公开(公告)号：US09284270B2

公开(公告)日：2016-03-15

申请号：US13985236

申请日：2012-02-14

申请人： Dennis Hall ,  Nicolas Gernigon ,  Raed M. Al-Zoubi ,  Paul D. Thornton

发明人： Dennis Hall ,  Nicolas Gernigon ,  Raed M. Al-Zoubi ,  Paul D. Thornton

IPC分类号： C07F5/02 ,  C07D207/04 ,  C07D209/48 ,  C07F5/05 ,  C07D295/185 ,  C07D307/56 ,  B01J31/14

CPC分类号： C07D207/04 ,  B01J31/146 ,  B01J2231/4283 ,  C07D209/48 ,  C07D295/185 ,  C07D307/56 ,  C07F5/025 ,  C07F5/05

摘要： The present application provides methods and catalysts for activation of carboxylic acids for organic reactions. In particular, methods are disclosed for direct nucleophilic addition reactions, such as, amidation reactions with amines, cycloadditions, and conjugate additions, using boronic acid catalysts of formula I, II or III: Also included are novel boronic acid catalysts of formula IV, V and III:

摘要翻译： 本申请提供了用于活化羧酸用于有机反应的方法和催化剂。 具体地，公开了用于直接亲核加成反应的方法，例如与胺的酰胺化反应，环加成和偶联加成，使用式I，II或III的硼酸催化剂：还包括式IV的新型硼酸催化剂，V 和三：

公开(公告)号：US08822720B2

公开(公告)日：2014-09-02

申请号：US12669983

申请日：2008-09-05

申请人： Dennis Hall ,  Olivier Marion ,  Raed Al-Zoubi

发明人： Dennis Hall ,  Olivier Marion ,  Raed Al-Zoubi

IPC分类号： C07F5/02

CPC分类号： B01J31/146 ,  B01J2231/326 ,  B01J2231/44

摘要： The present disclosure describes operationally simple methods for the low temperature, catalytic activation of carboxylic acids for organic reactions, in particular for direct amidation reactions with amines. The methods involve the use of orthosubstituted arylboromc acids of the formula (I), wherein the groups R1 to R5 are as defined herein. In preferred embodiments R1 is halogen. The arylboromc acids catalyze nucleophilic 1,2-addition reactions, conjugate 1,4-addition reactions, and cycloaddition reactions, including Diels-Alder reactions involving α,β-unsaturated carboxylic acids.

摘要翻译： 本公开描述了用于有机反应的羧酸的低温催化活化的操作上简单的方法，特别是用于与胺的直接酰胺化反应。 所述方法包括使用式（I）的邻位取代的芳基硼酸，其中基团R 1至R 5如本文所定义。 在优选的实施方案中，R 1是卤素。 芳基硼酸催化亲核的1,2-加成反应，偶联的1,4-加成反应和环加成反应，包括涉及α，β-不饱和羧酸的Diels-Alder反应。

公开(公告)号：US20140142322A1

公开(公告)日：2014-05-22

申请号：US13985236

申请日：2012-02-14

申请人： Dennis Hall ,  Nicolas Gernigon ,  Raed Al-Zoubi ,  Paul D. Thornton

发明人： Dennis Hall ,  Nicolas Gernigon ,  Raed Al-Zoubi ,  Paul D. Thornton

IPC分类号： C07D207/04 ,  C07F5/02 ,  C07D209/48

CPC分类号： C07D207/04 ,  B01J31/146 ,  B01J2231/4283 ,  C07D209/48 ,  C07D295/185 ,  C07D307/56 ,  C07F5/025 ,  C07F5/05

摘要： The present application provides methods and catalysts for activation of carboxylic acids for organic reactions. In particular, methods are disclosed for direct nucleophilic addition reactions, such as, amidation reactions with amines, cycloadditions, and conjugate additions, using boronic acid catalysts of formula I, II or III: Also included are novel boronic acid catalysts of formula IV, V and III:

摘要翻译： 本申请提供了用于活化羧酸用于有机反应的方法和催化剂。 具体地，公开了用于直接亲核加成反应的方法，例如与胺的酰胺化反应，环加成和偶联加成，使用式I，II或III的硼酸催化剂：还包括式IV的新型硼酸催化剂，V 和三：

公开(公告)号：US20110255942A1

公开(公告)日：2011-10-20

申请号：US13170363

申请日：2011-06-28

申请人： Michael Harris ,  Kal Ugargol ,  Dennis Hall

发明人： Michael Harris ,  Kal Ugargol ,  Dennis Hall

IPC分类号： B65G67/50 ,  B23P19/00 ,  B23P23/00

CPC分类号： B65G69/182 ,  B65G67/42 ,  B65G67/50 ,  B65G69/186 ,  Y10T29/49716 ,  Y10T29/52

摘要： An apparatus for rotary dumping of rail cars, including a material receiving pit. A rotary rail car dumper includes a rotational frame supporting at least one baffle. The rotational frame is configured to dump a load from a rail car during rotational motion of the rotational frame between an upright position wherein the entire load is in the rail car and a dumping position wherein the load can exit the rail car. A backside airflow diverter is located beneath the rotational frame and includes a curved upper surface. A lower margin of the at least one baffle contacts the curved upper surface during at least part of the rotational motion of the rotational frame. A backside hood is located beneath the backside airflow diverter on the back side of the pit.

