公开(公告)号：US20080280204A1

公开(公告)日：2008-11-13

申请号：US11632790

申请日：2005-07-09

Applicant: Roland Beckmann ,  Karl-Heinz Dulle ,  Peter Woltering ,  Randolf Kiefer ,  Frank Holthuis ,  Frank Funck ,  Wolfram Stolp ,  Hans-Joachim Kohnke ,  Joachim Helmke

Inventor： Roland Beckmann ,  Karl-Heinz Dulle ,  Peter Woltering ,  Randolf Kiefer ,  Frank Holthuis ,  Frank Funck ,  Wolfram Stolp ,  Hans-Joachim Kohnke ,  Joachim Helmke

IPC: H01M4/32 ,  H01B1/02 ,  H01M4/26

CPC classification number: C25B11/041 ,  H01M4/32 ,  H01M4/485 ,  H01M4/52 ,  H01M4/8817 ,  H01M4/8882 ,  H01M4/9016

Abstract: The invention relates to a method for producing electrically conducting nickel oxide surfaces made of nickel-containing material. According to said method, the nickel surface is first degreased and is then roughened for approximately ten minutes in a solution containing about one percent of hydrochloric acid, said process being accelerated by adding hydrogen peroxide solution, resulting in the electrolyte turning green. The nickel surface is briefly wetted, the nickel material is introduced into a solution of 3.5 molar lye to which about ten percent of hydrogen peroxide is added and is kept therein for ten minutes, and the resulting nickel hydroxide surface is dehydrated in a subsequent thermal process and is then further oxidized to obtain nickel oxide. The invention further relates to a conductive boundary layer that is produced according to said method, the electrodes therefrom, and the use thereof in chlorine-alkali electrolysis processes, in fuel cells and storage batteries.

Abstract translation: 本发明涉及一种用于制造由含镍材料制成的导电氧化镍表面的方法。 根据所述方法，镍表面首先脱脂，然后在含有约1％盐酸的溶液中粗糙化大约十分钟，所述方法通过加入过氧化氢溶液加速，导致电解质变绿。 镍表面短暂润湿，将镍材料引入3.5摩尔碱液的溶液中，向其中加入约10％的过氧化氢并保存在其中10分钟，并将所得氢氧化镍表面在随后的热处理中脱水 然后进一步氧化以获得氧化镍。 本发明还涉及根据所述方法制备的导电边界层，其电极及其在氯碱电解过程中，在燃料电池和蓄电池中的应用。

公开(公告)号：US07351317B2

公开(公告)日：2008-04-01

申请号：US10531863

申请日：2003-10-16

Applicant: Karl Heinz Dulle ,  Peter Woltering ,  Frank Funck ,  Martin Wollny ,  Randolf Kiefer ,  Thomas Steinmetz ,  Kosmas Janowitz ,  Roland Beckmann ,  Torsten Dresel ,  Hans-Joachim Hartz

Inventor： Karl Heinz Dulle ,  Peter Woltering ,  Frank Funck ,  Martin Wollny ,  Randolf Kiefer ,  Thomas Steinmetz ,  Kosmas Janowitz ,  Roland Beckmann ,  Torsten Dresel ,  Hans-Joachim Hartz

IPC: C25B9/08

CPC classification number: C25B9/08 ,  C25B9/18 ,  C25B15/08

Abstract: The invention relates to an electrolysis device for halogen gas production from an aqueous alkali halide solution in several plate-type electrolysis cells stacked and arranged side by side, with electrical contacts, each of the cells with a housing consisting of two half-shells made of electrically conductive material, said housing being equipped with devices for feeding electrolytic current and the electrolysis plant reactants and devices for discharging electrolytic current and discharging the electrolysis products, with anodic electrode, cathodic electrode and a membrane arranged therebetween, built-in components being fitted in at least one of the two half-shells and permitting a defined increase in the liquid level and thus minimizing the remaining gas volume accordingly.The built-in components are arranged in such a manner that they form an internal trough parallel to the said membrane and arranged horizontally, an interspace thus being provided between the trough and the membrane and an interspace between the trough and the electrolysis chamber, a part of which is located above the membrane, said trough having at least one opening communicating with the interspace between said trough and the upper side of the electrolytic chamber, and at least one outlet.

Abstract translation: 本发明涉及一种电解装置，用于在多个板式电解池中碱金属卤化物水溶液生产卤素气体，并排布置并具有电接触，每个电池具有由两个半壳制成的壳体 导电材料，所述壳体配备有用于供给电解电流的装置和电解装置反应物以及用于排出电解电流并排出电解产物的装置，阳极电极，阴极电极和布置在其间的膜，内置组件安装在 两个半壳中的至少一个，并允许限定的液面增加，从而相应地使剩余气体体积最小化。 内置组件以这样的方式排列，使得它们形成平行于所述膜并且水平布置的内部槽，因此设置在槽和膜之间的间隙以及槽和电解室之间的间隙，部分 所述槽具有与所述槽和所述电解室的上侧之间的间隙连通的至少一个开口，以及至少一个出口。

公开(公告)号：US20060006062A1

公开(公告)日：2006-01-12

申请号：US10531863

申请日：2003-10-16

Applicant: Karl-Heinz Dulle ,  Peter Woltering ,  Frank Funck ,  Martin Wollny ,  Randolf Kiefer ,  Thomas Steinmetz ,  Kosmas Janowitz ,  Roland Beckmann ,  Torsten Dresel ,  Hans-Joachim Hartz

Inventor： Karl-Heinz Dulle ,  Peter Woltering ,  Frank Funck ,  Martin Wollny ,  Randolf Kiefer ,  Thomas Steinmetz ,  Kosmas Janowitz ,  Roland Beckmann ,  Torsten Dresel ,  Hans-Joachim Hartz

IPC: C25B1/24

CPC classification number: C25B9/08 ,  C25B9/18 ,  C25B15/08

Abstract: The invention relates to an electrolysis device for halogen gas production from an aqueous alkali halide solution in several plate-type electrolysis cells stacked and arranged side by side, with electrical contacts, each of the cells with a housing consisting of two half-shells made of electrically conductive material, said housing being equipped with devices for feeding electrolytic current and the electrolysis plant reactants and devices for discharging electrolytic current and discharging the electrolysis products, with anodic electrode, cathodic electrode and a membrane arranged therebetween, built-in components being fitted in at least one of the two half-shells and permitting a defined increase in the liquid level and thus minimising the remaining gas volume accordingly. The built-in components are arranged in such a manner that they form an internal trough parallel to the said membrane and arranged horizontally, an interspace thus being provided between the trough and the membrane and an interspace between the trough and the electrolysis chamber, a part of which is located above the membrane, said trough having at least one opening communicating with the interspace between said trough and the upper side of the electrolytic chamber, and at least one outlet.

Abstract translation: 本发明涉及一种电解装置，用于在多个板式电解池中碱金属卤化物水溶液生产卤素气体，并排布置并具有电接触，每个电池具有由两个半壳制成的壳体 导电材料，所述壳体配备有用于供给电解电流的装置和电解装置反应物以及用于排出电解电流并排出电解产物的装置，阳极电极，阴极电极和布置在其间的膜，内置组件安装在 两个半壳中的至少一个，并允许限定的液面增加，从而相应地使剩余气体体积最小化。 内置组件以这样的方式排列，使得它们形成平行于所述膜并且水平布置的内部槽，因此设置在槽和膜之间的间隙以及槽和电解室之间的间隙，部分 所述槽具有与所述槽和所述电解室的上侧之间的间隙连通的至少一个开口，以及至少一个出口。