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    Transition metal complexes, ligands, polymerization catalysts for olefins, and process for production of olefin polymers
    11.
    发明授权
    Transition metal complexes, ligands, polymerization catalysts for olefins, and process for production of olefin polymers 失效
    过渡金属络合物，配体，烯烃聚合催化剂和烯烃聚合物生产方法

    公开(公告)号：US07141690B2

    公开(公告)日：2006-11-28

    申请号：US10503252

    申请日：2003-02-06

    申请人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    发明人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    IPC分类号： C08F4/64 ,  C07F7/28 ,  C07F7/00

    CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex represented by the formula (1): wherein M is a Group 4 transition metal, A is a Group 16 element, B is a Group 14 element, n is an integer of 0 or 1, R1, R2, R3 and R4 may be the same or different and each independently denotes a substituent selected from the group consisting of the groups (I) and (II): group (I): hydrogen, alkyl and so on, group (II): alkoxy, alkylthio and so on, provided that at least one of R1, R2, R3 and R4 is a substituent selected from group (II); R5, R6, R7, R8, R9, R10, X1 and X2 may be the same or different and are each hydrogen, halogen, alkyd or the like; and a catalyst for olefin polymerization comprising said complex, an organoaluminum compound and a boron compound are provided.

    摘要翻译： 由式（1）表示的过渡金属络合物：其中M是第4族过渡金属，A是第16族元素，B是第14族元素，n是0或1的整数，R 1， R 2，R 3，R 4和R 4可以相同或不同，并且各自独立地表示选自以下的取代基： 的基团（I）和（II）：基团（I）：氢，烷基等，基团（II）：烷氧基，烷硫基等，条件是R 1， R 2，R 3和R 4是选自（II）组的取代基。 R 5，R 6，R 7，R 8，R 9， R 10，X 1和X 2可以相同或不同，各自为氢，卤素，醇酸等; 并提供包含所述络合物，有机铝化合物和硼化合物的烯烃聚合催化剂。

    ETHYLENIC POLYMER
    13.
    发明申请
    ETHYLENIC POLYMER 有权
    乙烯聚合物

    公开(公告)号：US20130005931A1

    公开(公告)日：2013-01-03

    申请号：US13498075

    申请日：2010-09-30

    申请人： Yasutoyo Kawashima ,  Takahiro Hino ,  Taichi Senda

    发明人： Yasutoyo Kawashima ,  Takahiro Hino ,  Taichi Senda

    IPC分类号： C08F110/02

    CPC分类号： B01J31/2295 ,  B01J31/143 ,  B01J2231/20 ,  B01J2231/32 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2/34 ,  C07C2531/14 ,  C07C2531/22 ,  C07F7/28 ,  C07F17/00 ,  C07F19/00 ,  C08F10/00 ,  Y02P20/52 ,  C07C11/107 ,  C08F4/6592

    摘要： Disclosed is an ethylenic polymer having a long characteristic relaxation time. The ethylenic polymer satisfies the following requirements: (a) the ethylenic polymer is a non-crosslinked ethylenic polymer; (b) the number of long-chain branches (LCB) per 1000 carbon atoms is 0.1-1.5 inclusive; (c) the intrinsic viscosity [η] is 1.0-3.0 dl/g inclusive; and (d) the ratio (G′/G″) of the storage modulus (G′) to the loss modulus (G″), determined by dynamic viscoelasticity measurement at 190° C. and at an angular frequency of 0.1 rad/sec is 0.8 or more and 4.0 or less.

