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公开(公告)号：US4139714A
公开(公告)日：1979-02-13
申请号：US812206
申请日：1977-07-01
IPC分类号： C07C69/74
CPC分类号： C07C67/343 , C07C2103/86
摘要： Norbornadiene and an acrylic acid ester, e.g. methyl acrylate, are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, an alkyl aluminum chloride and triphenylphosphine. The resulting codimer can be used as a precursor for missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O- wherein the R is an H or an alkyl containing up to 10 carbon atoms.
摘要翻译： 降冰片二烯和丙烯酸酯，例如 丙烯酸甲酯在由乙酰丙酮镍，烷基氯化铝和三苯基膦组成的三组分均相催化体系存在下进行催化共聚。 所得到的同源二聚体可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。
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12.发明授权Process for making codimers of norbornadiene and phenylacetylenes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和苯乙炔的共聚物的方法
公开(公告)号：US4132742A
公开(公告)日：1979-01-02
申请号：US842813
申请日：1977-10-17
CPC分类号： C07C2/42 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substituents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
摘要翻译： 降冰片二烯和苯乙炔及其氢化衍生物（II）的新型共聚物（I）及其氢化衍生物（II），其具有以下结构：其中R是氢，苯基或具有烷基取代基的苯基，R 1是具有烷基取代基的苯基或苯基 并公开了制备两者的方法。 Codimer（II）可用作这种燃料的高能燃料或稀释剂。 制备编码（I）的方法包括使降冰片二烯和苯基乙炔或二苯基乙炔与钴或钴乙酰丙酮化合物的催化剂体系，1,2-双二苯基膦基乙烷和烷基氯化铝反应。
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公开(公告)号：US4100216A
公开(公告)日：1978-07-11
申请号：US819445
申请日：1977-07-27
CPC分类号： C07C2/42
摘要： Norbornadiene and isoprene are catalytically codimerized to an olefinic codimer. Used is a three-component homogeneous catalytic system consisting of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. The codimer upon hydrogenation forms .beta.-methyltetramethylene nortricyclane having utility as a diluent for a high energy hydrocarbon missile fuel.
摘要翻译： 降冰片二烯和异戊二烯被催化同分异构化成烯属共聚体。 使用由钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝组成的三组分均相催化体系。 加氢时的同分子化形式可用作高能烃类导弹燃料的稀释剂的β-甲基四亚甲基核桃素。
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14.发明授权
公开(公告)号：US4222800A
公开(公告)日：1980-09-16
申请号：US964855
申请日：1978-11-30
CPC分类号： C10L1/04 , C07C13/64 , C07C5/03 , C07C5/29 , C07C2103/90 , C07C2521/04
摘要： The endo-endo olefinic hexacyclic dimer of 2,5-norbornadiene is isomerized using an acidic alumina catalyst. The isomerization temperatures ranges from between about an ambient temperature to about 300.degree. C. The isomerized product, after hydrogenation, can be used as a high density missile fuel.
摘要翻译： 使用酸性氧化铝催化剂将2,5-降冰片二烯的内 - 内烯烃六环二聚体异构化。 异构化温度范围为约环境温度至约300℃。氢化后的异构化产物可用作高密度导弹燃料。
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公开(公告)号：US4169864A
公开(公告)日：1979-10-02
申请号：US888906
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimers (I) of norbornadiene and phenylacetylenes and their hydrogenated derivatives (II), having the following structures ##STR1## wherein R is a hydrogen, a phenyl, or a phenyl having alkyl substitutents and R.sub.1 is a phenyl or a phenyl having alkyl substituents and processes for preparing both are disclosed. Codimer (II) can be used as a high energy fuel or a diluent for such a fuel. Process for making codimer (I) involves reacting norbornadiene and phenylacetylene or diphenylacetylene with a catalyst system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride.
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公开(公告)号：US4139715A
公开(公告)日：1979-02-13
申请号：US812207
申请日：1977-07-01
IPC分类号： C07C69/74
CPC分类号： C07C67/347 , C07C2103/86
摘要： Norbornadiene and an acrylic acid ester, e.g. methyl acrylate, are catalytically codimerized in the presence of a three-component homogeneous catalytic system consisting of nickel acetylacetonate, an alkyl aluminum chloride and 1,2-bisdiphenylphosphino ethane. The resulting codimer can be used as a precursor for missile fuel. The ester portion of the acrylic acid ester is the radical RCH.sub.2 O-- wherein the R is an H or an alkyl containing up to 10 carbon atoms.