摘要翻译： 一种用于轨道车辆的旋转倾倒的装置，包括材料接收坑。 旋转轨道车辆翻斗车包括支撑至少一个挡板的旋转框架。 旋转框架被配置为在旋转框架的旋转运动期间将轨道车辆的负载转移在其中整个负载在轨道车厢中的直立位置和负载可以离开轨道车厢的倾倒位置之间。 背面气流分流器位于旋转框架下方并且包括弯曲的上表面。 至少一个挡板的下边缘在旋转框架的旋转运动的至少一部分期间接触弯曲的上表面。 背面罩位于坑背侧的背侧气流分流器下方。

公开(公告)号：US07988401B2

公开(公告)日：2011-08-02

申请号：US12822845

申请日：2010-06-24

申请人： Dennis Hall ,  Michael Harris ,  Kal Ugargol

发明人： Dennis Hall ,  Michael Harris ,  Kal Ugargol

IPC分类号： B65G67/50

CPC分类号： B65G69/182 ,  B65G67/42 ,  B65G67/50 ,  B65G69/186 ,  Y10T29/49716 ,  Y10T29/52

摘要： An apparatus for rotary dumping of rail cars, including a material receiving pit. A rotational frame is disposed at least partially in the pit, is configured to dump a load from a rail car during rotational motion. A backside airflow diverter is disposed within the pit along with a backside hood for removing contaminated air. At least one baffle contacts the upper surface of the backside airflow diverter during at least a portion of the rotational motion. The invention includes an end of hood close off panel extending substantially from a platen supporting wall to the backside air flow diverter or an end ring baffle that extends from a grizzly upwardly to approximately the perimeter of a supporting ring and from the backside airflow diverter toward a dump side of the pit whereby dust laden air is substantially prevented from escaping from the pit under the end ring baffle.

摘要翻译： 一种用于轨道车辆的旋转倾倒的装置，包括材料接收坑。 旋转框架至少部分地设置在凹坑中，构造成在旋转运动期间从轨道车辆倾倒负载。 背面气流分流器与用于去除污染空气的背面罩一起设置在坑内。 至少一个挡板在旋转运动的至少一部分期间接触背侧气流分流器的上表面。 本发明包括基本上从压盘支撑壁延伸到后侧空气流分流器的端盖封闭面板，或端壁环挡板，其从灰色向上延伸到大约支撑环的周边，并且从背侧气流分流器朝向 垃圾堆的一侧，从而基本上防止了灰尘的空气从端环挡板下方的坑中逸出。

公开(公告)号：US06960054B2

公开(公告)日：2005-11-01

申请号：US10159808

申请日：2002-05-31

申请人： Dennis Hall ,  Michael Harris ,  Kal Ugargol

发明人： Dennis Hall ,  Michael Harris ,  Kal Ugargol

IPC分类号： B65G69/18 ,  B65G67/50

CPC分类号： B65G67/42 ,  B65G67/50 ,  B65G69/186

摘要： A method and apparatus for controlling dust generated by the rotary dumping or rail cars may include one or more flexible baffles are provided to the back-side of a rotary dump frame to seal a portion of the material receiving pit during a portion of the rotary motion. The dust cloud generated by this dumping is retained in the pit for an increased time due to tumbling of the cloud induced by the baffles and other features of the facility. A plurality of intake ducts removes the dust cloud from the pit for transfer to a remote filtering facility.

摘要翻译： 用于控制由倾倒式或轨道车辆产生的灰尘的方法和装置可以包括一个或多个柔性挡板设置在旋转倾卸架的后侧以在旋转运动的一部分期间密封材料接收凹坑的一部分 。 这种倾倒产生的尘云由于挡板引起的云和设施的其他特征的翻滚而保留在坑中增加时间。 多个进气管道将灰尘云从坑中去除以转移到远程过滤设施。

公开(公告)号：US5980653A

公开(公告)日：1999-11-09

申请号：US787845

申请日：1997-01-23

申请人： Charles Walter Hershberger ,  Dennis Hall

发明人： Charles Walter Hershberger ,  Dennis Hall

IPC分类号： C22C19/03 ,  C22C19/05

CPC分类号： C22C19/058 ,  C22C19/03

摘要： A nickel-based alloy composition is disclosed comprising from about 0.05 to about 3 percent by weight beryllium; from about 1 to about 40 percent by weight copper; no greater than about 10 percent by weight chromium, the balance being nickel. The alloy composition may be adjusted to achieve a high, as-cast hardness alloy over a wide range of alloy component contents, or a moderate, as-cast hardness alloy useful for forming articles such as golf clubs which has relatively constant mechanical properties over a wide range of copper contents.