Abstract:
A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.
Abstract:
A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.
Abstract:
A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.
Abstract:
A positioning device is provided, including: a base seat, including a plurality through holes and a slide groove; a clamping assembly, disposed within the slide groove, including a first clamping body and a second clamping body; an adjustment assembly, including a first driving rod, a second driving rod and at least one rotation rod, the first driving rod including a first thread section and a first bevel gear, the second driving rod including a second thread section and a second bevel gear, the first clamping body and the second clamping body are respectively screwed on the first thread section and the second thread section, each rotation rod including a third bevel gear, the third bevel gear respectively meshed with the first bevel gear and the second bevel gear.
Abstract:
A centering vice is provided, including: a base, a clamp assembly and an adjusting assembly. The base includes a sliding groove extending in a first direction and a first abutting portion. The clamp assembly includes a first jaw portion and a second jaw portion. The adjusting assembly includes a threaded rod, a positioning member and two adjusting members. The threaded rod includes a first threaded segment, a second threaded segment and a positioning portion. The positioning member is immovably connected to the positioning portion and disposed between the two adjusting members, and the two adjusting members respectively have a second abutting portion abutted against the first abutting portion. The two adjusting members are movable relative to the base in a second direction lateral to the first direction to urge the positioning member to move in the first direction.
Abstract:
A driving circuit for a sound outputting apparatus includes a H-bridge and a charge pump established by six switches for driving two types of loudspeakers, respectively. The six switches include two common switches to be configured in the H-bridge and the charge pump, thereby reducing the costs and circuit area of the driving circuit.
Abstract:
A vise jaw is provided, including: a first jaw, including a slide groove and at least one locking portion, each locking portion including a receiving room, a threaded hole and a through hole, the receiving room, the threaded hole and the through hole respectively communicated with each other; a second jaw, having a slide protrusion slidably disposed within the slide groove, the slide protrusion having a lateral face facing the through hole; at least one fastening assembly, each fastening assembly including a screw member, an abutting member and at least one elastic member, the screw member screwed into the threaded hole, the abutting member adjustably disposed within the receiving room, the abutting member including a large diameter section and a small diameter section which are arranged along a first direction, the small diameter section disposed through the through hole and extending into the slide groove.
Abstract:
A user is authenticated using portraits of known contacts. During a challenge-response process, a collection of portraits are presented, some known to an authenticated user and some randomly selected. Responsive to correctly identifying the known portraits, the user is granted access to a system.