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11.发明授权High chloride emulsion that contains a dopant and peptizer combination that increases high density contrast 失效含有掺杂剂和胶溶剂组合的高氯化物乳液，增加了高密度的对比度
公开(公告)号：US5783378A
公开(公告)日：1998-07-21
申请号：US739980
申请日：1996-10-30
申请人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
发明人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
摘要： A radiation-sensitive high chloride emulsion is disclosed comprised of grains predominantly bounded by {100} crystal faces and internally containing three dopants each selected to satisfy a different one of the following class requirements: (i) a metal coordination complex containing a nitrosyl or thionitrosyl ligand in combination with a transition metal chosen from groups 5 to 10 inclusive of the periodic table of elements, (ii) a shallow electron trapping dopant, and (iii) an iridium coordination complex having ligands each of which are more electropositive than a cyano ligand. A gelatino-peptizer for the grains is employed that contains less than 30 micromoles of methionine per gram. The dopants and peptizer in combination increase contrast and provide a highly unexpected increase in high density contrast.
摘要翻译： 公开了一种辐射敏感的高氯化物乳液，其包含主要由{100}晶面限定的晶粒，并且内部含有三种掺杂剂，每种掺杂剂选择为满足以下类别要求中的不同之一：（i）含有亚硝酰基或亚硫酰基 配体与选自元素周期表第5至10组的过渡金属组合，（ii）浅电子捕获掺杂剂，和（iii）铱配位络合物，其配体各自比氰基配体更具有正电性 。 使用含有每克少于30微摩尔甲硫氨酸的晶粒的明胶胶溶剂。 掺杂剂和胶溶剂组合增加了对比度，并提供了高度意想不到的高密度对比度的增加。
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12.发明授权Silver halide color photography element with improved high density contrast and bright low density colors 失效卤化银彩色摄影元件具有改进的高密度对比度和明亮的低密度颜色
公开(公告)号：US5512103A
公开(公告)日：1996-04-30
申请号：US374054
申请日：1995-01-19
CPC分类号： G03C7/3041 , G03C7/3225 , G03C7/39204
摘要： The invention provides a cyan color producing silver halide emulsion layer or a magenta color producing silver halide emulsion layer wherein said at least one layer has an exposure range of at least 0.6 log E from the point where the instantaneous contrast is 1.0 and wherein the instantaneous contrast of said layer increases as a function of increasing exposure over at least 70 percent of said exposure range.
摘要翻译： 本发明提供了产生青色的卤化银乳剂层或品红色产生卤化银乳剂层，其中所述至少一层具有至少0.6log E的曝光范围，其中瞬时对比度为1.0，其中瞬时对比度 作为所述曝光范围的至少70％的曝光量增加的函数。
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公开(公告)号：US06242172B1
公开(公告)日：2001-06-05
申请号：US09475841
申请日：1999-12-30
申请人： Jerzy A. Budz , Eric L. Bell , Rajesh V. Mehta
发明人： Jerzy A. Budz , Eric L. Bell , Rajesh V. Mehta
IPC分类号： G03C108
CPC分类号： G03C5/04 , G03C1/035 , G03C1/09 , G03C2001/03535 , G03C2001/03541 , G03C2001/093 , G03C2200/39
摘要： A radiation-sensitive emulsion is disclosed comprised of cubical silver halide grains containing from 0.05 to 3 mole percent iodide, based on total silver, and an iridium coordination complex dopant, wherein (i) the iodide is incorporated in the grains in a controlled, non-uniform distribution forming a core containing at least 50 percent of total silver, an iodide free surface shell having a thickness of greater than 50 Å, and a sub-surface shell that contains a maximum iodide concentration, and (ii) the iridium coordination complex dopant is incorporated into the sub-surface shell or into a region of the core extending up to 60% of the total silver into the grain from the sub-surface shell. Speed and reciprocity of iodochloride emulsions can be improved by localized addition of known in the art reciprocity-controlling iridium dopants in relation to high iodide region of the grain. By carefully incorporating reciprocity-controlling dopant within a well defined band within a grain the difficulties of the prior art can be overcome.
