摘要:
Aziridinocarboxylic acid esters of polyols are manufactured by trans-esterification of the corresponding esters of lower alcohols, using magnesium oxide or calcium oxide as the trans-esterification catalyst; this method gives a higher yield and a purer product.
摘要:
A sample of a fuel/oil/additive mixture is metered continuously to a channel-like, inclined test element along which there is an increasing temperature profile. Under the increasing action of heat on the flowing mixture, solid residual products form on the test element after a certain flow distance. Their weight and the flow distance are evaluated in order to evaluate the additive.
摘要:
Serine-N,N-diacetic acid and derivatives thereof are prepared in various ways and used in particular as complexing agents, bleaching agent stabilizers and builders in detergents.
摘要:
Quaternized condensation products useful as aftertreating agents for fixing reactive dyeings and prints on textile materials which contain cellulose fibers are formed fromA) a precondensate of one or more trialkanolamines I ##STR1## (R.sup.1 -R.sup.3 =C.sub.2 -C.sub.4 -1,2-alkylene), B) a) a carboxylic acid or a derivative thereof IIa ##STR2## [n=0, 1; R.sup.4, R.sup.5 =OH (except if n=0), C.sub.1 -C.sub.8 -alkoxy (possibly joined together to form a 5- or 6-membered ring if n=0), Cl, Br; R.sup.6 =C.sub.1 -C.sub.50 -alkylene (possibly interrupted by one or more nonadjacent oxygen atoms)],b) a carboxamide IIb ##STR3## [m, n, r=0, 1; R.sup.7 =H, C.sub.1 -C.sub.4 -alkyl; R.sup.8 =H, C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkenyl, Ph (possibly substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, F, Cl, Br)],c) an epihalohydrin IIc, ##STR4## d) a monofunctional compound IIdR.sup.9 --Y IId [R.sup.9 =C.sub.1 -C.sub.25 -alkyl, C.sub.2 -C.sub.25 -alkenyl, Ph (possibly substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, F, Cl, Br); Y=isocyanate, OCONHR.sup.8, glycidyloxy],e) a bifunctional compound IIeZ.sup.1 --R.sup.10 --Z.sup.2 IIe [R.sup.10 =C.sub.a -C.sub.50 -alkylene (possibly interrupted by one or more nonadjacent oxygen atoms, possibly containing one or more mutually nonvicinal hydroxyl groups); Z.sup.1, Z.sup.2 =Cl, Br, isocyanate, NH--COOR.sup.9, glycidyloxy, OR.sup.9 ], andC) a benzyl halide III ##STR5## (p=0-2; R.sup.11 =C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, F, Cl, Br).
摘要:
Dyeings with reactive dyes on cellulose fiber materials are after-treated with an aqueous solution of a condensate which is obtainable by reacting (a) bisbenzylpiperzine with (b) ethylene chloride, an epihalohydrin, propylene chloride, 1,3-dichloro-2-hydroxypropane, bisepoxybutane or 1,4-dichlorobutane or a mixture of these, in a molar ratio of from 1:0.5 to 1:1.1, or by reacting (c) piperazine, bis-1,4-aminopropylpiperazine, 1-aminoethylpiperazine, 2-hydroxyethylpiperazine or 1-methylpiperazine, or a mixture of these, with a compound according to (b) in a molar ratio of from 1:0.5 to 1:1.1 and benzylating the condensate, the benzylation being carried out using 0.15-1.0 mole of benzyl chloride per equivalent of nitrogen in component (c). The cellulose fiber materials after-treated in this manner possess very good wetfastness.
摘要:
Petroleum demulsifiers which contain, as the active ingredients, oxyalkylated isoalkylphenol-formaldehyde resins and oxyalkylated polyalkylenepolyamines.
摘要:
Water-soluble benzylated polyamidoamines which contain from 0.1 to 0.9 mole of benzyl groups per equivalent of nitrogen, and onto which from 20 to 400 parts by weight of ethyleneimine or propyleneimine have been grafted per 100 parts by weight of polyamidoamine, processes for the preparation of the materials, and the use of the materials as cationic assistants in processes for coloring paper with acid dyes and/or direct dyes in an aqueous medium. The papers obtained show a high color strength, with substantially no two sidedness of the coloration.
摘要:
Process for the production of water-soluble auxiliaries for the papermaking industry by reacting(a) 1 part by weight of a polyamidoamine obtained by condensing 1 mole of a dicarboxylic acid having from 4 to 10 carbon atoms with from 0.8 to 1.4 moles of a polyalkylene polyamine having from 3 to 10 alkyleneamine units and containing up to 8 ethyleneimine units per basic nitrogen atom with (b) 0.1 to 4 parts by weight of an .alpha.,.omega.-dichloro polyalkylene oxide obtained by reacting a polyalkylene oxide having from 8 to 100 alkylene oxide units with a compound selected from the group consisting of a thionyl chloride and phosgene and then cleaving the reaction products by heating them to a temperature of from 70.degree. to 150.degree. C. in the presence of a tertiary amine as catalyst,as crosslinking agent, at a temperature above 20.degree. C. in aqueous solution or in a water-soluble organic solvent, the reaction being carried out to a point at which the viscosity of an aqueous solution containing 20% by weight of auxiliary is from 300 to 2,500 mPas.
摘要:
Water-soluble, crosslinked nitrogen-containing condensation products, the viscosity of which, in aqueous solution, increases with increasing temperature, are obtained by reacting a chlorohydrin-ether of the formula ##STR1## where x is from 50 to 250, y is from 20 to 100, the ratio x:y is from 6.1:1 to 1:15 and n is from 0.5 to 5, with ethyleneimine in the weight ratio of from 1:10.1 to 1:0.8; the condensation products are added to aqueous systems, e.g. polymer solutions and polymer dispersions, to improve the viscosity characteristics.
摘要:
Acrylonitrile polymer fibers are dyed level shades with basic dyes using as leveling agent a quaternary ammonium salt containing two or three benzyl groups as nitrogen ligands.