METHOD OF SELECTION OF ASPHALTENE PRECIPITANT ADDITIVES AND PROCESS FOR SUBSURFACE UPGRADING THEREWITH

    公开(公告)号:US20190241795A1

    公开(公告)日:2019-08-08

    申请号:US15890459

    申请日:2018-02-07

    CPC classification number: C09K8/594 E21B43/24 E21B43/26 E21B43/38

    Abstract: In-situ upgrading of heavy hydrocarbons includes injecting into a reservoir solvent, an asphaltene precipitant additive and optionally steam, at a ratio of solvent to heavy hydrocarbon between 0.1:1 and 20:1 under reservoir conditions. The additive has C—H, C—C and/or C—O bonds that thermally crack to generate free radicals in the vapor phase after injection. Formed downhole are a blend containing an upgraded hydrocarbon, and precipitated asphaltenes. The upgraded hydrocarbon is produced such that the precipitated asphaltenes remain in the reservoir. The upgraded hydrocarbon has a greater API gravity, lower asphaltene content, and lower viscosity than the heavy hydrocarbon. The precipitated asphaltenes are present in a higher amount than a similar blend not containing the additive. A method for selecting the additive includes identifying candidate additives having bonds that crack to generate free radicals in the vapor phase at the operating temperature, and calculating percent increase of asphaltenes precipitated for each.

    METHOD FOR DETERMINING ASPHALTENE STABILITY OF A HYDROCARBON-CONTAINING MATERIAL

    公开(公告)号:US20190169512A1

    公开(公告)日:2019-06-06

    申请号:US16272725

    申请日:2019-02-11

    Abstract: A method for determining asphaltene stability in a hydrocarbon-containing material having solvated asphaltenes therein is disclosed. The method involves the steps of: (a) precipitating an amount of the asphaltenes from a liquid sample of the hydrocarbon-containing material with an alkane mobile phase solvent in a column; (b) dissolving a first amount and a second amount of the precipitated asphaltenes by gradually and continuously changing the alkane mobile phase solvent to a final mobile phase solvent having a solubility parameter at least 1 MPa0.5 higher than the alkane mobile phase solvent; (c) monitoring the concentration of eluted fractions from the column; (d) creating a solubility profile of the dissolved asphaltenes in the hydrocarbon-containing material; and (e) determining one or more asphaltene stability parameters of the hydrocarbon-containing material.

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