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公开(公告)号：US4294621A
公开(公告)日：1981-10-13
申请号：US141135
申请日：1980-04-16
申请人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
发明人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
CPC分类号： C01B25/322 , C01B25/325 , C09C1/02 , C01P2004/61 , C01P2006/12
摘要： The invention relates to the production of phosphorus-containing anticorrosive pigments with a particle size of at most 20 microns by reacting one or more calcium or magnesium compounds with phosphoric acid or acid alkali metal or ammonium phosphates by intimately mixing an aqueous suspension or solution of the reactants inside a dispersing means rotating at a speed of 3000 to 10,000 rpm. More particularly, fine pulverulent calcium and magnesium compounds are converted, with agitation, together with water and, if desired, a water-soluble alkanol to a homogeneous suspension or solution. The suspension or solution is intimately mixed, inside the dispersing means at 0.degree. to 40.degree. C. and in an approximately stoichiometric ratio, with the phosphoric acid or acid phosphate solution. Resulting and precipitated pigment is separated and dried under mild conditions while maintaining its content of water of crystallization. The anticorrosive pigment is comprised of a homogeneous mixture and/or mixed crystals of which 10 to 95 mol % is calcium hydrogen phosphate dihydrate, the balance being magnesium hydrogen phosphate trihydrate. An at least 55 weight % proportion consists of particles with a size of up to 5 microns with a BET-surface of at least 1 m.sup.2 /g.
摘要翻译： 本发明涉及通过使一种或多种钙或镁化合物与磷酸或酸性碱金属或铵磷酸盐反应，通过将下列物质的水性悬浮液或溶液紧密混合，从而生产粒径至多为20微米的含磷防腐颜料 分散装置内的反应物以3000至10,000rpm的速度旋转。 更具体地，精细的粉末状钙和镁化合物在搅拌下与水一起转化，如果需要，将水溶性链烷醇转化成均匀的悬浮液或溶液。 悬浮液或溶液在分散装置内在0℃至40℃下以大约化学计量比与磷酸或酸式磷酸盐溶液紧密混合。 将所得沉淀的颜料分离并在温和条件下干燥，同时保持其结晶水含量。 防腐颜料由均匀的混合物和/或其中10〜95摩尔％为磷酸氢钙二水合物的混合晶体组成，余量为磷酸氢二氢钙三水合物。 至少55重量％的比例由尺寸高达5微米，BET表面至少为1m 2 / g的颗粒组成。
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公开(公告)号：US4265776A
公开(公告)日：1981-05-05
申请号：US130156
申请日：1980-03-13
申请人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Klaus Sommer , Hans-Adolf Rohlfs , Karl Merkenich
发明人： Werner Gohla , Klaus Hestermann , Joachim Kandler , Horst-Dieter Wasel-Nielen , Klaus Sommer , Hans-Adolf Rohlfs , Karl Merkenich
CPC分类号： C11D3/365
摘要： The invention provides cleaning and detergent compositions which contain about 0.2 to 5 weight % of at least one compound of the general formula (I) ##STR1## in which R stands for a hydrogen atom or a methyl group and R.sub.1 stands for a hydrogen atom or an alkali metal or NH.sub.4 -ion.
摘要翻译： 本发明提供了包含约0.2至5重量％的至少一种通式（I）的化合物的清洁和洗涤剂组合物，其中R代表氢原子或甲基，R1代表氢原子或 碱金属或NH4-离子。
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公开(公告)号：US4189449A
公开(公告)日：1980-02-19
申请号：US924709
申请日：1978-07-14
IPC分类号： C07F9/54
CPC分类号： C07F9/5407
摘要： Quaternary phosphonium hydroxides of the general formula: ##STR1## in which R stands either for hydrogen or an aliphatic or aromatic hydrocarbon having 1 to 12 carbon atoms and n stands for 1 or 2, are made by reacting a di- or trimethylphosphine in an aqueous medium with an epoxide of the general formula ##STR2## in which R has the meaning given above. More specifically a pH-value of .gtoreq.12 is established in the aqueous medium by means of a base and the starting materials are mixed in said medium.
