NICKEL HYDROGEN SECONDARY BATTERY
    12.
    发明申请

    公开(公告)号:US20170110764A1

    公开(公告)日:2017-04-20

    申请号:US15317106

    申请日:2015-06-23

    Abstract: A nickel hydrogen secondary battery accommodates an electrode group including a positive electrode and a negative electrode which are stacked one on top of another through a separator, together with an alkaline electrolyte. The battery contains Li, with a total amount of Li in the battery 2 of 15 to 50 mg/Ah, as determined as the mass in terms of LiOH per Ah of the positive electrode capacity. The negative electrode includes particles of rare earth-Mg—Ni-based hydrogen storage alloy which contains a rare earth element, Mg and Ni. The hydrogen storage alloy particles 44 includes, on the surface thereof, a rare earth hydroxide which is the hydroxide of a rare earth element and has a specific surface area of 0.1 to 0.5 m2/g.

    Alkaline storage battery and method for manufacturing the alkaline storage battery

    公开(公告)号:US11876186B2

    公开(公告)日:2024-01-16

    申请号:US17158711

    申请日:2021-01-26

    Inventor: Akira Saguchi

    Abstract: An alkaline storage battery includes a spiral electrode group in which a positive electrode plate, a negative electrode plate, and a separator arranged between the positive electrode plate and the negative electrode plate are laminated, the negative electrode plate is located on the inner peripheral side of the positive electrode plate at an innermost peripheral portion, and an electrically conductive outer packaging can in which the spiral electrode group is accommodated together with an alkaline electrolytic solution. The negative electrode plate includes a negative electrode core body, a first negative electrode mixture layer carried on a surface on the outer peripheral side of the negative electrode core body, and a second negative electrode mixture layer carried on a surface on the inner peripheral side of the negative electrode core body. The negative electrode core body has a burr protruding toward the outer peripheral side at an edge portion of an innermost peripheral portion of the negative electrode core body. The thickness of the edge portion of an innermost peripheral portion of the first negative electrode mixture layer is smaller than the thickness of a portion other than the edge portion of the first negative electrode mixture layer. The height of the burr is 30% or less of the thickness of the separator.

    ALKALINE STORAGE BATTERY AND METHOD FOR MANUFACTURING THE ALKALINE STORAGE BATTERY

    公开(公告)号:US20210257674A1

    公开(公告)日:2021-08-19

    申请号:US17158711

    申请日:2021-01-26

    Inventor: Akira Saguchi

    Abstract: An alkaline storage battery includes a spiral electrode group in which a positive electrode plate, a negative electrode plate, and a separator arranged between the positive electrode plate and the negative electrode plate are laminated, the negative electrode plate is located on the inner peripheral side of the positive electrode plate at an innermost peripheral portion, and an electrically conductive outer packaging can in which the spiral electrode group is accommodated together with an alkaline electrolytic solution. The negative electrode plate includes a negative electrode core body, a first negative electrode mixture layer carried on a surface on the outer peripheral side of the negative electrode core body, and a second negative electrode mixture layer carried on a surface on the inner peripheral side of the negative electrode core body. The negative electrode core body has a burr protruding toward the outer peripheral side at an edge portion of an innermost peripheral portion of the negative electrode core body. The thickness of the edge portion of an innermost peripheral portion of the first negative electrode mixture layer is smaller than the thickness of a portion other than the edge portion of the first negative electrode mixture layer. The height of the burr is 30% or less of the thickness of the separator.

    Negative electrode for alkaline secondary battery, and alkaline secondary battery

    公开(公告)号:US11043664B2

    公开(公告)日:2021-06-22

    申请号:US16383048

    申请日:2019-04-12

    Abstract: A battery comprises an electrode group including a separator, a positive electrode and a negative electrode. The negative electrode comprises a negative electrode core, negative electrode mixture layers retained to the negative electrode core, and a fluorine resin layer disposed on the surface of the negative electrode mixture layers. The negative electrode mixture layers include a first outermost peripheral region located at the outermost periphery of the electrode group and a second outermost peripheral region located opposite to the first outermost peripheral region. When the amount of the fluorine resin constituting a first fluorine resin layer in a portion of the first outermost peripheral region is represented by A, and the amount of the fluorine resin constituting a second fluorine resin layer in a portion of the second outermost peripheral region is represented by B, a relation A>B is satisfied.

    Electrode for alkaline secondary battery and alkaline secondary battery

    公开(公告)号:US12183894B2

    公开(公告)日:2024-12-31

    申请号:US17653282

    申请日:2022-03-02

    Inventor: Akira Saguchi

    Abstract: An electrode has a band-shaped core and an electrode mixture layer carried by the core to form a spiral electrode assembly with a gas generating electrode and a separator for an alkaline secondary battery. The electrode in the spiral shape has a first circumference portion, an intermediate portion, and an outermost circumference portion. The first circumference portion is a starting portion for winding into the spiral shape. The intermediate portion is a second and following circumferences of the spiral shape. The outermost circumference portion has an inner surface only which faces the gas generating electrode. The electrode mixture layer includes a reactant that develops a reaction consuming gas generated from the gas generating electrode. An amount of the reactant in the first circumference portion is more than those in the intermediate portion and/or the outermost circumference portion.

    NEGATIVE ELECTRODE FOR NICKEL-HYDROGEN SECONDARY BATTERY, AND NICKEL-HYDROGEN SECONDARY BATTERY

    公开(公告)号:US20190305301A1

    公开(公告)日:2019-10-03

    申请号:US16357050

    申请日:2019-03-18

    Abstract: A nickel-hydrogen secondary battery includes an electrode group which contains a positive electrode, a negative electrode, and a separator, wherein the negative electrode includes a negative electrode core, and a negative electrode mixture layer held by the negative electrode core, wherein the negative electrode mixture layer contains a fluororesin; a quantity of the fluororesin, expressed by a mass applied per unit area of the negative electrode, is within a range of 0.2 mg/cm2 or more and 2.0 mg/cm2 or less; and a fluororesin content which is a ratio of the fluororesin contained in a unit volume of the negative electrode mixture layer is higher in an inner layer portion than in an outer layer portion in the negative electrode mixture layer.

    HYDROGEN ABSORBING ALLOY POWDER, AND NICKEL HYDROGEN SECONDARY BATTERY USING THE HYDROGEN ABSORBING ALLOY POWDER

    公开(公告)号:US20180248172A1

    公开(公告)日:2018-08-30

    申请号:US15549144

    申请日:2016-02-24

    Abstract: A nickel hydrogen secondary battery comprises an outer can and an electrode group accommodated in a hermetically sealed state together with an alkaline electrolyte solution in the outer can, wherein the electrode group comprises a positive electrode and a negative electrode stacked through a separator, wherein the negative electrode contains a hydrogen absorbing alloy powder that is an aggregate of particles of a hydrogen absorbing alloy, wherein the hydrogen absorbing alloy powder is such that when an average particle size of the particles is represented by M; a particle size of ½ of the M is represented by P; and a particle size of ⅓ of the M is represented by Q, a content of the particles having a particle size equal to or smaller than the P is lower than 20% by mass of the whole of the hydrogen absorbing alloy powder; and the content of the particles having a particle size equal to or smaller than the Q is lower than 10% by mass of the whole of the hydrogen absorbing alloy powder.

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