公开(公告)号：US5663422A

公开(公告)日：1997-09-02

申请号：US609698

申请日：1996-03-01

Applicant: Steven Thomas Perri ,  Stephen Neal Falling

Inventor： Steven Thomas Perri ,  Stephen Neal Falling

IPC: B01J31/16 ,  C07B61/00 ,  C07C67/26 ,  C07C69/16 ,  C07C69/28

CPC classification number: C07C67/26 ,  Y02P20/582

Abstract: A process for the preparation of a 1,2-diacetoxy ester comprises acetylation of an epoxide with an acetic anhydride in the presence of a quaternary phosphonium acetate catalyst or its complex with acetic acid.

Abstract translation: 1,2-二乙酰氧基酯的制备方法包括在乙酸季鏻催化剂或其与​​乙酸的络合物存在下，用乙酸酐乙酰化环氧化物。

公开(公告)号：US07538060B2

公开(公告)日：2009-05-26

申请号：US11674831

申请日：2007-02-14

Applicant: Scott Donald Barnicki ,  Bruce LeRoy Gustafson ,  Zhufang Liu ,  Steven Thomas Perri ,  Paul Randolph Worsham

Inventor： Scott Donald Barnicki ,  Bruce LeRoy Gustafson ,  Zhufang Liu ,  Steven Thomas Perri ,  Paul Randolph Worsham

IPC: B01J35/00 ,  B01J37/00 ,  C07C29/132 ,  C07C29/149

CPC classification number: C07C29/149 ,  B01J23/868 ,  B01J23/8993 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/03 ,  C07C29/157 ,  C07C2601/14 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/276 ,  C07C31/04

Abstract: Disclosed are catalysts comprising copper chromite, palladium and lanthanum having hydrogenation activity. The combination of copper chromite with palladium and lanthanum enhances catalyst activity more than the presence of either palladium alone or palladium in combination with alkali or alkaline earth metals. The catalysts are useful for the preparation of methanol from carbon monoxide and hydrogen and for the hydrogenation of carbonyl compounds such as, for example, aldehydes, ketones, and esters, to their corresponding alcohols. The catalysts may be used for the preparation of cyclohexanedimethanols from dialkyl cyclohexanedicarboxylates or of ethylene glycol from alkyl glycolates.

Abstract translation: 公开了包含具有氢化活性的亚铬酸铜，钯和镧的催化剂。 亚铬酸铜与钯和镧的组合比单独的钯或钯与碱金属或碱土金属组合的存在提高了催化剂活性。 催化剂可用于从一氧化碳和氢气制备甲醇，并将羰基化合物（例如醛，酮和酯）氢化成其相应的醇。 催化剂可用于从环己烷二羧酸二烷基酯或乙二醇由烷基乙醇酸制备环己烷二甲醇。

公开(公告)号：US07524994B2

公开(公告)日：2009-04-28

申请号：US11947941

申请日：2007-11-30

Applicant: Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha, Jr. ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

Inventor： Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha, Jr. ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

IPC: C07C35/04 ,  C07C31/18 ,  C07C29/143

CPC classification number: C07C29/145 ,  C07B2200/09 ,  C07C45/72 ,  C07C45/89 ,  C07C45/90 ,  C07C49/88 ,  C07C2601/04 ,  C07C49/39 ,  C07C35/045

Abstract: The present disclosure relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of a 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of an iridium-promoted cobalt-based catalyst.

Abstract translation: 本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。 在一个实施方案中，本发明涉及在存在下通过氢化2,2,4,4-四烷基环丁烷-1,3-二酮制备2,2,4,4-四烷基环丁烷-1,3-二醇 的铱促进的钴基催化剂。

公开(公告)号：US20080132737A1

公开(公告)日：2008-06-05

申请号：US11947941

申请日：2007-11-30

Applicant: Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

Inventor： Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

IPC: C07C35/04

CPC classification number: C07C29/145 ,  C07B2200/09 ,  C07C45/72 ,  C07C45/89 ,  C07C45/90 ,  C07C49/88 ,  C07C2601/04 ,  C07C49/39 ,  C07C35/045

Abstract: The present disclosure relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of a 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of a 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of an iridium-promoted cobalt-based catalyst.

Abstract translation: 本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。 在一个实施方案中，本发明涉及在存在下通过氢化2,2,4,4-四烷基环丁烷-1,3-二酮制备2,2,4,4-四烷基环丁烷-1,3-二醇 的铱促进的钴基催化剂。

公开(公告)号：US07582804B2

公开(公告)日：2009-09-01

申请号：US11948000

申请日：2007-11-30

Applicant: Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha, Jr. ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

Inventor： Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha, Jr. ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

IPC: C07C35/04

CPC classification number: C07C29/145 ,  C07B2200/09 ,  C07C45/72 ,  C07C45/89 ,  C07C45/90 ,  C07C49/88 ,  C07C2601/04 ,  C07C49/39 ,  C07C35/045

Abstract: The present disclosure relates to the production of 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of a promoted copper-based catalyst.

