公开(公告)号：US20190210944A1

公开(公告)日：2019-07-11

申请号：US15864730

申请日：2018-01-08

申请人： Honeywell International Inc.

发明人： Haiyou Wang ,  Terris Yang ,  Daniel C. Merkel ,  Haluk Kopkalli ,  Gustavo Cerri ,  Yuon Chiu ,  Richard D. Horwath

IPC分类号： C07C17/25 ,  C07C17/386 ,  C07C17/395 ,  C07C21/18 ,  B01D3/00 ,  B01D3/36

CPC分类号： C07C17/25 ,  B01D3/002 ,  B01D3/36 ,  C07C17/386 ,  C07C17/395 ,  C07C21/18

摘要： The present disclosure provides various manufacturing processes for the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf or 1234yf). Such methods may allow for the improved yields, more economical processes, and waste reduction in the production of 1234yf and subsequent processes.

公开(公告)号：US20190194399A1

公开(公告)日：2019-06-27

申请号：US16322255

申请日：2017-08-08

申请人： Arkema France

发明人： Dominque DEUR-BERT ,  Wissam RACHED ,  Laurent WENDLINGER

IPC分类号： C08J3/09 ,  C09K5/04 ,  C09K3/30 ,  C08J9/14 ,  C07C21/18 ,  C07C19/08 ,  B01D3/36 ,  B01D3/40 ,  H01B3/44

CPC分类号： C08J3/093 ,  B01D3/36 ,  B01D3/40 ,  C07C17/386 ,  C07C19/08 ,  C07C21/18 ,  C08J9/146 ,  C08J2203/142 ,  C08J2203/162 ,  C08J2203/182 ,  C09K3/30 ,  C09K5/045 ,  C09K5/048 ,  C09K2205/126 ,  H01B3/445 ,  H01B3/56

摘要： The present invention relates to compositions comprising 1,1,1,2,2-pentafluoropropane and trans-1,3,3,3-tetrafluoropropene, which are of use in numerous fields of application.

公开(公告)号：US20190002375A1

公开(公告)日：2019-01-03

申请号：US16105407

申请日：2018-08-20

申请人： AGC Inc.

发明人： Tomoaki TANIGUCHI ,  Jumpei NOMURA ,  Takayuki SAKAI ,  Takashi HAYASE

IPC分类号： C07C17/383 ,  C07C21/18

CPC分类号： C07C17/383 ,  B01D3/143 ,  B01D11/04 ,  B01D2257/206 ,  C07C17/38 ,  C07C17/386 ,  C07C21/18 ,  Y02P20/124

摘要： There is provided a method of efficiently manufacturing purified 1224yd containing 1224yd at a high concentration from a mixture containing 1224yd and a compound that forms an azeotropic composition or an azeotropic-like composition with 1224yd. A manufacturing method of purified 1224yd, includes making a first mixture of 1224yd and a compound (X1) forming an azeotropic composition or an azeotropic-like composition with 1224yd to be brought into contact with a first extraction solvent to obtain purified 1224yd not substantially containing the compound (X1).

公开(公告)号：USRE46928E1

公开(公告)日：2018-07-03

申请号：US15429745

申请日：2017-02-10

申请人： THE CHEMOURS COMPANY FC, LLC

发明人： Ryan Hulse ,  Haluk Kopkalli ,  Hang T. Pham

IPC分类号： C09K5/04 ,  C07C17/386 ,  C07C17/38 ,  C07C17/383 ,  C07C17/389

CPC分类号： C07C17/386 ,  C07C17/38 ,  C07C17/383 ,  C07C17/389 ,  C07C21/18

摘要： Provided are azeotropic and azeotrope-like compositions of 1,2,3,3,3-pentafluoropropene (HFO-1225ye) and water. Such azeotropic and azeotrope-like compositions are useful in isolating 1,2,3,3,3-pentafluoropropene from impurities during production. Azeotropes of the instant invention are similarly useful in final compositions or manufacturing final compositions, such as blowing agent, propellants, refrigerants, diluents for gaseous sterilization and the like.

公开(公告)号：US20180155259A1

公开(公告)日：2018-06-07

申请号：US15576398

申请日：2016-05-18

申请人： DAIKIN INDUSTRIES, LTD.