    摘要翻译： 公开了具有长特征弛豫时间的乙烯类聚合物。 乙烯类聚合物满足以下要求：（a）乙烯类聚合物是非交联乙烯类聚合物; （b）每1000个碳原子的长链支链数（LCB）为0.1-1.5（含）; （c）特性粘度[... eegr]为1.0-3.0 dl / g（含）; 和（d）通过在190℃和0.1弧度/秒的角频率下的动态粘弹性测量确定的储能模量（G'）与损耗模量（G“）的比率（G'/ G”） 为0.8以上且4.0以​​下。

    TRANSITION METAL ION COMPLEX, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING POLYMER
    14.
    发明申请
    TRANSITION METAL ION COMPLEX, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING POLYMER 审中-公开
    过渡金属离子复合物，其制备方法和制备聚合物的方法

    公开(公告)号：US20120172552A1

    公开(公告)日：2012-07-05

    申请号：US13418505

    申请日：2012-03-13

    申请人： Taichi SENDA ,  Hidenori Hanaoka

    发明人： Taichi SENDA ,  Hidenori Hanaoka

    IPC分类号： C08F4/76 ,  C08F110/00 ,  C08F120/10 ,  C07F7/28

    CPC分类号： C07F17/00 ,  C08F4/65908 ,  C08F10/00 ,  C08F110/14 ,  C08F210/14 ,  C08F232/00 ,  C08F2420/02 ,  C08F4/6592 ,  C08F2500/03 ,  C08F212/08 ,  C08F2500/25

    摘要： A transition metal ion complex represented by formula (1): wherein M represents a group-IV element of the periodic table, A represents a group-XIV element of the periodic table, D represents a group-XVI element of the periodic table, Cp represents a group having a cyclopentadienyl type anion skeleton, E represents a counter anion, R1-R6 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, a silyl group substituted with a hydrocarbon, an alkoxy group, an aryloxy group, an aralkyl oxy group or an amino group substituted with hydrocarbon, and X1 represents an alkyl group, an aryl group or an aralkyl group.

    摘要翻译： 由式（1）表示的过渡金属离子络合物：其中M表示周期表的IV族元素，A表示周期表的基团-XIV元素，D表示周期表的基团-XVI元素，Cp 表示具有环戊二烯基型阴离子骨架的基团，E表示抗衡阴离子，R1-R6表示氢原子，卤素原子，烷基，芳基，芳烷基，被烃取代的甲硅烷基，烷氧基 基团，芳氧基，芳烷基氧基或被烃取代的氨基，X1表示烷基，芳基或芳烷基。

    Process for producing metallocene compound
    16.
    发明授权
    Process for producing metallocene compound 失效
    金属茂化合物的制备方法

    公开(公告)号：US07652159B2

    公开(公告)日：2010-01-26

    申请号：US11660933

    申请日：2005-07-11

    申请人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

    发明人： Taichi Senda ,  Noriyuki Hida ,  Hidenori Hanaoka

    IPC分类号： C07F7/00

    CPC分类号： C07F17/00 ,  C08F10/00 ,  C08F2420/02 ,  C08F4/6592

    摘要： The invention provides a process for producing a metallocene compound of formula (3) wherein R1 to R9 independently denote a hydrogen atom, a halogen atom, an alkyl, or the like; R10 denotes a halogen atom, an alkyl, an alkoxy, or the like; X5 and X6 independently denote a hydrogen atom, a halogen atom, or the like; and M denotes a transition metal atom of Group 4 of the Periodic Table, which process is characterized by reacting a silicon-substituted cyclopentadiene compound of formula (1) wherein R1 to R10 independently denote the same as described above; R11 denotes a hydrocarbon group or a tri-substituted silyl; and R12 to R14 independently denote a halogen atom or a hydrocarbon group, with a transition metal compound of the following formula (2) wherein M denotes the same as described above; X1, X2, X3, and X4 independently denotes a hydrogen atom, a halogen atom, an alkyl, or the like, in a solvent containing an aromatic hydrocarbon.

