公开(公告)号：US20130210085A1

公开(公告)日：2013-08-15

申请号：US13745403

申请日：2013-01-18

Applicant: PETER H. KILNER ,  THOMAS P. GRIFFIN ,  BERNARD COOKER ,  ROGER WEINBERG

Inventor： PETER H. KILNER ,  THOMAS P. GRIFFIN ,  BERNARD COOKER ,  ROGER WEINBERG

IPC: C12P19/14

CPC classification number: C12P19/14 ,  C12M45/02 ,  C12M45/06 ,  C12P19/00 ,  C12P2201/00

Abstract: A method for the pretreatment of biomass solids includes hydrating the biomass solids to form a biomass slurry, shear treating the biomass solids, and hydrolyzing the biomass solids in the presence of reactive enzymes in a pressure hydrolysis zone. Shear treatment of the biomass solids reduces the particle size of the biomass solids, modifies the particle or slurry morphology, and/or ruptures the cell walls of the biomass solids. The pressure hydrolysis zone includes a high-shear, high-pressure, low-temperature heat exchange and reaction zone and a low-pressure, low-temperature polishing zone. Sugars formed from the biomass solids treated in accordance with the methods described above may be used to produce various biofuels.

Abstract translation: 用于预处理生物质固体的方法包括将生物质固体水合以形成生物质浆料，剪切处理生物质固体，以及在反应性酶存在下在压力水解区中水解生物质固体。 生物质固体的剪切处理降低了生物质固体的粒径，改变了颗粒或浆料的形态，和/或破坏了生物质固体的细胞壁。 压力水解区包括高剪切，高压，低温的热交换和反应区以及低压低温抛光区。 由根据上述方法处理的生物质固体形成的糖可用于生产各种生物燃料。

公开(公告)号：US20080132717A1

公开(公告)日：2008-06-05

申请号：US11633196

申请日：2006-12-04

Applicant: Bernard Cooker ,  John H. Speidel

Inventor： Bernard Cooker ,  John H. Speidel

IPC: C07D301/06

CPC classification number: C07D301/12

Abstract: In a propylene oxide process wherein propylene is oxidized in a reaction mixture comprised of a solid catalyst slurried in a solvent and wherein propane and propylene are separated by distillation in a C3 splitter, the improvement of removing exothermic heat of reaction by indirect heat exchange with propane, separating the heated propane into a liquid and a vapor fraction and heating the C3 splitter distillation with the said propane vapor.

Abstract translation: 在其中丙烯在由在溶剂中浆化的固体催化剂组成的反应混合物中被氧化并且其中丙烷和丙烯在C 3分馏器中通过蒸馏分离的环氧丙烷方法中，改进了去除放热 通过与丙烷的间接热交换反应，将加热的丙烷分离成液体和蒸气馏分，并用所述丙烷蒸气加热C 3 H 3分馏塔。

公开(公告)号：US07273826B2

公开(公告)日：2007-09-25

申请号：US11190088

申请日：2005-07-26

Applicant: Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

Inventor： Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

IPC: B01J29/06 ,  B01J29/78

CPC classification number: C07D303/04 ,  B01J23/06 ,  B01J23/60 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07D301/06

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.

Abstract translation: 本发明是一种包含钛或钒沸石，粘合剂和氧化锌的催化剂，其中催化剂正在制备沸石，粘合剂源和氧化锌源的含水混合物，并使混合物快速干燥。 该催化剂可用于烯烃环氧化。

公开(公告)号：US20110098491A1

公开(公告)日：2011-04-28

申请号：US12589775

申请日：2009-10-28

Applicant: Bernard Cooker ,  Bi Le-Khac

Inventor： Bernard Cooker ,  Bi Le-Khac

IPC: C07D301/06 ,  C07D301/04

CPC classification number: C07D301/06 ,  C07D301/04

Abstract: The invention is a process for epoxidizing an olefin with hydrogen and oxygen in the presence of an alkanoic acid and a catalyst comprising a noble metal and a titanium zeolite, wherein the catalyst has not been reduced prior to epoxidation. This process surprisingly gives significantly improved productivity and reduced formation of unwanted propane compared to processes that do not use the alkanoic acid modifier.

Abstract translation: 本发明是在链烷酸和包含贵金属和钛沸石的催化剂存在下用氢和氧环氧化烯烃的方法，其中催化剂在环氧化之前没有还原。 与不使用链烷酸改性剂的方法相比，该方法令人惊奇地提供了显着提高的生产率并减少了不想要的丙烷的形成。

公开(公告)号：US07476770B2

公开(公告)日：2009-01-13

申请号：US11888600

申请日：2007-08-01

Applicant: Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

Inventor： Jay F. Miller ,  Bernard Cooker ,  Robert N. Cochran ,  Peter J. Whitman

IPC: C07C27/00 ,  C07D301/02 ,  C07D301/12

CPC classification number: C07D303/04 ,  B01J23/06 ,  B01J23/60 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07D301/06

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.

