摘要:
The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluorobutane (HFC-365) and hydrogen fluoride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production of HFC-365. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent and aerosol to propellant.
摘要:
The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluorobutane (HFC-365) and hydrogen fluoride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production of HFC-365. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent and aerosol to propellant.
摘要:
The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentafluorobutane (HFC-365) and hydrogen fluoride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production of HFC-365. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent and aerosol to propellant.
摘要:
The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.
摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a C1 addition agent under conditions effective to produce a compound of formula (I).
摘要翻译:公开了一种制备氟化有机化合物的方法,包括氢氟丙烯,其优选包括将至少一种式(I)化合物:CF 3 CF n CH m X a-m(I)转化为至少一种式(II)CF 3 CZCHZ(II)化合物。 其中每个X独立地为Cl,I或Br; 每个Z独立地为H或F; n为1或2; m为1,2或3,条件是当n为1时,m为1或2; a为2或3,a-m≥0。 某些实施方案包括在有效产生式(I)化合物的条件下使氟化C 2烯烃如四氟乙烯与C1加成剂反应的步骤。
摘要:
Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.
摘要翻译:用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法,其中氟丙烯具有式CF 3 C Y = C X N H P,其中X和Y独立地是氢或选自氟,氯,溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数,条件是(N + P)= 2。
摘要:
Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.
摘要翻译:用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法,其中氟丙烯具有式CF 3 C 1 -C 6 N N H P H,其中X Y独立地为氢或选自氟,氯,溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数,条件是(N + P)= 2。
摘要:
Dehydrohalogenation processes for the preparation of fluoropropenes from corresponding halopropanes, in which the fluoropropenes have the formula CF3CY═CXNHP, wherein X and Y are independently hydrogen or a halogen selected from fluorine, chlorine, bromine and iodine; and N and P are independently integers equal to 0, 1 or 2, provided that (N+P)=2.
摘要翻译:用于从相应的卤代丙烷制备氟丙烯的脱卤化氢方法,其中氟丙烯具有式CF 3 C 1 -C 6 N N H P H,其中X Y独立地为氢或选自氟,氯,溴和碘的卤素; 并且N和P独立地为等于0,1或2的整数,条件是(N + P)= 2。
摘要:
The invention provides an economic process for the manufacture of the hydrofluorocarbon 1,1,3,3,3-pentafluoropropene (HFC-1225zc). HFC-1225zc can be made from the dehydrochlorination of 1-chloro-1,1,3,3,3-pentafluoropropane (HCFC-235fa). Alternatively, HFC-1225zc can also be made from the dehydrofluorination of 1,1,1,3,3,3-hexafluoropropane (HFC-236fa). HFC-1225zc) is a compound that has the potential to be used as a low Global Warming Potential refrigerant, blowing agent, aerosol propellant, or solvent.
摘要:
Provided are azeotropic and azeotrope-like compositions of 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) and hydrogen fluoride (HF). Such azeotropic and azeotrope-like compositions are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).