    摘要翻译： 本发明提供一种制备式（3）的茂金属化合物的方法，其中R 1至R 9独立地表示氢原子，卤素原子，烷基等; R 10表示卤素原子，烷基，烷氧基等; X 5和X 6独立地表示氢原子，卤素原子等; 并且M表示周期表第4族的过渡金属原子，该方法的特征在于使式（1）的硅取代的环戊二烯化合物（其中R 1至R 10独立地表示与上述相同的基团） R 11表示烃基或三取代甲硅烷基; 和R 12至R 14独立地表示卤素原子或烃基，与下式（2）的过渡金属化合物，其中M表示与上述相同的基团; X 1，X 2，X 3和X 4独立地表示在含有芳香族烃的溶剂中的氢原子，卤素原子，烷基等。

    Transition Metal Complex, Process For Producing Said Transition Metal Complex, Substituent-Carrying Fluorene Compound, Process For Producing Said Fluorene Compound, Catalyst Component For Olefin Polymerization, Catalyst For Olefin Polymerization, and Process For Producing Olefin Polymer
    17.
    发明申请
    Transition Metal Complex, Process For Producing Said Transition Metal Complex, Substituent-Carrying Fluorene Compound, Process For Producing Said Fluorene Compound, Catalyst Component For Olefin Polymerization, Catalyst For Olefin Polymerization, and Process For Producing Olefin Polymer 失效

    公开(公告)号：US20080161514A1

    公开(公告)日：2008-07-03

    申请号：US11795967

    申请日：2006-01-24

    申请人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

    发明人： Taichi Senda ,  Hidenori Hanaoka ,  Shinya Nakahara ,  Kenji Sogoh

    IPC分类号： C07F7/08 ,  C07F7/28 ,  C07F7/30 ,  C08F10/00 ,  B01J31/22

    CPC分类号： C08F10/00 ,  B01J31/2295 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/02 ,  C08F210/16 ,  C08F2420/02 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/659 ,  C08F4/6592 ,  C08F232/00 ,  C08F2500/17 ,  C08F2500/25 ,  C08F210/14

    摘要： A transition metal complex represented by the general formula [1]; a catalyst component for olefin polymerization comprising said transition metal complex; a catalyst for olefin polymerization using said transition metal complex as a catalyst component for olefin polymerization; a process for producing an olefin polymer comprising the step of polymerizing an olefin in the presence of said catalyst for olefin polymerization; a substituent-carrying fluorene compound; a process for producing said substituent-carrying fluorene compound; and a process for producing said transition metal complex using said substituent-carrying fluorene compound: wherein M is the group 4 transition metal atom in the periodic table of elements; A is the group 16 atom therein; J is the group 14 atom therein; R1, R2, R3, R4, R5, R6, X1 and X2 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; R1 and R2, R2 and R3, and R3 and R4 may be linked to each other, respectively, to form respective rings; R5 and R6 may be linked to each other to form a ring; R7, R8, R9 and R10 are independently of one another (1) a substituent selected from the group consisting of (1-1) an alkyl group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-2) an aralkyl group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, (1-3) an aryl group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (1-4) a substituent-carrying silyl group having 1 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-5) a disubstituent-carrying amino group having 2 to 20 carbon atoms, which substituent is a hydrocarbyl group, and said hydrocarbyl group may be substituted by a halogen atom, (1-6) an alkoxy group having 1 to 20 carbon atoms, which may be substituted by a halogen atom, (1-7) an aralkyloxy group having 7 to 20 carbon atoms, which may be substituted by a halogen atom, and (1-8) an aryloxy group having 6 to 20 carbon atoms, which may be substituted by a halogen atom, (2) a halogen atom or (3) a hydrogen atom; at least two of R7, R8, R9 and R10 are the substituent selected from the above-mentioned group or a halogen atom; R7 and R8 may be linked to each other to form a ring; and R9 and R10 may be linked to each other to form a ring.

    Transition metal complexes, ligands, catalysts for olefin polymerization, and process for production of olefin polymers
    18.
    发明授权
    Transition metal complexes, ligands, catalysts for olefin polymerization, and process for production of olefin polymers 失效
    过渡金属络合物，配体，烯烃聚合用催化剂和烯烃聚合物生产方法

    公开(公告)号：US07241927B2

    公开(公告)日：2007-07-10

    申请号：US11324260

    申请日：2006-01-04

    申请人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    发明人： Hidenori Hanaoka ,  Taichi Senda ,  Eiji Yoshikawa ,  Satoshi Kobayashi

