 有权环氧硅烷和反应性聚合物与固化催化剂的组成及其制备方法公开(公告)号：US06221938B1
公开(公告)日：2001-04-24
申请号：US09543020
申请日：2000-04-04
IPC分类号： C08F800
CPC分类号： C08K5/5435 , C08L83/06 , C09D133/064 , C09D183/06 , C08L2666/04 , C08L2666/28
摘要： A method of preparing a coating or a sealant wherein a class of epoxysilanes; optionally, an emulsifier; water; a polymer containing a functional group with an active hydrogen; and a curing catalyst are mixed together.
摘要翻译： 一种制备涂层或密封剂的方法，其中一类环氧硅烷; 任选的乳化剂; 水; 含有具有活性氢的官能团的聚合物; 和固化催化剂混合在一起。
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公开(公告)号：US5621038A
公开(公告)日：1997-04-15
申请号：US452163
申请日：1995-05-26
IPC分类号： C08K5/5415 , C09D143/04 , C09D167/00 , C09D201/10 , C08L83/04
CPC分类号： C09D167/00 , C08K5/5415 , C09D143/04 , C09D201/10
摘要： Curable composition comprising a stable, water dispersible, curable polymer containing a sterically hindered alkoxylated silane group at 0.1 to 75 weight percent of the total composition; a water dispersible or water soluble, hydrolytically stable organometallic catalyst, at 0.1 to 10 weight percent of the total composition; and water at 99.8 to 24.9 weight percent of the total composition are taught herein. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance.Particular catalysts for use herein include dihydroxy bis [2-hydroxypropanato (2-)-O.sup.1,O.sup.2 ] titanate, mixed titanium ortho ester complexes, acetylacetonate chelate, bis(ethyl-3-oxobutanolato-O.sup.1,O.sup.3) bis(2-propanolato) titanium, alkanolamine complex of titanium and mercaptoalcohol, mercaptide or sulfide forms of diorganotins having either a Sn--S or Sn.dbd.S bond.
摘要翻译： 包含稳定的水分散性可固化聚合物的可固化组合物，其含有占总组合物重量百分比为0.1-75重量％的空间位阻烷氧基化硅烷基团; 水分散或水溶性，水解稳定的有机金属催化剂，占总组合物的0.1至10重量％ 并且在本文中教导了总组合物的99.8至24.9重量％的水。 这些组合物可用作粘合剂，密封剂和油漆。 该组合物具有改进的性能，包括耐溶剂性，粘合性，硬度，耐磨性和耐擦伤性。 用于本文的具体催化剂包括二羟基双[2-羟基丙酸酯（2 - ） - O1，O 2]钛酸酯，混合钛原酸酯络合物，乙酰丙酮化合物螯合物，双（乙基-3-氧代丁醇酰-O1，O3）双（2-丙醇） 钛，巯基醇的链烷醇胺络合物，硫醇盐或硫化物形式的具有Sn-S或Sn = S键的二有机锡。
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公开(公告)号：US06887835B1
公开(公告)日：2005-05-03
申请号：US10404176
申请日：2003-03-31
IPC分类号： C10L1/14 , C10L1/26 , C10L1/28 , C10L1/30 , C10L10/04 , C10M137/10 , C10M139/02 , C10M139/04 , C10M141/12 , C10M155/02 , C10M169/02 , C10M169/04 , C10N30/06 , C10N40/04 , C10N40/08 , C10N40/20 , C10N40/25 , C10N40/30
CPC分类号： C10L10/08 , C10L1/14 , C10L1/265 , C10L1/28 , C10L10/04 , C10M139/02 , C10M139/04 , C10M141/12 , C10M2219/082 , C10M2223/045 , C10M2227/02 , C10M2227/04 , C10N2230/06
摘要： Lubricants, especially lubricating oils, and fuels, especially hydrocarbon fuels, contain a class of anti-wear, anti-fatigue, and extreme pressure additives that are derived from silanes. The additives can be used as either partial or complete replacements for zinc dialkyldithiophosphates currently used in lubricants and fuels.
