Abstract:
An electrochemical cell is presented. The cell includes a housing having an interior surface defining a volume, and an elongated separator disposed in the housing volume. The elongated separator defines an axis of the cell. The separator has an inner surface and an outer surface. The inner surface of the separator defines a first compartment. The outer surface of the separator and the interior surface of the housing define a second compartment having a volume. The cell further includes a conductive matrix disposed in at least a portion of the second compartment volume such that the conductive matrix occupies a gap between the outer surface of the separator and the interior surface of the housing. The gap in the second compartment extends in a direction substantially perpendicular to the axis of the cell.
Abstract:
An electrochemical cell is presented. The cell includes a housing formed of a metallic material. A component is disposed within an anode compartment of the cell that contains an alkali metal. The component comprises a sacrificial metal that has an oxidation potential less than the oxidation potential of the housing material. An energy storage device including such an electrochemical cell is also provided.
Abstract:
A system includes a primary source of power, a main battery, a reserve battery, and a battery management system. A method for operating the system is also disclosed. The main battery of the system is electrically connected to the article, and the reserve battery is configured to back-up the main battery. The battery management system is electrically connected to the main battery. The battery management system maintains the reserve battery in a dormant state when the primary source of power is operational. The reserve battery is also maintained at a dormant state when the primary source of power is not operational; and the main battery is discharging and able to effectively back-up the primary source of power in supplying power to the article.
Abstract:
A positive electrode composition is presented. The composition includes granules that comprise an electroactive metal, an alkali metal halide, and a metal sulfide composition that is substantially-free of oxygen. A molar ratio of the electroactive metal to an amount of sulfur in the metal sulfide composition is between about 1.5:1 and about 50:1. The positive electrode composition is substantially free of iron oxide, iron sulfate, cobalt oxide and cobalt sulfate. An energy storage device and a related energy storage system are also described.
Abstract:
A positive electrode composition is presented. The composition includes granules that comprise an electroactive metal, an alkali metal halide, sulfur and carbon. A molar ratio of the electroactive metal to an amount of sulfur in the composition is between about 1.5:1 and about 10:1. Carbon is present in an amount greater than about 0.1 and less than about 5 weight percent, based on a total weight of the granules. An energy storage device and a related energy storage system are also described.
Abstract:
A positive electrode composition is provided. The positive electrode composition includes at least one electroactive metal, a first alkali metal halide, an electrolyte comprising a complex metal halide having a second alkali metal halide; and sodium iodide. The electroactive metal is selected from the group consisting of nickel, cobalt, iron, zinc, tin, vanadium, niobium, manganese and antimony; and the first alkali metal halide and the second alkali metal halide independently comprise a halide selected from chlorine, bromine, and fluorine. The composition includes sodium iodide present in an amount in a range from about 0.1 weight percent to about 0.9 weight percent, based on a total weight of metal halides in the positive electrode composition. Related devices also form embodiments of this invention.