摘要翻译： 其中R代表氢或具有1至12个碳原子并且n代表1或2的脂族或芳族烃的通式为：其中R 1代表氢原子的第四季氢氧化鏻是通过二 - 或三甲基膦 在具有通式“IMAGE”（II）的环氧化物的水性介质中，其中R具有上述含义。 更具体地，通过碱在水性介质中建立> / = 12的pH值，并将起始材料混合在所述介质中。
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公开(公告)号：US3998886A
公开(公告)日：1976-12-21
申请号：US557926
申请日：1975-03-13
CPC分类号： C07F9/5304 , C07F3/10 , C07F9/5407
摘要： Production of halogen-containing tertiary phosphine oxides of the general formula (I) ##STR1## in which R.sub.1 stands for an alkyl, halogenoalkyl, alkenyl, halogenoalkenyl, alkinyl or halogenoalkinyl radical, each of these radicals containing from 1 to 18 carbon atoms, or stands for a cycloalkyl, a halogenated cycloalkyl, an aryl, a halogenated aryl, an aralkyl or a halogenated aralkyl radical, and X stands for halogen.The oxides are made by subjecting a compound of the general formula (II) ##STR2## in which R has the same meaning as R.sub.1 and X stands for halogen, to thermal treatment in the presence of hydrogen halide at atmospheric or at elevated pressure so as to split off water and formaldehyde in vapor form therefrom; by continuously freeing the resulting reaction mixture from the said components in vapor form; by terminating the reaction and thereafter stripping off the hydrogen halide from the reaction mixture by introducing an inert gas thereinto; and by purifying the remaining crude product by distillation or recrystallization.
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公开(公告)号：US3980711A
公开(公告)日：1976-09-14
申请号：US549174
申请日：1975-02-12
申请人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
发明人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
CPC分类号： C07F9/53
摘要： Methylphosphine oxides of the general formula (I) ##EQU1## are produced from hydroxymethylphosphines of the general formula (II) ##EQU2## in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl groups having from 1 to 18 carbon atoms, or carrying substituents being inert under the reaction conditions.The methylphosphine oxides are more particularly produced by subjecting the hydroxymethylphosphines to a rearrangement reaction with the aid of radical-yielding compounds.
摘要翻译： 由通式（I）R HOCH2-P ANGLE（II）R'的羟甲基膦制备通式（I）的二甲基膦氧化物。其中式R和R'各自为 代表具有1至18个碳原子的相同或不同的烷基 - ，环烷基 - ，芳烷基 - 或芳基，或在反应条件下携带取代基是惰性的。
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16.发明授权
公开(公告)号：US4308158A
公开(公告)日：1981-12-29
申请号：US36403
申请日：1979-05-07
CPC分类号： C11D3/06
摘要： The invention provides cleaning and detergent compositions containing about:5 to 30 weight % of a surfactant and10 to 30 weight % of a builder mixture consisting of alkali metal orthophosphate, alkali metal pyrophosphate, alkali metal tripolyphosphate and alkali metal melt phosphate, wherein the ratio by weight of the sum of orthophosphate, pyrophosphate and tripolyphosphate to melt phosphate is about 30:1 to 1:30, the ratio by weight of orthophosphate to pyrophosphate is about 10:1 to 1:10, and the ratio by weight of orthophosphate to tripolyphosphate is about 20:1 to 1:20, the balance being detergent auxiliaries and addends.
摘要翻译： 本发明提供了含有约5至30重量％的表面活性剂和10至30重量％的由碱金属正磷酸盐，碱金属焦磷酸盐，碱金属三聚磷酸盐和碱金属熔融磷酸盐组成的助洗剂混合物的清洁和洗涤剂组合物， 重量的正磷酸盐，焦磷酸盐和三聚磷酸盐之间的熔融磷酸盐的总量为约30:1至1:30，正磷酸盐与焦磷酸盐的重量比为约10:1至1:10，并且正磷酸盐与重量比 三聚磷酸盐约为20:1至1:20，其余为洗涤剂助剂和附加物。
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公开(公告)号：US4150058A
公开(公告)日：1979-04-17
申请号：US904027
申请日：1978-05-08
申请人： Klaus Hestermann , Gero Heymer
发明人： Klaus Hestermann , Gero Heymer
IPC分类号： C07F9/50
CPC分类号： C07F9/5004 , Y02P20/582
摘要： Alkyl phosphines are made. To this end, phosphorus in vapor form is reacted with steam and an alkyl amine at elevated temperature in contact with a carbon catalyst placed in a reactor, the reactants being used individually or in admixture with one another.