摘要翻译： 公开了一种辐射敏感性乳剂，其包含基于总银含有0.05至3摩尔％碘化物的立方体卤化银颗粒和铱配位络合物掺杂剂，其中（i）碘化物以受控的非 - - 均匀分布，形成含有至少50％的总银，不含碘离子的表面壳，厚度大于的核心，以及含有最大碘化物浓度的亚表面壳，和（ⅱ）铱配位络合物 掺杂剂结合到子表面壳体中或引入芯部的区域中，该区域从底表面壳体延伸到总银的60％到晶粒内。 通过本领域已知的互易控制铱掺杂剂相对于颗粒的高碘化物区域的局部添加可以提高碘氯化物乳剂的速度和互惠。 通过将互易控制掺杂剂小心地结合在晶粒内的良好限定的带内，可以克服现有技术的困难。
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公开(公告)号：US6107018A
公开(公告)日：2000-08-22
申请号：US250200
申请日：1999-02-16
CPC分类号： G03C1/09 , G03C1/035 , G03C1/07 , Y10S430/145 , Y10S430/146
摘要： A radiation-sensitive emulsion is disclosed comprised of silver halide grains (a) containing greater than 50 mole percent chloride, based on silver, (b) having greater than 50 percent of their surface area provided by {100} crystal faces, and (c) having a central portion accounting for from 95 to 99 percent of total silver and containing two dopants selected to satisfy each of the following class requirements: (i) a hexacoordination metal complex which satisfies the formula (I)[ML.sub.6 ].sup.nwherein n is zero, -1, -2, -3 or -4; M is a filled frontier orbital polyvalent metal ion, other than iridium; and L.sub.6 represents bridging ligands which can be independently selected, provided that least four of the ligands are anionic ligands, and at least one of the ligands is a cyano ligand or a ligand more electronegative than a cyano ligand; and (ii) an iridium coordination complex containing a thiazole or substituted thiazole ligand. A photographic recording element comprising a support and at least one light sensitive silver halide emulsion layer comprising silver halide grains as described above is also disclosed, as well as an electronic printing method which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100.mu. seconds duration in a pixel-by-pixel mode, wherein the silver halide emulsion layer is comprised of silver halide grains as described above.
摘要翻译： 公开了一种辐射敏感乳液，其包含基于银的大于50摩尔百分比的氯化银（a）的卤化银颗粒（a），（b）其具有由{100}晶面提供的其表面积的50％以上，（c ），其中心部分占总银的95％至99％，并且含有两种掺杂剂，其选择为满足以下各项要求：（i）满足式（I）[ML6] n的六配位金属络合物，其中n为零 ，-1，-2，-3或-4; M是除铱之外的填充边界轨道多价金属离子; 并且L6表示可以独立选择的桥连配体，条件是至少四种配体是阴离子配体，并且至少一种配体是氰基配体或比氰基配体更具有负电性的配体; 和（ii）含有噻唑或取代的噻唑配体的铱配位络合物。 还公开了一种包含载体和包含如上所述的包含卤化银颗粒的至少一种感光卤化银乳剂层的照相记录元件，以及电子印刷方法，其包括将记录元件的辐射敏感卤化银乳剂层 以像素为单位的模式，至少10-4erg / cm2的光化辐射长达100μs的持续时间，其中卤化银乳剂层由如上所述的卤化银颗粒组成。
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公开(公告)号：US5962210A
公开(公告)日：1999-10-05
申请号：US5861
申请日：1998-01-12
摘要： The invention relates to a photographic emulsion comprising silver iodochloride grains, said grains further comprising iridium, said grains chemically sensitized with gold in an amount of between 120 and 200 mg gold per silver mole and sulfur in an amount between 0.1 and 20 mg sulfur per silver mole, 1-(3-acetamidophenyl)-5-mercaptotetrazole, 1-phenyl-5-mercaptotetrazole, and a disulfide compound represented by the following formula: ##STR1## wherein X is independently --O--, --NH-- or --NR--, where R is a substituent;m and r are independently 0, 1 or 2;X is --H or a cationic species;Ar is an aromatic group; andL is a linking group, where p is 0 or 1.
摘要翻译： 本发明涉及一种包含碘氯化银颗粒的照相乳剂，所述颗粒还包含铱，所述颗粒用金对金银进行化学增感，金量为每个银摩尔为120至200mg金，硫含量为0.1至20mg硫/银 摩尔，1-（3-乙酰氨基苯基）-5-巯基四唑，1-苯基-5-巯基四唑和由下式表示的二硫化物：其中X独立地是-O - ， - NH-或-NR-，其中R 是取代基; m和r独立地为0,1或2; X是-H或阳离子物质; Ar是芳族基团; L为连接基团，p为0或1。
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公开(公告)号：US5480771A
公开(公告)日：1996-01-02
申请号：US316003
申请日：1994-09-30
申请人： Eric L. Bell
发明人： Eric L. Bell
CPC分类号： G03C1/08
摘要： The present invention provides a photographic emulsion silver halide grains having incorporated therein or thereon a dopant, a grain surface modifier, and a hexacoordination complex comprising iridium, wherein the dopant is a transition metal complex comprising a nitrosyl or thionitrosyl ligand with a transition metal selected from the Groups 5 to 10 of the periodic table, and the grain surface modifier is a transition metal complex comprising a transition metal, other than iridium, which is selected from Groups 7 to 10 of the periodic table.
