公开(公告)号：US10153087B2

公开(公告)日：2018-12-11

申请号：US15163595

申请日：2016-05-24

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li ,  Ian S. G. Kelly-Morgan

IPC: H01G4/14 ,  C07D471/22 ,  C09B5/62 ,  H01G4/005 ,  H01G4/32

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule. R1 are electron donor groups connected to Core1 and R1′ are electron acceptor groups connected to Core1, m is number of acceptor groups R1, m′ is a number of donor groups R′. The numbers m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, but both m and m′ are not both equal to 0. R2 is a substituent comprising one or more ionic groups connected to Core1 directly or via a connecting group; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is a self-assembling electro-conductive oligomer, a number n of the such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US20180033554A1

公开(公告)日：2018-02-01

申请号：US15710587

申请日：2017-09-20

Applicant: Capacitor Sciences Incorporated

Inventor： Yan Li ,  Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Samuel Hein

IPC: H01G4/18 ,  C08F20/18 ,  C08F20/34 ,  H01L49/02

CPC classification number: H01G4/18 ,  C08F20/18 ,  C08F20/34 ,  C08F20/36 ,  C08G73/024 ,  C08L33/02 ,  H01G9/04 ,  H01G9/07 ,  H01L28/40 ,  C08L77/00

Abstract: A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20170301477A1

公开(公告)日：2017-10-19

申请号：US15449587

申请日：2017-03-03

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G9/07 ,  C08F20/36 ,  C08G73/02 ,  H01G9/04

CPC classification number: H01G9/07 ,  C08F20/36 ,  C08G73/024 ,  H01G4/18 ,  H01G9/04

Abstract: A composite oligomeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a handle linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite oligomer material may be polymerized to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20170287638A1

公开(公告)日：2017-10-05

申请号：US15163595

申请日：2016-05-24

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li ,  Ian S.G. Kelly-Morgan

IPC: H01G4/14 ,  H01G4/005 ,  C07D471/22 ,  H01G4/32

CPC classification number: H01G4/14 ,  C07D471/22 ,  C09B5/008 ,  C09B5/62 ,  H01G4/005 ,  H01G4/18 ,  H01G4/32

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule. R1 are electron donor groups connected to Core1 and R1′ are electron acceptor groups connected to Core1, m is number of acceptor groups R1, m′ is a number of donor groups R′. The numbers m and m′ are equal to 0, 1, 2, 3, 4, 5 or 6, but both m and m′ are not both equal to 0. R2 is a substituent comprising one or more ionic groups connected to Core1 directly or via a connecting group; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is a self-assembling electro-conductive oligomer, a number n of the such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US10755857B2

公开(公告)日：2020-08-25

申请号：US16436269

申请日：2019-06-10

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Yan Li ,  Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Samuel Hein

IPC: H01G4/18 ,  C08F20/34 ,  C08F20/18 ,  H01L49/02 ,  C08F20/36 ,  C08G73/02 ,  C08L33/02 ,  H01G4/32 ,  H01G9/04 ,  H01G9/07

Abstract: A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20190139705A1

公开(公告)日：2019-05-09

申请号：US15982482

申请日：2018-05-17

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  H01G4/18 ,  H01G4/32 ,  C09B5/62 ,  C09K19/60 ,  C09B5/00 ,  C07D471/22 ,  C09B47/00 ,  C09B47/04

Abstract: An electro-polarizable compound has the following general formula: where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, which is tetrapirolic macro-cyclic fragment, R1 is an dopant group connected to Core1, m is number of R1 which is equal to 1, 2, 3 or 4, R2 is a substituent comprising one or more ionic groups, p is number of R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE containing the Core1 with at least one R1 has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, n is number of Core2 which is equal to 2, or 4, R3 is a substituent comprising one or more ionic groups, s is number of R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-polar resistive substituent, k is a number of R4 which is equal to 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US20190108944A1

公开(公告)日：2019-04-11

申请号：US16208953

申请日：2018-12-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li ,  Ian S.G. Kelly-Morgan

IPC: H01G4/14 ,  C09B5/00 ,  H01G4/18 ,  H01G4/32 ,  H01G4/005 ,  C07D471/22 ,  C09B5/62

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having a structural formula: Core1 is of two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule. R1 and R1′ are, electron donor and acceptor groups, respectively, m and m′ are the numbers of donor and acceptor groups, respectively and are equal to 0, 1, 2, 3, 4, 5 or 6 but are not both equal to 0. R2 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to Core1, p is a number of ionic groups R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer and n is a number of the electro-conductive oligomers equal to 0, 2, or 4. R3 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to Core2, s is a number of the ionic groups R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-conjugate cyclic or polycyclic resistive substituent providing solubility of the organic compound in a solvent and electrically insulating the column-like supramolecules from each other and connected to Core1 and/or to Core2, k is a number of substituents R4 which is equal to 1, 2, 3, 4, 5, 6, 7 or 8