摘要翻译： 制备烷基膦。 为此，蒸气形式的磷与蒸汽和烷基胺在升高的温度下与放置在反应器中的碳催化剂接触，反应物单独使用或彼此混合使用。
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公开(公告)号：US4091078A
公开(公告)日：1978-05-23
申请号：US736556
申请日：1976-10-28
申请人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
发明人： Klaus Hestermann , Jurgen Stengel , Gero Heymer , Christian May
CPC分类号： C01B25/06
摘要： Phosphine is produced from elementary yellow phosphorus and an aqueous alkali metal hydroxide solution in the presence of an alcohol. The phosphine is more particularly made by using an alcohol having from 5 to 10 carbon atoms and a dissolving power for yellow phosphorus of more than 5 g/l; suspending the phosphorus with agitation in the said alcohol in a reaction zone; reacting the resulting suspension with the alkali metal hydroxide solution at temperatures lower than the boiling point of the alcohol; and collecting the resulting issuing gaseous phosphine.
摘要翻译： 在醇的存在下，由元素黄磷和碱金属氢氧化物水溶液生产磷化氢。 膦更特别地通过使用具有5至10个碳原子的醇和大于5g / l的黄磷的溶解力来制备; 在反应区内搅拌将磷悬浮在所述醇中; 在低于醇的沸点的温度下使得到的悬浮液与碱金属氢氧化物溶液反应; 并收集产生的发出的气态膦。
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公开(公告)号：US4073810A
公开(公告)日：1978-02-14
申请号：US549172
申请日：1975-02-12
申请人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
发明人： Klaus Hestermann , Bernd Lippsmeier , Gero Heymer
CPC分类号： C07F9/5086 , C07F9/54
摘要： Production of organophosphines of the general formula R.sub.n PH.sub.3-n, in which R stands for identical or different, substituted or unsubstituted alkyl, cycloalkyl or aralkyl groups having from 1 to 18 carbon atoms, preferably from 1 to 4 carbon atoms, more preferably from 1 to 2 carbon atoms, and n stands for a whole number within the range 1 and 3. The compounds are more particularly produced by continuously reacting hydrocarbon halides of the general formula RX, in which R has the meaning given hereinabove and X stands for halogen, especially for chlorine or bromine, with hydrogen phosphide, and primary or secondary organophosphines at temperatures within the range 100.degree. and 600.degree. C. and under pressures of up to 20 atmospheres in contact with a catalyst being placed in a reactor. Gaseous matter issuing from the reactor is cooled and the resulting organophosphonium halides (R.sub.n PH.sub.4-n)X are hydrolyzed in conventional manner to the corresponding organophosphines.
摘要翻译： 制备通式RnPH3-n的有机膦，其中R代表相同或不同的取代或未取代的具有1至18个碳原子，优选1至4个碳原子的烷基，环烷基或芳烷基，更优选1至 2个碳原子，n表示1和3范围内的整数。化合物更特别地通过连续反应通式RX的卤代烃，其中R具有上文给出的含义，X代表卤素，特别是 对于氯或溴，与磷化氢以及初级或次级有机膦在100℃和600℃的温度范围内以及在与置于反应器中的催化剂接触的情况下在高达20个大气压的压力下进行。 将从反应器排出的气态物质冷却，并将所得的有机鏻卤化物（RnPH4-n）X以常规方式水解成相应的有机膦。
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公开(公告)号：US4028421A
公开(公告)日：1977-06-07
申请号：US560890
申请日：1975-03-21
CPC分类号： C07F9/5004 , C07F9/5304
摘要： Production of tertiary (hydroxymethyl)-methylphosphine oxides of the general formula: ##STR1## in which R stands for a branched or unbranched, substituted or unsubstituted alkyl, cycloalkyl, aralkyl or aryl group having from 1 to 18 carbon atoms. To this end tertiary bis-(hydroxymethyl)-phosphines of the general formula ##STR2## in which R has the meaning given above, are subjected to a thermal rearrangement reaction at temperatures higher than about 90.degree. C or at temperatures within the range -10.degree. and +250.degree. C, in the presence of a catalyst.
摘要翻译： 制备通式为（Ⅰ）的叔（羟甲基） - 甲基氧化膦，其中R代表具有1至18个碳原子的支链或非支链，取代或未取代的烷基，环烷基，芳烷基或芳基。 为此，其中R具有上述含义的通式为“IMAGE”（II）的叔双（羟甲基） - 膦在高于约90℃的温度或在高于约90℃的温度下进行热重排反应 在-10℃和+ 250℃下，在催化剂存在下进行。
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