公开(公告)号：US5700298A

公开(公告)日：1997-12-23

申请号：US616826

申请日：1996-03-15

Applicant: Hang Shi ,  Jeremy Barker ,  Rene Koksbang

Inventor： Hang Shi ,  Jeremy Barker ,  Rene Koksbang

IPC: C01B31/00 ,  H01M4/02 ,  H01M4/1393 ,  H01M4/58 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/36 ,  H01M6/00 ,  C01B31/04 ,  C25B11/12 ,  H01M4/62

CPC classification number: H01M10/0525 ,  C01B31/0415 ,  H01M4/587 ,  H01M2004/021 ,  H01M4/1393 ,  Y02P70/54 ,  Y10T29/49108

Abstract: Increasing the percentage of the 3R phase present in graphite reduces the first capacity loss of anodes employing the so modified graphite. Conversion of 2H phase graphite to 3R phase graphite can be achieved by grinding graphite. Non-aqueous solid electrochemical cells with improved performance can be fabricated by employing intercalation based carbon anodes comprising graphite with high percentage of 3R. When employed in an electrochemical cell, the first cycle capacity loss of only about 10%.

Abstract translation: 增加存在于石墨中的3R相的百分比降低了使用这种改性石墨的阳极的第一容量损失。 2H相石墨转化为3R相石墨可以通过研磨石墨来实现。 具有改进性能的非水固体电化学电池可以通过采用包含高比例的3R的石墨的基于嵌入的碳阳极来制造。 当用于电化学电池时，第一次循环容量损失仅为10％左右。

公开(公告)号：US5698338A

公开(公告)日：1997-12-16

申请号：US616900

申请日：1996-03-15

Applicant: Jeremy Barker ,  M. Yazid Saidi

Inventor： Jeremy Barker ,  M. Yazid Saidi

IPC: C01G53/00 ,  H01M4/131 ,  H01M4/133 ,  H01M4/48 ,  H01M4/485 ,  H01M4/52 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/36 ,  H01M9/48

CPC classification number: H01M4/485 ,  C01G53/42 ,  H01M4/525 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/40 ,  H01M10/0525 ,  H01M4/131 ,  H01M4/133

Abstract: Non-aqueous lithium solid electrochemical cells with improved performance can be fabricated by employing intercalation based carbon anodes and cathodes comprising Li.sub.x Ni.sub.y CO.sub.1-y VO.sub.4 wherein 0.9.ltoreq.X.ltoreq.1.1 and 0.1

Abstract translation: 具有改进性能的非水性锂固体电化学电池可以通过采用基于嵌层的碳阳极和包含LixNiy CO1-yVO4的阴极来制造，其中0.9

公开(公告)号：US5670277A

公开(公告)日：1997-09-23

申请号：US664092

申请日：1996-06-13

Applicant: Jeremy Barker ,  M. Yazid Saidi

Inventor： Jeremy Barker ,  M. Yazid Saidi

IPC: H01M4/131 ,  H01M4/133 ,  H01M4/48 ,  H01M4/485 ,  H01M6/10 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0569 ,  H01M10/36 ,  H01M4/02

CPC classification number: H01M4/485 ,  H01M10/0525 ,  H01M10/052 ,  H01M10/0569 ,  H01M4/131 ,  H01M4/133

Abstract: The invention provides a rechargeable lithium battery which comprises an electrolyte; a negative electrode having a compatible active material; and a positive electrode comprising a lithium copper oxide intercalation compound. The positive electrode active material is characterized by an ability to deintercalate lithium ions for intercalation into the negative electrode active material. The lithium copper oxide has a proportion of 2 lithium ions per formula unit of the copper oxide and upon electrochemical interaction with a negative electrode deintercalates lithium ions whereupon the proportion of lithium ions per copper oxide formula unit is less than 2. The lithium copper oxide is a compound represented by the nominal general formula Li.sub.2 CuO.sub.2. The lithium copper oxide compound is alternatively represented by the nominal general formula Li.sub.2-x CuO.sub.2, signifying its capability to deintercalate lithium.

Abstract translation: 本发明提供一种可充电锂电池，其包括电解质; 具有相容的活性物质的负极; 以及包含锂铜氧化物插层化合物的正极。 正极活性物质的特征在于将锂离子脱嵌插入负极活性物质中的能力。 锂二氧化铜每氧化铜的配方单位具有2个锂离子的比例，并且与负极的电化学相互作用脱去锂离子，因此每个氧化铜配方单元的锂离子的比例小于2.氧化铜锂是 由标称通式Li 2 CuO 2表示的化合物。 氧化锂铜化合物可替代地由标称通式Li 2-x Cu 2 O 2表示，表示其脱嵌锂的能力。