    IPC分类号： C07C43/20 ,  C07C43/205 ,  C07C43/215

    CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/02 ,  C08F210/16 ,  Y10S526/943 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/10

    摘要： A transition metal complex represented by the formula (1): wherein M is a Group 4 transition metal, A is a Group 16 element, B is a Group 14 element, n is an integer of 0 or 1, R1, R2, R3 and R4 may be the same or different and each independently denotes a substituent selected from the group consisting of the groups (I) and (II): group (I): hydrogen, alkyl and so on, group (II): alkoxy, alkylthio and so on, provided that at least one of R1, R2, R3 and R4 is a substituent selected from group (II); R5, R6, R7, R8, R9, R10, X1 and X2 may be the same or different and are each hydrogen, halogen, alkyl or the like; and a catalyst for olefin polymerization comprising said complex, an organoaluminum compound and a boron compound are provided.

    摘要翻译： 由式（1）表示的过渡金属络合物：其中M是第4族过渡金属，A是第16族元素，B是第14族元素，n是0或1的整数，R 1， R 2，R 3，R 4和R 4可以相同或不同，并且各自独立地表示选自以下的取代基： 的基团（I）和（II）：基团（I）：氢，烷基等，基团（II）：烷氧基，烷硫基等，条件是R 1， R 2，R 3和R 4是选自（II）组的取代基。 R 5，R 6，R 7，R 8，R 9， R 10，X 1和X 2可以相同或不同，各自为氢，卤素，烷基等; 并提供包含所述络合物，有机铝化合物和硼化合物的烯烃聚合催化剂。

    METHOD FOR PRODUCING TRANSITION METAL COMPLEX, CATALYST FOR TRIMERIZATION, METHOD FOR PRODUCING 1-HEXENE, METHOD FOR PRODUCING SUBSTITUTED CYCLOPENTADIENE COMPOUND (2)
    19.
    发明申请
    METHOD FOR PRODUCING TRANSITION METAL COMPLEX, CATALYST FOR TRIMERIZATION, METHOD FOR PRODUCING 1-HEXENE, METHOD FOR PRODUCING SUBSTITUTED CYCLOPENTADIENE COMPOUND (2) 有权
    用于生产过渡金属络合物的方法，用于三聚物的催化剂，用于生产1-HEXENE的方法，用于生产取代的环戊二烯化合物的方法（2）

    公开(公告)号：US20140018565A1

    公开(公告)日：2014-01-16

    申请号：US14007692

    申请日：2012-03-29

    申请人： Taichi Senda ,  Masaya Tanimoto

    发明人： Taichi Senda ,  Masaya Tanimoto

    IPC分类号： C07C2/34 ,  B01J31/22

    CPC分类号： C07C2/34 ,  B01J31/2295 ,  B01J2231/20 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  C07C2531/14 ,  C07C2531/22 ,  C07F17/00 ,  C07C11/107

    摘要： A silicon-bridged Cp-Ar transition metal complex serves as a catalytic component capable of efficiently and highly selectively producing 1-hexene through trimerization reaction of ethylene. The transition metal complex is represented by formula (1): wherein M represents a transition metal atom of Group 4 of the Periodic Table of the Elements; X1, X2, X3, R1, R2, R3, R4, R5, R6, R7, R8, and R9 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, an aryloxy group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, and an aralkyloxy group having 7 to 20 carbon atoms, and wherein each of the groups may have a halogen atom as a substituent.

    摘要翻译： 硅桥接的Cp-Ar过渡金属络合物用作能够通过乙烯的三聚反应有效和高选择性地生产1-己烯的催化组分。 过渡金属络合物由式（1）表示：其中M表示元素周期表第4族的过渡金属原子; X1，X2，X3，R1，R2，R3，R4，R5，R6，R7，R8和R9各自独立地表示氢原子，卤素原子，碳原子数1〜20的烷基， 20个碳原子，碳原子数6〜20的芳基，碳原子数6〜20的芳氧基，碳原子数7〜20的芳烷基和碳原子数7〜20的芳烷氧基， 该基团可以具有卤素原子作为取代基。