公开(公告)号：US20170301467A1

公开(公告)日：2017-10-19

申请号：US15449524

申请日：2017-03-03

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Pavel Ivan Lazarev ,  Barry K. Sharp ,  Paul Furuta ,  Yan Li ,  Ian SG Kelly-Morgan ,  Matthew R. Robinson ,  Daniel Membreno

IPC: H01G4/18 ,  H02J7/00 ,  H01G4/38 ,  C08G73/02 ,  H01G4/01 ,  H01G4/008 ,  H01G4/002 ,  H01G4/32 ,  H02J7/34

CPC classification number: H01G4/186 ,  C08G73/0266 ,  H01G4/002 ,  H01G4/008 ,  H01G4/01 ,  H01G4/14 ,  H01G4/18 ,  H01G4/32 ,  H01G4/38 ,  H01G4/40 ,  H01L29/00 ,  H02J7/0068 ,  H02J7/345

Abstract: A capacitor includes a first electrode, a second electrode, and a dielectric layer of molecular material disposed between said first and second electrodes. The molecular material is described by the general formula: Dp-(Core)- Hq, where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.

公开(公告)号：US20170236641A1

公开(公告)日：2017-08-17

申请号：US15043186

申请日：2016-02-12

Applicant: Capacitor Sciences Incorporated

Inventor： Paul Furuta ,  Barry K. Sharp ,  Pavel Ivan Lazarev

IPC: H01G4/18 ,  H01B3/44 ,  C08F220/68

CPC classification number: H01G4/18 ,  C08F220/18 ,  C08F220/68 ,  C08L33/064 ,  C08L33/14 ,  H01B3/447 ,  H01G4/32 ,  C08F2220/1891 ,  C08F220/06 ,  C08F220/34

Abstract: An organic co-polymeric compound characterized by polarizability and resistivity has a general structural formula: P1 and P2 are structural units selected from acrylate, methacrylate, repeat units for polypropylene (PP), repeat units for polyethylene (PE), siloxane, and repeat units for polyethylene terephthalate. Tail is a resistive substitute that includes an oligomer of a polymeric material and n is a number of P1-Tail repeat units. Q is an ionic functional group, which is connected to the structural unit P2 via a linker group L, and m is a number of P2-L-Q repeat units. The ionic functional group Q comprises one or more ionic liquid ions, zwitterions, or polymeric acids. B is a counter ion in the form of a molecule or oligomer that can supply an opposite charge to balance a charge of the co-polymer, and s is the number of the counter ions in the compound.

公开(公告)号：US10685782B2

公开(公告)日：2020-06-16

申请号：US16454221

申请日：2019-06-27

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Pavel Ivan Lazarev ,  Barry K. Sharp ,  Paul Furuta ,  Yan Li ,  Ian S. G. Kelly-Morgan ,  Matthew R. Robinson ,  Daniel Membreno

IPC: H01G4/18 ,  H01G4/14 ,  H01G4/01 ,  H01G4/008 ,  H01G4/002 ,  H01G4/38 ,  H01G4/32 ,  H02J7/00 ,  C08G73/02 ,  H01G4/40 ,  H01L29/00 ,  H02J7/34

Abstract: A capacitor includes a first electrode, a second electrode, and a dielectric layer of molecular material disposed between said first and second electrodes. The molecular material is described by the general formula: Dp-(Core)-Hq, where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.

公开(公告)号：US20170372842A1

公开(公告)日：2017-12-28

申请号：US15194224

申请日：2016-06-27

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp

IPC: H01G9/025 ,  C09D7/12 ,  C07F5/00 ,  H01G9/048 ,  H01G9/15

CPC classification number: H01G9/025 ,  C07F5/003 ,  C09D7/63 ,  H01G9/048 ,  H01G9/15 ,  H01G9/151

Abstract: The present disclosure provides an electro-polarizable complex compound having the following general formula: [M4+(L)m]xKn,  (I) where complexing agent M is a four-valence metal; ligand L comprises one or more heteroatomic fragments comprising one or more neutral or anionic metal-coordinating heteroatoms and one or more electrically resistive fragments, m represents the number of ligands; x represents the oxidative state of the metal-ligand complex; K is a counter-ion or zwitterionic polymers which provides an electro-neutrality of the complex compound, n represents the number of counter-ions. The metal-coordinating heteroatoms form a first coordination sphere, and the number of heteroatoms in this first coordination sphere does not exceed 12.

公开(公告)号：US20170287637A1

公开(公告)日：2017-10-05

申请号：US15090509

申请日：2016-04-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  C07F7/08 ,  H01G4/005 ,  C09K19/22 ,  C09K19/32 ,  H01G4/32 ,  C07D471/22 ,  C09K19/34

CPC classification number: H01G4/14 ,  C07D471/22 ,  C09B5/008 ,  C09B5/62 ,  C09B47/00 ,  C09B47/04 ,  C09K19/606 ,  H01G4/18 ,  H01G4/32

