PREPARATION OF ALKALINE EARTH METAL-COMPLEXED METAL BISAMIDES FROM METAL MONOAMIDES
    14.
    发明申请
    PREPARATION OF ALKALINE EARTH METAL-COMPLEXED METAL BISAMIDES FROM METAL MONOAMIDES 有权
    从金属单体制备碱金属金属复合金属异硬脂酸

    公开(公告)号:US20150368277A1

    公开(公告)日:2015-12-24

    申请号:US14766160

    申请日:2014-02-11

    CPC classification number: C07F3/06 C07D239/30 C07F3/02

    Abstract: The present invention relates to a process for preparing alkaline earth metal-complexed metal bisamides of the formula (I) from metal monoamides of the formula (II). The present invention further relates to a process for preparing alkaline earth metal monoamides of the formula (II-AE), to novel LiCl-free alkaline earth metal monoamides of the formula (II-AE-L), and to the use of these alkaline earth metal monoamides for metallation of aromatics, heteroaromatics, alkenes, alkynes and other organic compounds having activated C—H bonds.

    Abstract translation: 本发明涉及由式(II)的金属单酰胺制备式(I)的碱土金属络合金属双酰胺的方法。 本发明还涉及制备式(II-AE)的碱土金属单酰胺,式(II-AE-L)的新型无LiCl的碱土金属单酰胺的方法,以及这些碱 用于芳族化合物,杂芳族化合物,烯烃,炔烃和其它具有活化C-H键的有机化合物的金属化的土金属单酰胺。

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