摘要翻译： 降冰片二烯和丙烯酸酯，例如 丙烯酸甲酯在由乙酰丙酮镍，烷基氯化铝和1,2-双二苯基膦基乙烷组成的三组分均相催化体系的存在下进行催化共聚。 所得到的同源二聚体可用作导弹燃料的前体。 丙烯酸酯的酯部分是自由基RCH2O-，其中R是H或含有至多10个碳原子的烷基。
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17.发明授权Process for making codimers of norbornadiene and alkynes using a cobalt catalyst 失效使用钴催化剂制备降冰片二烯和炔烃的共聚物的方法
公开(公告)号：US4110409A
公开(公告)日：1978-08-29
申请号：US842812
申请日：1977-10-17
CPC分类号： C07C13/68 , C07C2/42 , C07C5/03 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl aluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
摘要翻译： 降冰片二烯和炔烃在钴或钴乙酰丙酮化合物，1,2-双二苯基膦基乙烷和烷基氯化铝的均相催化体系存在下进行催化同步化。 此外，公开了降冰片二烯和含有至少三个碳的炔烃的新型共聚物。 氢化后，得到的共混物可用作这种燃料的高能燃料或稀释剂。
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18.发明授权Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacyclic dimer 失效2,5-降冰片二烯饱和内 - 内六环二聚体的氢解
公开(公告)号：US4278823A
公开(公告)日：1981-07-14
申请号：US102726
申请日：1979-12-13
CPC分类号： C07C13/64 , C07C5/13 , C07C2103/90 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755
摘要： Hydrogenolysis of a saturated endo-endo dihydronorbornadiene hexacyclic dimer involves the use of a catalytic amount of a Group VIII metal and the presence of hydrogen. The resulting pentacyclic isomers can be used as a diluent for depressing the freezing point of the saturated hexacyclic dimer which is a component of a high density missile fuel.
摘要翻译： 饱和内消旋二氢龙脑二烯六环二聚体的氢解涉及使用催化量的VIII族金属和氢的存在。 所得到的五环异构体可用作抑制作为高密度导弹燃料组分的饱和六环二聚体的凝固点的稀释剂。
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公开(公告)号：US4229612A
公开(公告)日：1980-10-21
申请号：US7112
申请日：1979-01-29
申请人： Lewis W. Hall, Jr. , David L. Kerr , Elmer J. Hollstein , Harry K. Myers, Jr. , Abraham Schneider
发明人： Lewis W. Hall, Jr. , David L. Kerr , Elmer J. Hollstein , Harry K. Myers, Jr. , Abraham Schneider
摘要： The removal of color bodies from an olefinic or saturated endo-endo hexacyclic homodimer of norbornadiene or mixtures thereof is accomplished by the use of a serpentine clay. Also acid bentonite clay or a montmorillonite clay can be used to remove the color bodies from the saturated dimer. The saturated dimer has a high density and a high heat of combustion making it useful as a missile fuel. Removal of the color bodies avoids possible catalyst poisoning in the hydrogenation of the olefinic to the saturated dimer. Also removal of the color bodies from the saturated dimer eliminates the possible problem of a material precipitating out on engine turbine blades and causing maintenance or operational problems.
摘要翻译： 通过使用蛇纹石粘土来实现从降冰片二烯的烯属或饱和内六角六环同系二聚体或其混合物中去除着色体。 酸性膨润土或蒙脱石粘土也可用于从饱和二聚体中除去颜色体。 饱和二聚体具有高密度和高的燃烧热，使其可用作导弹燃料。 去除颜色体可以避免在烯烃氢化成饱和二聚体时催化剂中毒。 从饱和二聚体中去除颜色体也消除了在发动机涡轮叶片上析出物质并导致维护或操作问题的可能问题。
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公开(公告)号：US4169863A
公开(公告)日：1979-10-02
申请号：US888905
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
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