发明人： Shun OHKUBO

IPC分类号： C07C17/25 ,  C07C17/383 ,  C07C17/386 ,  C07C17/38 ,  C07C17/354

CPC分类号： C07C17/25 ,  C07B61/00 ,  C07C17/354 ,  C07C17/38 ,  C07C17/383 ,  C07C17/386 ,  C07C21/18

摘要： Provided is an efficient method for producing a fluorine-containing compound without the need for a rectification column involving numerous stages, extractive distillation, etc. The method for producing a fluorine-containing compound includes the step of supplying a composition containing a mixture to a dehydrohalogenation step, the mixture being at least one member selected from the group consisting of mixtures of at least one fluoroolefin and at least one hydrofluorocarbon, the boiling points of which are close to each other, azeotropic mixtures of at least one fluoroolefin and at least one hydrofluorocarbon, and pseudo-azeotropic compounds of at least one fluoroolefin and at least one hydrofluorocarbon.

公开(公告)号：US09598337B2

公开(公告)日：2017-03-21

申请号：US14767417

申请日：2014-02-12

申请人： OCCIDENTAL CHEMICAL CORPORATION

发明人： John Lee Dawkins ,  Darrell Gene Hollis ,  Rodney L. Klausmeyer ,  Keith S. Kramer ,  Michael Andrew Garmon

IPC分类号： C07C17/363 ,  C07C17/395 ,  C07C17/386 ,  C07C17/383 ,  C07C17/25 ,  C07C17/38 ,  C07C17/42 ,  B01D3/10 ,  B01D3/34 ,  B01D3/00 ,  B01D11/04 ,  C07C17/06 ,  C07C17/278

CPC分类号： C07C17/386 ,  B01D3/009 ,  B01D3/10 ,  B01D3/34 ,  B01D11/04 ,  C07C17/06 ,  C07C17/25 ,  C07C17/278 ,  C07C17/38 ,  C07C17/383 ,  C07C17/395 ,  C07C17/42 ,  Y02P20/127 ,  C07C19/01 ,  C07C21/04

摘要： Processes for isolating 1,1,1,2,3-pentachloropropane from a crude product stream containing the 1,1,1,2,3-pentachloropropane and ferric chloride. The processes may include deep distillation of the crude, treatment of the crude with a reagent that deactivates the ferric chloride followed by distillation on the deactivated crude stream, aqueous washing of the crude product stream to remove ferric chloride followed by distillation on the deactivated crude stream. Other embodiments simultaneously prepare 1,1,2,3-tetrachloroprene and 1,1,1,2,3-pentachloroprane.

公开(公告)号：US09296670B2

公开(公告)日：2016-03-29

申请号：US14377727

申请日：2013-02-08

申请人： Honeywell International, Inc.

发明人： Haiyou Wang ,  Hsueh S. Tung ,  Haluk Kopkalli ,  Yuon Chiu ,  Gustavo Cerri ,  Jeffrey Ball ,  Philip L. Da Prato ,  Xuehui Sun ,  Mario Joseph Nappa

IPC分类号： C07C17/23 ,  C07C17/395 ,  C07C17/06 ,  C07C17/087 ,  C07C17/25 ,  C07C17/386 ,  C07C17/389 ,  B01J27/08

CPC分类号： C07C17/395 ,  B01J27/08 ,  C07C17/06 ,  C07C17/087 ,  C07C17/23 ,  C07C17/25 ,  C07C17/386 ,  C07C17/389 ,  Y02P20/582 ,  C07C19/10 ,  C07C21/18

摘要： A method for forming 2,3,3,3-tetrafluoropropene (HFO-1234yf) comprising providing a dehydrochlorination starting material having relatively low concentrations of 2-chloro-3,3,3-trifluoropropene (HCFO-1233xf), especially and preferable less than about 8.0% when the dehydrochlorination reaction utilizes no substantial amount of catalyst or catalyst comprising austenitic nickel-based materials.

摘要翻译： 一种形成2,3,3,3-四氟丙烯（HFO-1234yf）的方法，包括提供具有较低浓度的2-氯-3,3,3-三氟丙烯（HCFO-1233xf）的脱氯化氢原料，特别优选较少 当脱氯化氢反应不使用显着量的包含奥氏体镍基材料的催化剂或催化剂时，约为8.0％。

公开(公告)号：US20150291490A1

公开(公告)日：2015-10-15

申请号：US14749877

申请日：2015-06-25

申请人： ASAHI GLASS COMPANY, LIMITED

发明人： Shoji FURUTA ,  Tetsuo OTSUKA

IPC分类号： C07C17/386

CPC分类号： C07C17/386 ,  C07C17/18 ,  C07C17/395 ,  C07C21/18 ,  C07C19/03

摘要： To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition containing HFO-1234yf and R40.A method for separating HFO-1234yf containing substantially no R40, which comprises bringing an azeotropic composition or azeotrope-like composition of HFO-1234yf and R40 into contact with a specific extraction solvent.