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having two-dimensional teat form and self-assembling by pi-pi stacking in a column-like supramolecule, R1 is a dopant group connected to Core1; a number m of R1 groups is 1, 2, 3 or 4. R2 is a substituent comprising one or more ionic groups connected to Core1; a number p of ionic groups R2 is 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear polarization effect. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, a number n of such oligomers is 0, 2, or 4. R3 is a substituent comprising one or more ionic groups connected to Core2; a number s of the ionic groups R3 is 0, 1, 2, 3 or 4. R4 is a resistive substituent providing solubility of the compound in a solvent and electrically insulating the column-like supramolecules from each other. A number k of substituents R4 is 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US10755857B2

公开(公告)日：2020-08-25

申请号：US16436269

申请日：2019-06-10

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Yan Li ,  Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Samuel Hein

IPC: H01G4/18 ,  C08F20/34 ,  C08F20/18 ,  H01L49/02 ,  C08F20/36 ,  C08G73/02 ,  C08L33/02 ,  H01G4/32 ,  H01G9/04 ,  H01G9/07

Abstract: A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20190139705A1

公开(公告)日：2019-05-09

申请号：US15982482

申请日：2018-05-17

Applicant: CAPACITOR SCIENCES INCORPORATED

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G4/14 ,  H01G4/18 ,  H01G4/32 ,  C09B5/62 ,  C09K19/60 ,  C09B5/00 ,  C07D471/22 ,  C09B47/00 ,  C09B47/04

Abstract: An electro-polarizable compound has the following general formula: where Core1 is an aromatic polycyclic conjugated molecule having two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule, which is tetrapirolic macro-cyclic fragment, R1 is an dopant group connected to Core1, m is number of R1 which is equal to 1, 2, 3 or 4, R2 is a substituent comprising one or more ionic groups, p is number of R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE containing the Core1 with at least one R1 has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer self-assembling by pi-pi stacking in a column-like supramolecule, n is number of Core2 which is equal to 2, or 4, R3 is a substituent comprising one or more ionic groups, s is number of R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-polar resistive substituent, k is a number of R4 which is equal to 0, 1, 2, 3, 4, 5, 6, 7 or 8.

公开(公告)号：US20190108944A1

公开(公告)日：2019-04-11

申请号：US16208953

申请日：2018-12-04

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Yan Li ,  Ian S.G. Kelly-Morgan

IPC: H01G4/14 ,  C09B5/00 ,  H01G4/18 ,  H01G4/32 ,  H01G4/005 ,  C07D471/22 ,  C09B5/62

Abstract: An electro-polarizable compound has the following general formula: Core1 is an aromatic polycyclic conjugated molecule having a structural formula: Core1 is of two-dimensional flat form and self-assembling by pi-pi stacking in a column-like supramolecule. R1 and R1′ are, electron donor and acceptor groups, respectively, m and m′ are the numbers of donor and acceptor groups, respectively and are equal to 0, 1, 2, 3, 4, 5 or 6 but are not both equal to 0. R2 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to Core1, p is a number of ionic groups R2 which is equal to 0, 1, 2, 3 or 4. The fragment marked NLE has a nonlinear effect of polarization. Core2 is an electro-conductive oligomer and n is a number of the electro-conductive oligomers equal to 0, 2, or 4. R3 is a substituent comprising one or more ionic groups from a class of ionic compounds that form ionic liquids connected to Core2, s is a number of the ionic groups R3 which is equal to 0, 1, 2, 3 or 4. R4 is a non-conjugate cyclic or polycyclic resistive substituent providing solubility of the organic compound in a solvent and electrically insulating the column-like supramolecules from each other and connected to Core1 and/or to Core2, k is a number of substituents R4 which is equal to 1, 2, 3, 4, 5, 6, 7 or 8

公开(公告)号：US10319523B2

公开(公告)日：2019-06-11

申请号：US15710587

申请日：2017-09-20

Applicant: Capacitor Sciences Incorporated

Inventor： Yan Li ,  Pavel Ivan Lazarev ,  Paul T. Furuta ,  Barry K. Sharp ,  Samuel Hein

IPC: H01G4/18 ,  C08F20/34 ,  C08F20/18 ,  H01L49/02 ,  C08F20/36 ,  C08G73/02 ,  C08L33/02 ,  H01G9/04 ,  H01G9/07

Abstract: A composite polymeric material includes one or more repeating backbone units; one or more polarizable units incorporated into or connected to one or more of the one or more repeating backbone units; and one or more resistive tails connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit, on a hydrocarbon chain linking a polarizable unit to a backbone unit, or directly attached to a backbone unit. The composite polymeric material may be used to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.

公开(公告)号：US20190148082A1

公开(公告)日：2019-05-16

申请号：US16243906

申请日：2019-01-09

Applicant: Capacitor Sciences Incorporated

Inventor： Pavel Ivan Lazarev ,  Paul Furuta ,  Barry K. Sharp ,  Yan Li

IPC: H01G9/07 ,  H01G9/04 ,  C08F20/36 ,  C08G73/02

Abstract: A composite oligomeric material includes one or more repeating backbone units. One or more polarizable units are incorporated into or connected to one or more of the one or more repeating backbone units. One or more resistive tails are connected to one or more of the repeating backbone units or to the one or more polarizable units as a side chain on the polarizable unit. The composite oligomer material may be polymerized to form a metadielectric, which may be sandwiched between to electrodes to form a metacapacitor.