Bisbiphenylacylphosphine oxide and preparation method therefore

    公开(公告)号:US07825274B2

    公开(公告)日:2010-11-02

    申请号:US12141380

    申请日:2008-06-18

    CPC classification number: C07F9/657172

    Abstract: A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.

    BISBIPHENYLACYLPHOSPHINE OXIDE AND PREPARATION METHOD THEREFORE

    公开(公告)号:US20080255381A1

    公开(公告)日:2008-10-16

    申请号:US12141354

    申请日:2008-06-18

    CPC classification number: C07F9/657172

    Abstract: A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.

    Bisbiphenylacylphosphine oxide and preparation method therefore
    13.
    发明申请
    Bisbiphenylacylphosphine oxide and preparation method therefore 有权
    二苯基酰基氧化膦及其制备方法

    公开(公告)号:US20070173659A1

    公开(公告)日:2007-07-26

    申请号:US11337441

    申请日:2006-01-24

    CPC classification number: C07F9/657172

    Abstract: A bisbiphenylacylphosphine oxide of formula (I) and its preparation method are provided. The formula of —Ar— is First, 10-chloro-9,10-dihydro-9-oxa-10-phosphaphenanthrene (CDOP) is prepared by using 2-phenylphenol, and then is esterified to synthesize 6-methoxy-(6H)-dibenz[c,e][1,2]oxa-phosphorin (MDOP). Next, acid chloride compounds are added for performing the Arbuzov reaction to synthesize bisbiphenylacylphosphine oxide. CDOP is hydrolyzed to be derived into 9,10-dihydro-9-oxa-10-phosphaphen-anthrene-10-oxide (DOPO), and then DOPO reacts with arylaldehyde to form secondary alcohol. Therefore, bisbiphenylacylphosphine oxide is prepared by using secondary alcohol under oxidation. Also, under a coupling reaction, DOPO reacts with the acid chloride compounds by using a Lewis acid as a catalyst to prepare bisbiphenylacylphosphine oxide.

    Abstract translation: 提供式(I)的双联苯酰基氧化膦及其制备方法。 -Ar-的配方是通过使用2-苯基苯酚制备10-氯-9,10-二氢-9-氧杂-10-磷杂菲(CDOP),然后酯化合成6-甲氧基 - (6H) - 二苯并[c,e] [1,2]氧杂 - 磷杂(MDOP)。 接下来,加入酰氯化合物进行Arbuzov反应以合成双联苯基酰基氧化膦。 将CDOP水解成9,10-二氢-9-氧杂-10-磷杂蒽-10-氧化物(DOPO),然后DOPO与芳基醛反应形成仲醇。 因此,通过使用仲醇在氧化下制备双联苯基酰基氧化膦。 此外,在偶联反应中,DOPO通过使用路易斯酸作为催化剂与酰基氯化合物反应以制备双联苯基酰基氧化膦。

    POSITIONING DEVICE
    14.
    发明公开
    POSITIONING DEVICE 审中-公开

    公开(公告)号:US20240033865A1

    公开(公告)日:2024-02-01

    申请号:US17873614

    申请日:2022-07-26

    CPC classification number: B23Q1/009

    Abstract: A positioning device is provided, including: a base seat, including a plurality through holes and a slide groove; a clamping assembly, disposed within the slide groove, including a first clamping body and a second clamping body; an adjustment assembly, including a first driving rod, a second driving rod and at least one rotation rod, the first driving rod including a first thread section and a first bevel gear, the second driving rod including a second thread section and a second bevel gear, the first clamping body and the second clamping body are respectively screwed on the first thread section and the second thread section, each rotation rod including a third bevel gear, the third bevel gear respectively meshed with the first bevel gear and the second bevel gear.

    CENTERING VICE
    15.
    发明申请

    公开(公告)号:US20230114338A1

    公开(公告)日:2023-04-13

    申请号:US17891743

    申请日:2022-08-19

    Abstract: A centering vice is provided, including: a base, a clamp assembly and an adjusting assembly. The base includes a sliding groove extending in a first direction and a first abutting portion. The clamp assembly includes a first jaw portion and a second jaw portion. The adjusting assembly includes a threaded rod, a positioning member and two adjusting members. The threaded rod includes a first threaded segment, a second threaded segment and a positioning portion. The positioning member is immovably connected to the positioning portion and disposed between the two adjusting members, and the two adjusting members respectively have a second abutting portion abutted against the first abutting portion. The two adjusting members are movable relative to the base in a second direction lateral to the first direction to urge the positioning member to move in the first direction.

    Driving circuit for a sound outputting apparatus
    17.
    发明授权
    Driving circuit for a sound outputting apparatus 失效
    声音输出装置的驱动电路

    公开(公告)号:US08660276B2

    公开(公告)日:2014-02-25

    申请号:US13309397

    申请日:2011-12-01

    CPC classification number: H04R3/00

    Abstract: A driving circuit for a sound outputting apparatus includes a H-bridge and a charge pump established by six switches for driving two types of loudspeakers, respectively. The six switches include two common switches to be configured in the H-bridge and the charge pump, thereby reducing the costs and circuit area of the driving circuit.

    Abstract translation: 用于声音输出装置的驱动电路包括分别由用于驱动两种扬声器的六个开关建立的H桥和电荷泵。 六个开关包括在H桥和电荷泵中配置的两个公共开关,从而降低驱动电路的成本和电路面积。

    Vise jaw
    18.
    发明授权
    Vise jaw 有权

    公开(公告)号:US11305403B2

    公开(公告)日:2022-04-19

    申请号:US16554358

    申请日:2019-08-28

    Abstract: A vise jaw is provided, including: a first jaw, including a slide groove and at least one locking portion, each locking portion including a receiving room, a threaded hole and a through hole, the receiving room, the threaded hole and the through hole respectively communicated with each other; a second jaw, having a slide protrusion slidably disposed within the slide groove, the slide protrusion having a lateral face facing the through hole; at least one fastening assembly, each fastening assembly including a screw member, an abutting member and at least one elastic member, the screw member screwed into the threaded hole, the abutting member adjustably disposed within the receiving room, the abutting member including a large diameter section and a small diameter section which are arranged along a first direction, the small diameter section disposed through the through hole and extending into the slide groove.

    Non-textual security using portraits
    20.
    发明授权
    Non-textual security using portraits 有权
    非文字安全性使用肖像

    公开(公告)号:US09075981B2

    公开(公告)日:2015-07-07

    申请号:US13027276

    申请日:2011-02-15

    CPC classification number: G06F21/36 H04L63/08

    Abstract: A user is authenticated using portraits of known contacts. During a challenge-response process, a collection of portraits are presented, some known to an authenticated user and some randomly selected. Responsive to correctly identifying the known portraits, the user is granted access to a system.

    Abstract translation: 使用已知联系人的肖像对用户进行身份验证。 在挑战响应过程中,呈现了一组肖像,一些被认证的用户已知,一些随机选择。 响应于正确识别已知的肖像,用户被授予访问系统的权限。

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