公开(公告)号：US20130102505A1

公开(公告)日：2013-04-25

申请号：US13659285

申请日：2012-10-24

Applicant: Basf SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明进一步涉及其使用和制备以及包含该混合物的含水表面活性剂制剂，以及通过Winsor III型微乳液淹水制备矿物油的方法，其中将表面活性剂水溶液注入矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。

公开(公告)号：US10961432B2

公开(公告)日：2021-03-30

申请号：US16296904

申请日：2019-03-08

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Sebastian Alexander Weiße ,  Hans-Christian Raths ,  Jack Tinsley ,  Marcel Kienle

IPC: C09K8/584 ,  B01F17/00 ,  C09K8/60 ,  E21B43/20 ,  C09K8/524 ,  C09K8/28 ,  C09K8/86

Abstract: The present invention relates to a method for producing mineral oil from underground mineral oil deposits, in which an aqueous formulation comprising at least a mixture of alkyl ether carboxylate and corresponding alkyl ether alcohol, where the alkyl ether carboxylate has been prepared from the alkyl ether alcohol and the molar ratio in the mixture of alkyl ether carboxylate:alkyl ether alcohol is from 51:49 to 92:8, is injected through at least one injection well into a mineral oil deposit, where the deposit has a deposit temperature of 55° C. to 150° C., a crude oil having more than 20° API and a deposit water having more than 100 ppm of divalent cations, and crude oil is withdrawn through at least one production well from the deposit. The invention further relates to the preparation of the mixture and to a concentrate comprising the mixture.

公开(公告)号：US10266751B2

公开(公告)日：2019-04-23

申请号：US15527249

申请日：2015-11-17

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Sebastian Alexander Weiβe ,  Hans-Christian Raths ,  Jack Tinsley ,  Marcel Kienle

IPC: E21B43/20 ,  C09K8/584 ,  B01F17/00 ,  C09K8/60 ,  C09K8/86 ,  C09K8/524

Abstract: The present invention relates to a method for producing mineral oil from underground mineral oil deposits, in which an aqueous formulation comprising at least a mixture of alkyl ether carboxylate and corresponding alkyl ether alcohol, where the alkyl ether carboxylate has been prepared from the alkyl ether alcohol and the molar ratio in the mixture of alkyl ether carboxylate:alkyl ether alcohol is from 51:49 to 92:8, is injected through at least one injection well into a mineral oil deposit, where the deposit has a deposit temperature of 55° C. to 150° C., a crude oil having more than 20° API and a deposit water having more than 100 ppm of divalent cations, and crude oil is withdrawn through at least one production well from the deposit. The invention further relates to the preparation of the mixture and to a concentrate comprising the mixture.

公开(公告)号：US09751905B2

公开(公告)日：2017-09-05

申请号：US14081027

申请日：2013-11-15

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Vogel

IPC: C09K8/584 ,  C07F9/46 ,  B01F17/00 ,  C07C305/06

CPC classification number: C07F9/46 ,  B01F17/0021 ,  C07C305/06 ,  C09K8/584

Abstract: A surfactant and a surfactant formulation comprising at least one ionic surfactant of the general formula R1—O-(D)n-(B)m-(A)l-XY−M+ where R1 is a linear or branched, saturated or unsaturated, aliphatic and/or aromatic hydrocarbon radical having 8 to 30 carbon atoms, A is ethyleneoxy, B is propyleneoxy, and D is butyleneoxy, l is from 0 to 99, m is from 0 to 99 and n is from 1 to 99, X is an alkyl or alkylene group having 0 to 10 carbon atoms, M+ is a cation, and Y− is selected from the group of sulfate groups, sulfonate groups, carboxylate groups and phosphate groups.

公开(公告)号：US09475977B2

公开(公告)日：2016-10-25

申请号：US13659285

申请日：2012-10-24

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type III microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

公开(公告)号：US20140116689A1

公开(公告)日：2014-05-01

申请号：US14060967

申请日：2013-10-23

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Jürgenson ,  Sophie Maitro-Vogel

IPC: C09K8/584 ,  E21B43/16

CPC classification number: C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least one surfactant of the general formula (I) R1O—(CH2CH(CH2OR2)O)p-(D)n-(B)m-(A)l-(X)k—Y−1/bMb+  (I) where R1, R2, p, D, n, B, m, A, l, X, k, Y−, b, Mb+ are each as defined in the claims and the description. The invention further relates to processes for mineral oil production by means of Winsor type III microemulsion flooding using a surfactant formulation comprising the surfactant mixture.

Abstract translation: 本发明涉及包含至少一种通式（I）的表面活性剂的表面活性剂混合物：R1O-（CH2CH（CH2OR2）O）p-（D）n-（B）m-（A）1-（X） -Y-1 / bMb +（I）其中R1，R2，p，D，n，B，m，A，l，X，k，Y-，b，Mb +各自如权利要求和说明书中所定义。 本发明还涉及使用包含表面活性剂混合物的表面活性剂制剂通过Winsor III型微乳液淹没进行矿物油生产的方法。

公开(公告)号：US20130098612A1

公开(公告)日：2013-04-25

申请号：US13659393

申请日：2012-10-24

Applicant: BASF SE

Inventor： Christian Bittner ,  Günter Oetter ,  Jack Tinsley ,  Christian Spindler ,  Gabriela Alvarez-Juergenson ,  Sophie Maitro-Vogel

IPC: C09K8/584

CPC classification number: C09K8/602 ,  C09K8/584

Abstract: The present invention relates to a surfactant mixture comprising at least three ionic surfactants which differ in terms of the hydrocarbyl moiety (R1)(R2)—CH—CH2— and are of the general formula (I) where R1, R2, A0, k, X, o, Y, a, b, M are each as defined in the description and the claims. The invention further relates to the use and preparation thereof, and to aqueous surfactant formulations comprising the mixtures, and to processes for producing mineral oil by means of Winsor type Ill microemulsion flooding, in which the aqueous surfactant formulation is injected into a mineral oil deposit through injection wells and crude oil is withdrawn from the deposit through production wells.

Abstract translation: 本发明涉及包含至少三种离子表面活性剂的表面活性剂混合物，它们在烃基部分（R 1）（R 2）-CH-CH 2 - 和通式（I）方面不同，其中R1，R2，A0，k ，X，o，Y，a，b，M各自如说明书和权利要求书中所定义。 本发明还涉及其使用和制备，以及包含该混合物的水性表面活性剂制剂，以及通过Winsor III型微乳液淹水生产矿物油的方法，其中将表面活性剂水溶液注入到矿物油沉积物中 注入井和原油通过生产井从沉积物中取出。