Abstract translation: 本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。 在一个实施方案中，本发明涉及通过2,2,4,4-四烷基环丁烷-1,3-二酮在存在下氢化制备2,2,4,4-四烷基环丁烷-1,3-二醇 促进铜基催化剂。

公开(公告)号：US20080194397A1

公开(公告)日：2008-08-14

申请号：US11674831

申请日：2007-02-14

Applicant: SCOTT DONALD BARNICKI ,  BRUCE LEROY GUSTAFSON ,  ZHUFANG LIU ,  STEVEN THOMAS PERRI ,  PAUL RANDOLPH WORSHAM

Inventor： SCOTT DONALD BARNICKI ,  BRUCE LEROY GUSTAFSON ,  ZHUFANG LIU ,  STEVEN THOMAS PERRI ,  PAUL RANDOLPH WORSHAM

IPC: B01J31/00

CPC classification number: C07C29/149 ,  B01J23/868 ,  B01J23/8993 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/03 ,  C07C29/157 ,  C07C2601/14 ,  Y02P20/52 ,  C07C31/202 ,  C07C31/276 ,  C07C31/04

Abstract: Disclosed are catalysts comprising copper chromite, palladium and lanthanum having hydrogenation activity. The combination of copper chromite with palladium and lanthanum enhances catalyst activity more than the presence of either palladium alone or palladium in combination with alkali or alkaline earth metals. The catalysts are useful for the preparation of methanol from carbon monoxide and hydrogen and for the hydrogenation of carbonyl compounds such as, for example, aldehydes, ketones, and esters, to their corresponding alcohols. The catalysts may be used for the preparation of cyclohexanedimethanols from dialkyl cyclohexanedicarboxylates or of ethylene glycol from alkyl glycolates.

Abstract translation: 公开了包含具有氢化活性的亚铬酸铜，钯和镧的催化剂。 亚铬酸铜与钯和镧的组合比单独的钯或钯与碱金属或碱土金属组合的存在提高了催化剂活性。 催化剂可用于从一氧化碳和氢气制备甲醇，并将羰基化合物（例如醛，酮和酯）氢化成其相应的醇。 催化剂可用于从环己烷二羧酸二烷基酯或乙二醇由烷基乙醇酸制备环己烷二甲醇。

公开(公告)号：US20080132742A1

公开(公告)日：2008-06-05

申请号：US11948000

申请日：2007-11-30

Applicant: Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

Inventor： Jennifer Ellen McCusker-Orth ,  Jerome Leonard Stavinoha ,  Anthony Dominick Messina ,  Steven Thomas Perri ,  Zhufang Liu ,  Philip Conrad Heidt ,  Brent Alan Tennant

IPC: C07C29/141

CPC classification number: C07C29/145 ,  C07B2200/09 ,  C07C45/72 ,  C07C45/89 ,  C07C45/90 ,  C07C49/88 ,  C07C2601/04 ,  C07C49/39 ,  C07C35/045

Abstract: The present disclosure relates to the production of 2,2,4,4-tetraalkylcyclobutane-1,3-diol. In one embodiment, the present invention relates to the production of 2,2,4,4-tetraalkylcyclobutane-1,3-diol by hydrogenation of 2,2,4,4-tetraalkylcyclobutane-1,3-dione in the presence of a promoted copper-based catalyst.

Abstract translation: 本公开涉及制备2,2,4,4-四烷基环丁烷-1,3-二醇。 在一个实施方案中，本发明涉及通过2,2,4,4-四烷基环丁烷-1,3-二酮在存在下氢化制备2,2,4,4-四烷基环丁烷-1,3-二醇 促进铜基催化剂。

公开(公告)号：US06864376B2

公开(公告)日：2005-03-08

申请号：US10036912

申请日：2001-12-21

Applicant: Steven Thomas Perri ,  Michael Roy Cushman ,  Jeffery Earl Grant Powell ,  Brendan William Boyd ,  Bhaskar Krishna Arumugam ,  Nick Allen Collins

Inventor： Steven Thomas Perri ,  Michael Roy Cushman ,  Jeffery Earl Grant Powell ,  Brendan William Boyd ,  Bhaskar Krishna Arumugam ,  Nick Allen Collins

IPC: C07B61/00 ,  C07D307/62

CPC classification number: C07D307/62 ,  Y02P20/582

Abstract: The present invention comprises the use of sulfite additives to reduce discoloration of L-ascorbic acid produced from acid or aqueous solutions of 2-keto-L-gulonic acid. In one aspect, the present invention comprises a continuous process for producing L-ascorbic acid from an aqueous solution of 2-keto-L-gulonic acid. The use of sulfite additives reduces product stream color and improves product recovery by binding to high molecular weight reaction by-products. In a continuous process, the reaction stream is separated from residual sulfite and sulfite-bound by-products to produce a product stream enriched in aqueous ascorbic acid for recovery, and an enriched 2-keto-L-gulonic acid stream which is recycled to the reactor. The in situ use of sulfite additives during the reaction increases the overall yield of L-ascorbic acid, with no loss in selectivity of the synthesis.

Abstract translation: 本发明包括使用亚硫酸盐添加剂来减少由2-酮-L-古洛糖酸的酸或水溶液产生的L-抗坏血酸的变色。 一方面，本发明包括从2-酮-L-古洛糖酸的水溶液中生产L-抗坏血酸的连续方法。 使用亚硫酸盐添加剂可降低产品流颜色，并通过与高分子量反应副产物结合而提高产品回收率。 在连续方法中，将反应物流与残余的亚硫酸盐和亚硫酸盐结合的副产物分离以产生富含水溶性抗坏血酸以回收的产物流，以及富含2-酮-L-古洛糖酸流，将其再循环至 反应堆。 反应中亚硫酸盐添加剂的原位使用增加了L-抗坏血酸的总产率，合成的选择性没有损失。