摘要翻译： 提供从含有HFO-1234yf和R40的组合物有效分离2,3,3,3-四氟丙烯（HFO-1234yf）和氯甲烷（R40）的方法。 一种分离基本上不含R40的HFO-1234yf的方法，其包括使HFO-1234yf和R40的共沸组合物或类共沸组合物与特定的提取溶剂接触。

公开(公告)号：US08884084B2

公开(公告)日：2014-11-11

申请号：US13078320

申请日：2011-04-01

申请人： Ralph Thomas Baker ,  Ralph Newton Miller ,  Viacheslav Alexandrovich Petrov ,  Velliyur N. Mallikarjuna Rao ,  Allen Capron Sievert

发明人： Ralph Thomas Baker ,  Ralph Newton Miller ,  Viacheslav Alexandrovich Petrov ,  Velliyur N. Mallikarjuna Rao ,  Allen Capron Sievert

IPC分类号： C07C17/266 ,  C07C21/18 ,  C07C19/10 ,  C07C19/08 ,  C07C17/20 ,  C07C17/275 ,  C01B7/19 ,  C07C17/386 ,  C07C17/278 ,  C07C17/38

CPC分类号： C07C19/10 ,  C01B7/191 ,  C07C17/206 ,  C07C17/275 ,  C07C17/278 ,  C07C17/38 ,  C07C17/386 ,  C07C19/08 ,  Y02P20/582 ,  C07C19/01 ,  C07C19/16

摘要： A liquid phase process is disclosed for producing halogenated alkane adducts of the formula CAR1R2CBR3R4 (where A, B, R1, R2, R3, and R4 are as defined in the specification) which involves contacting a corresponding halogenated alkane, AB, with a corresponding olefin, CR1R2═CR3R4 in a dinitrile or cyclic carbonate ester solvent which divides the reaction mixture into two liquid phases and in the presence of a catalyst system containing (i) at least one catalyst selected from monovalent and divalent copper; and optionally (ii) a promoter selected from aromatic or aliphatic heterocyclic compounds which contain at least one carbon-nitrogen double bond in the heterocyclic ring. When hydrochlorofluorocarbons are formed, the chlorine content may be reduced by reacting the hydrochlorofluorocarbons with HF.Azeotropes of CClF2CH2CF3 with HF and azeotropes of CF3CH2CHF2 with HF are also disclosed; as are process for producing such azeotropes.

摘要翻译： 公开了用于制备式CAR1R2CBR3R4（其中A，B，R1，R2，R3和R4如说明书中所定义）的卤代烷烃加合物的液相方法，其涉及使相应的卤代烷烃AB与相应的烯烃 在二腈或环状碳酸酯溶剂中的CR 1 R 2 = CR 3 R 4，其将反应混合物分成两个液相，并且在含有（i）至少一种选自一价和二价铜的催化剂的催化剂体系的存在下， 和任选地（ii）选自在杂环中含有至少一个碳 - 氮双键的芳族或脂族杂环化合物的促进剂。 当形成氢氯氟烃时，可以通过氢氯氟烃与HF反应来降低氯含量。 还公开了CClF 2 CH 2 CF 3与HF的共沸物和CF 3 CH 2 CHF 2与HF的共沸物质; 生产这种共沸物的方法也是如此。

公开(公告)号：US08845921B2

公开(公告)日：2014-09-30

申请号：US12749207

申请日：2010-03-29

申请人： Daniel C. Merkel ,  Konstantin A. Pokrovski ,  Hsueh S. Tung ,  Hang T. Pham ,  Rajiv R. Singh

发明人： Daniel C. Merkel ,  Konstantin A. Pokrovski ,  Hsueh S. Tung ,  Hang T. Pham ,  Rajiv R. Singh

IPC分类号： C09K5/04 ,  C07C17/386 ,  B01D3/36

CPC分类号： B01D3/36 ,  C07C17/386 ,  C07C19/10 ,  C07C21/18

摘要： The invention provides a method for separating halocarbons. In particular, a method for separating 2-chloro-1,1,1,2-tetrafluoropropane (HCFC-244bb) from 2-chloro-3,3,3-trifluoropropene (HCFC-1233xf) by adding a third component and then separating via conventional distillation. More particularly the invention pertains to a method for separating HCFC-244bb from HCFC-1233xf which are useful as intermediates in the production of 2,3,3,3-tetrafluoropropene (HFO-1234yf).

摘要翻译： 本发明提供一种分离卤代烃的方法。 特别是通过添加第三成分分离2-氯-3,3,3-三氟丙烯（HCFC-1233xf）而分离出2-氯-1,1,1,2-四氟丙烷（HCFC-244bb）的方法， 通过常规蒸馏。 更具体地说，本发明涉及从HCFC-1233xf中分离HCFC-244bb的方法，其可用作制备2,3,3,3-四氟丙烯（HFO-1234yf）中的中间体。