摘要翻译： 本发明提供一种其中掺入其中或其上的掺杂剂，颗粒表面改性剂和包含铱的六配位络合物的照相乳剂卤化银颗粒，其中掺杂剂是包含亚硝酰基或亚硫酰基基配体与过渡金属的过渡金属络合物， 周期表第5至10族和晶粒表面改性剂是包含选自元素周期表第7至10族的除铱之外的过渡金属的过渡金属络合物。
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公开(公告)号：US5783373A
公开(公告)日：1998-07-21
申请号：US740535
申请日：1996-10-30
申请人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
发明人： Jerzy Z. Mydlarz , Jerzy A. Budz , Eric L. Bell
CPC分类号： G03C1/035 , G03C1/0053 , G03C1/08 , G03C1/09 , G03C7/3022 , G03C1/047 , G03C2001/03517 , G03C2001/03535 , G03C2001/03541 , G03C2001/0845 , G03C2001/0854 , G03C2001/093 , G03C2001/094 , G03C2200/01 , G03C2200/39 , G03C2200/42 , G03C5/164
摘要： An electronic printing method is disclosed which comprises subjecting a radiation sensitive silver halide emulsion layer of a recording element to actinic radiation of at least 10.sup.-4 ergs/cm.sup.2 for up to 100.mu. seconds duration in a pixel-by-pixel mode. The silver halide emulsion layer is comprised of grains predominantly bounded by {100} crystal faces and internally containing three dopants each selected to satisfy a different one of the following class requirements: (i) a metal coordination complex containing a nitrosyl or thionitrosyl ligand in combination with a transition metal chosen from groups 5 to 10 inclusive of the periodic table of elements, (ii) a shallow electron trapping dopant, and (iii) a iridium coordination complex having ligands each of which are more electropositive than a cyano ligand. A gelatino-peptizer for the grains is employed that contains less than 30 micromoles of methionine per gram. The dopants and peptizer in combination increase contrast and provide a highly unexpected increase in high density contrast.
摘要翻译： 公开了一种电子印刷方法，其包括以逐像素模式对记录元件的辐射敏感卤化银乳剂层进行至少10-4erg / cm2的光化辐射长达100μs的持续时间。 卤化银乳剂层由主要由{100}晶面限定的晶粒组成，内部含有三种掺杂剂，每种掺杂剂选择满足以下类别要求中的不同之一：（i）含有亚硝酰基或亚硫酰基配位体的金属配位络合物 具有选自元素周期表第5至10族的过渡金属，（ii）浅电子俘获掺杂剂，和（iii）具有比氰基配体更具有正电性的配体的铱配位络合物。 使用含有每克少于30微摩尔甲硫氨酸的晶粒的明胶胶溶剂。 掺杂剂和胶溶剂组合增加了对比度，并提供了高度意想不到的高密度对比度的增加。
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18.发明授权
公开(公告)号：US5597686A
公开(公告)日：1997-01-28
申请号：US429989
申请日：1995-04-27
申请人： Gladys L. MacIntyre , Eric L. Bell
发明人： Gladys L. MacIntyre , Eric L. Bell
CPC分类号： G03C1/08
摘要： The present invention provides a photographic emulsion comprising a silver halide grains containing at least two dopants. The dopants comprise an osmium-based transition metal complex containing a nitrosyl or thionitrosyl ligand, and a transition metal complex containing a transition metal selected from Group 8 of the periodic table.
摘要翻译： 本发明提供一种包含含有至少两种掺杂剂的卤化银颗粒的照相乳剂。 掺杂剂包含含有亚硝酰基或亚硫酰基基配体的锇基过渡金属络合物和含有选自元素周期表第8族的过渡金属的过渡金属络合物。
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公开(公告)号：US5474888A
公开(公告)日：1995-12-12
申请号：US331789
申请日：1994-10-31
申请人： Eric L. Bell
发明人： Eric L. Bell
摘要： The present invention provides a photographic emulsion silver halide grains having incorporated therein or thereon a dopant, a grain surface modifier, and a hexacoordination complex comprising iridium, wherein the grain surface modifier is a transition metal complex comprising a nitrosyl or thionitrosyl ligand with a transition metal selected from the Groups 5 to 10, inclusive, of the periodic table, and the dopant is a transition metal complex comprising a transition metal, other than iridium, which is selected from Groups 7 to 10 of the periodic table.
摘要翻译： 本发明提供一种其中掺有掺杂剂，颗粒表面改性剂和包含铱的六配位络合物的照相乳剂卤化银颗粒，其中晶粒表面改性剂是包含亚硝酰基或亚硫酰基基配体与过渡金属的过渡金属配合物 选自元素周期表的第5至10族，并且掺杂剂是包含选自元素周期表第7至10族的除铱之外的过渡金属的过渡金属络合物。
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20.发明授权Silver halide color photographic element with improved high density contrast and bright low density colors 失效卤化银彩色照相材料具有改善的高密度对比度和明亮的低密度颜色
公开(公告)号：US5418118A
公开(公告)日：1995-05-23
申请号：US199035
申请日：1994-02-18
CPC分类号： G03C7/3225 , G03C7/3041 , G03C7/39204
摘要： The invention provides a cyan color producing silver halide emulsion layer or a magenta color producing silver halide emulsion layer wherein said at least one layer has an exposure range of at least 0.6 log E from the point where the instantaneous contrast is 1.0 and wherein the instantaneous contrast of said layer increases as a function of increasing exposure over at least 70 percent of said exposure range.
摘要翻译： 本发明提供了产生青色的卤化银乳剂层或品红色产生卤化银乳剂层，其中所述至少一层具有至少0.6log E的曝光范围，其中瞬时对比度为1.0，其中瞬时对比度 作为所述曝光范围的至少70％的曝光量增加的函数。
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