摘要翻译： 润滑剂，特别是润滑油和燃料，特别是烃燃料，含有一类来自硅烷的抗磨损，抗疲劳和极压添加剂。 添加剂可用作目前用于润滑剂和燃料的二烷基二硫代磷酸锌的部分或完全替代物。
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7.发明授权Compositions of epoxysilane emulsion additives in waterbased reactive polymer dispersions and methods of preparation 失效水基反应性聚合物分散体中环氧硅烷乳液添加剂的组成及其制备方法公开(公告)号：US06369139B1
公开(公告)日：2002-04-09
申请号：US08977097
申请日：1997-11-24
IPC分类号： C08K51515
CPC分类号： C09D133/064 , C08K5/5435 , C08L83/06 , C09D183/06 , C08L2666/04 , C08L2666/28
摘要： The present invention provides stable epoxy silane emulsions and methods for the preparation of such compositions comprising (I) a water insoluble or slightly soluble epoxysilane; (II) an emulsifier; (III) water; and (IV) a water dispersible polymer containing a functional group with an active hydrogen. Also provided are two part systems such that an epoxysilane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I)-(III). Moreover, additional components (V), such as catalysts and pH buffers, may be added. Such compositions may be used for, among other things, coatings, adhesives and sealants.
摘要翻译： 本发明提供稳定的环氧硅烷乳液和制备这种组合物的方法，包括（I）水不溶性或微溶环氧硅烷; （II）乳化剂; （三）水; 和（IV）含有具有活性氢的官能团的水分散性聚合物。 还提供了两部分系统，使得包含组分（I） - （III）的环氧硅烷乳液组合，并且组分（IV）可以在使用组分（I） - （III）时加入。 此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。 这些组合物可以用于涂料，粘合剂和密封剂等。
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8.发明授权Compositions of epoxysilane and reactive polymer with cure catalyst and methods of preparation 失效环氧硅烷和反应性聚合物与固化催化剂的组成及其制备方法
公开(公告)号：US6127462A
公开(公告)日：2000-10-03
申请号：US902127
申请日：1997-07-30
IPC分类号： C08K5/5435 , C08L83/06 , C09D133/06 , C09D183/06 , C08F8/00
CPC分类号： C08K5/5435 , C08L83/06 , C09D133/064 , C09D183/06
摘要： The present invention provides stable epoxy silane solutions and emulsions and methods for the preparation of stable epoxy-silane solutions and emulsions comprising: (I) a water insoluble or slightly soluble epoxysilane; (II) optionally, an emulsifier; (III) water; (IV) a water dispersible polymer containing a functional group with an active hydrogen; and (V) a catalyst. Also provided are two part systems such that an epoxysilane solution or emulsion comprising components (I)-(III) are combined and the components (IV) and (V) may be added upon use of components (I) to (III). Moreover, additional components, such as pH buffers may be added. Said compositions may be used for, among other things, coatings, adhesives and sealants. The water epoxy functional silane for use herein are of the general structure R.sup.1.sub.a R.sup.2.sub.b Si(OR.sup.3).sub.4-a-b where R.sup.1 is an epoxy substituted alkyl or aralkyl group, where the alkyl may have from four to thirty carbon atoms, R.sup.3 is an alkyl or alkoxy-substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, R.sup.2 is an alkyl group or alkoxy substituted alkyl, aryl or aralkyl group having from one to ten carbon atoms, a is one to three, and b is zero to two, with the proviso that a+b is 1, 2, or 3. R.sup.1, R.sup.2, and R.sup.3 group may be cyclic, branched or linear.
摘要翻译： 本发明提供了稳定的环氧硅烷溶液和用于制备稳定的环氧硅烷溶液和乳液的乳液和方法，其包括：（I）水不溶性或微溶环氧硅烷; （II）任选的乳化剂; （三）水; （IV）含有具有活性氢的官能团的水分散性聚合物; 和（V）催化剂。 还提供了两部分系统，使得包含组分（I） - （III）的环氧硅烷溶液或乳液组合，并且可以在使用组分（I）至（III）时添加组分（IV）和（V）。 此外，可以添加另外的组分，例如pH缓冲液。 除其他外，所述组合物可用于涂料，粘合剂和密封剂。 用于本文的水环氧官能硅烷具有通式结构R1aR2bSi（OR3）4-ab，其中R1是环氧取代的烷基或芳烷基，其中烷基可以具有4至30个碳原子，R3是烷基或烷氧基 - 具有1至10个碳原子的取代的烷基，芳基或芳烷基，R 2是烷基或烷氧基取代的烷基，具有1至10个碳原子的芳基或芳烷基，a是1至3，b为0至2， 条件是a + b为1,2或3.R 1，R 2和R 3基团可以是环状，支链或直链的。
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公开(公告)号：US6069200A
公开(公告)日：2000-05-30
申请号：US935003
申请日：1997-09-22
IPC分类号： C08L101/10 , C09D201/10 , C08L43/00
CPC分类号： C08L101/10 , C09D201/10
摘要： Curable compositions comprising stable, water dispersible, curable polymers containing sterically hindered alkoxylated silane groups and acid groups blocked by fugitive bases at 0.1 to 75 weight percent of the total composition and water at 99.9 to 25 weight percent of the total composition are taught herein, as well as methods for the use and manufacture thereof. Additional components, such as emulsifiers, buffers and thickeners are also taught. These compositions are useful as adhesives, sealants and paints. The compositions have improved properties including solvent resistance, adhesion, hardness, abrasion resistance and mar resistance.
