Method of manufacturing nickelous positive-electrode active material for
alkaline battery
    13.
    发明授权
    Method of manufacturing nickelous positive-electrode active material for alkaline battery 失效
    制造碱性电池用的正极活性物质的方法

    公开(公告)号:US5879835A

    公开(公告)日:1999-03-09

    申请号:US803416

    申请日:1997-02-20

    IPC分类号: C01G53/00 H01M4/52 H01M2/04

    摘要: A method of manufacturing a nickelous positive-electrode active material for an alkaline battery has a formation process in which nickel hydroxide and cobalt hydroxide are formed by adding an alkali metal hydroxide to a reaction system containing nickel ions and cobalt (II) ions. The method comprises at least one step of removing any oxidant which oxidizes the cobalt (II) ions into cobalt (III) ions, during or before the formation process. An expedient for the removal of the oxidant is, for example, to reduce and remove the oxidant by adding a reductant, such as L-ascorbic acid, to the reaction system. The reductant should preferably have an oxidation potential which is lower than the reduction potential of oxygen. Besides, the method should preferably comprise the step of removing the cobalt (III) ions, during or before the formation process.

    摘要翻译: 制造用于碱性电池的尼克斯正极活性物质的方法具有通过向含有镍离子和钴(II)离子的反应体系中加入碱金属氢氧化物形成氢氧化镍和氢氧化钴的形成方法。 该方法包括在形成过程中或之前除去将钴(II)离子氧化成钴(III)离子的任何氧化剂的至少一个步骤。 用于除去氧化剂的方法是例如通过向反应体系中加入还原剂如L-抗坏血酸来还原和除去氧化剂。 还原剂应优选具有低于氧的还原电位的氧化电位。 此外,该方法应优选包括在形成过程中或之前除去钴(III)离子的步骤。