Abstract translation: 本发明是一种包含钛或钒沸石，粘合剂和氧化锌的催化剂，其中催化剂正在制备沸石，粘合剂源和氧化锌源的含水混合物，并使混合物快速干燥。 该催化剂可用于烯烃环氧化。

公开(公告)号：US20070276166A1

公开(公告)日：2007-11-29

申请号：US11888600

申请日：2007-08-01

Applicant: Jay Miller ,  Bernard Cooker ,  Robert Cochran ,  Peter Whitman

Inventor： Jay Miller ,  Bernard Cooker ,  Robert Cochran ,  Peter Whitman

IPC: B01J29/04 ,  C07C27/00

CPC classification number: C07D303/04 ,  B01J23/06 ,  B01J23/60 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/186 ,  B01J2229/20 ,  B01J2229/42 ,  C07D301/06

Abstract: The invention is a catalyst comprising a titanium or vanadium zeolite, a binder, and zinc oxide, wherein the catalyst is preparing an aqueous mixture of the zeolite, a binder source, and a zinc oxide source, and subjecting the mixture to rapid drying. The catalyst is useful in olefin epoxidation.

公开(公告)号：US20070004583A1

公开(公告)日：2007-01-04

申请号：US11173350

申请日：2005-07-02

Applicant: Bernard Cooker ,  Roger Grey ,  Edrick Morales

Inventor： Bernard Cooker ,  Roger Grey ,  Edrick Morales

IPC: B01J29/06 ,  B01J29/04 ,  C01B39/04 ,  C01B39/00

CPC classification number: C07D301/08 ,  B01J23/38 ,  B01J29/89 ,  B01J37/0045 ,  B01J2229/18 ,  B01J2229/20 ,  B01J2229/42 ,  Y02P20/52

Abstract: A process is provided for the production of a noble metal on TS-1 catalyst useful for the production of propylene oxide wherein TS-1 from hydrothermal crystallization has noble metal dispersed thereon, the resulting material is spray dried and template used in the crystallization is removed, the resulting product is treated with hydrogen to form active catalyst for propylene oxide production.

公开(公告)号：US06972337B1

公开(公告)日：2005-12-06

申请号：US10918605

申请日：2004-08-12

Applicant: Wilson H. Onimus ,  Bernard Cooker

Inventor： Wilson H. Onimus ,  Bernard Cooker

IPC: B01J29/44 ,  B01J29/48 ,  B01J29/89 ,  C07D301/06 ,  C07D301/12

CPC classification number: B01J29/48 ,  B01J29/44 ,  B01J29/89 ,  B01J2229/186 ,  B01J2229/30 ,  B01J2229/40 ,  C07D301/12

Abstract: Titanium or vanadium zeolites are heated at a temperature greater than 400° C., then contacted with water prior to use in olefin epoxidation with hydrogen peroxide.

Abstract translation: 钛或钒沸石在大于400℃的温度下加热，然后在用过氧化氢进行烯烃环氧化之前与水接触。

公开(公告)号：US06710194B1

公开(公告)日：2004-03-23

申请号：US10349655

申请日：2003-01-23

Applicant: Robert N. Cochran ,  Prakash G. Balan ,  Mark A. Liepa ,  Bernard Cooker

Inventor： Robert N. Cochran ,  Prakash G. Balan ,  Mark A. Liepa ,  Bernard Cooker

IPC: C07D30106

CPC classification number: C07D301/06

Abstract: Propylene oxide is produced by liquid phase reaction of propylene oxygen and hydrogen in contact with a solid epoxidation catalyst at elevated temperature and pressure, the reaction conditions being regulated to provide a weight ratio of dissolved oxygen to dissolved hydrogen in the liquid reaction mixture of at least 16.

Abstract translation: 环氧丙烷是通过在高温和高压下与固体环氧化催化剂接触的丙烯氧气和氢气的液相反应产生的，调节反应条件以提供至少在液体反应混合物中的溶解氧与溶解氢的重量比 16。

公开(公告)号：US06555493B2

公开(公告)日：2003-04-29

申请号：US09873715

申请日：2001-06-04

Applicant: Bernard Cooker ,  Jennifer D. Jewson ,  Wilson H. Onimus

Inventor： Bernard Cooker ,  Jennifer D. Jewson ,  Wilson H. Onimus

IPC: B01J2100

CPC classification number: C07D301/06 ,  C07D301/08

Abstract: The stability of a noble metal/titanium zeolite catalyst is improved by elevated temperature calcination with an oxygen containing gas; the catalyst is useful in epoxidation involving the reaction of olefin, oxygen and hydrogen.

Abstract translation: 贵金属/钛沸石催化剂的稳定性通过用含氧气体进行高温煅烧而提高; 该催化剂可用于涉及烯烃，氧和氢的反应的环氧化。