摘要翻译： 包含稳定的水分散性固化性聚合物，其含有空间位阻烷氧基化硅烷基团和酸性基团，以总组合物的0.1至75重量％和水为总组合物的99.9至25重量％ 以及其使用和制造方法。 还教导了其它组分，如乳化剂，缓冲剂和增稠剂。 这些组合物可用作粘合剂，密封剂和油漆。 该组合物具有改进的性能，包括耐溶剂性，粘合性，硬度，耐磨性和耐擦伤性。
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公开(公告)号：US06395856B1
公开(公告)日：2002-05-28
申请号：US09445080
申请日：1999-12-02
IPC分类号： C08G7708
CPC分类号： C08G77/485 , C08F290/148 , C08G77/045 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/442 , C08K5/5425 , C09D183/10 , C08L23/16 , C08L83/10 , C08L83/00
摘要： Oligomers of the formula: [R3SiO1/2]m[O1/2Si(R2)O1/2]n[SiO3/2R]o[SiO4/2]p (I) wherein each R is selected individually from the group consisting of B, R1, —OR2, R3 and R4; B is an organosilyl functional group bridged to the Si atom of the siloxane oligomer backbone by an Si—C bond; each R1 is independently a saturated aliphatic hydrocarbon group of 1 to 16 carbon atoms; each R2 is independently a group as defined for R1, an aromatic hydrocarbon group or an acyl group; each R3 is independently a monovalent organic radical containing an aliphatically unsaturated hydrocarbon group and each R4 is a monovalent organic radical linked to the Si atom of the siloxane oligomer backbone by an Si—C bond, which does not include an aliphatically unsaturated hydrocarbon group and which has thereon one or more members of the group selected from aromatic hydrocarbon, ether, ester, carbamate, thioether, polysulfide, blocked mercaptan, amide, epoxy, cyano and oximato groups; and with the provisos that at least one quarter of all R groups are —OR2; either at least one silicon atom of the oligomer has an R3 group thereon or at least one R is a B, or both; if there is a group R3 which is a vinyl group, there is at least one other group which is a B group, an R3 group other than vinyl, or an R4 group; m=2 to 20; n=0 to 50; o=0 to 20; and p=0 to 10, are useful as coupling agents in curable compositions of filled organic polymers used for wire and cable insulation. The oligomers also have utility as crosslinkers, as adhesion promoters, to provide a dual radical/moisture cure mechanism, and/or to provide moisture resistance in coating, in other compositions, such as curable adhesives and coatings.
摘要翻译： 下式的低聚物：其中R独立地选自B，R 1，-OR 2，R 3和R 4; B是通过Si-C键桥接到硅氧烷低聚物主链的Si原子上的有机甲硅烷基官能团; 每个R 1独立地为1至16个碳原子的饱和脂族烃基; 每个R 2独立地是如R1所定义的基团，芳族烃基或酰基; 每个R 3独立地是含有脂族不饱和烃基的一价有机基团，并且每个R 4是通过不包含脂族不饱和烃基的Si-C键与硅氧烷低聚物主链的Si原子连接的一价有机基团， 具有一个或多个选自芳族烃，醚，酯，氨基甲酸酯，硫醚，多硫化物，封端的硫醇，酰胺，环氧基，氰基和肟基的基团的成员; 并且条件是所有R组中至少四分之一为-OR2; 低聚物的至少一个硅原子在其上具有R 3基团或至少一个R是B或两者; 如果存在作为乙烯基的基团R 3，则至少另外一个为B基团，除乙烯基以外的R 3基团或R 4基团的基团; m = 2〜20; n = 0〜50; o = 0〜20; 和p = 0至10，可用作用于电线和电缆绝缘的填充有机聚合物的可固化组合物中的偶联剂。 低聚物在其它组合物如可固化粘合剂和涂料中也可用作交联剂，作为粘合促进剂，以提供双重自由基/湿度固化机理和/或提供涂层中的耐湿性。
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