公开(公告)号：US20210198113A1

公开(公告)日：2021-07-01

申请号：US17058004

申请日：2019-05-16

Applicant: IFP Energies nouvelles

Inventor： Raquel MARTINEZ FRANCO ,  Bogdan HARBUZARU

IPC: C01B39/02 ,  B01J29/80 ,  B01J29/70 ,  C01B39/48

Abstract: The present invention relates to a process for preparing a zeolite composite material composed of a mixture of AFX and BEA zeolites, comprising at least the following steps: i) mixing in aqueous medium, in particular proportions, of an FAU zeolite having an SiO2/Al2O3 mole ratio of between 30 and 100 and a parameter Pze such that: 3250

公开(公告)号：US20240351895A1

公开(公告)日：2024-10-24

申请号：US18291749

申请日：2022-07-07

Applicant: IFP ENERGIES NOUVELLES

Inventor： Souad RAFIK-CLEMENT ,  Bogdan HARBUZARU

IPC: C01B39/32

CPC classification number: C01B39/32 ,  C01P2002/72 ,  C01P2006/21

Abstract: The present invention relates to a method for the preparation of a microporous material shaped in the form of extrudates, tablets or beads having good mechanical crush strength and containing at least 90% by weight of KL zeolite (structural type LTL). This method comprises a stage of shaping a KL zeolite with at least one zeolitizable binder and at least one stage of zeolitization, in the presence of potassium hydroxide in one and/or the other of the stages, in order to obtain a material shaped in the form of extrudates, tablets or beads containing at least 90% by weight of KL zeolite and good mechanical crush strength.

公开(公告)号：US20210388272A1

公开(公告)日：2021-12-16

申请号：US17292158

申请日：2019-10-21

Applicant: IFP Energies Nouvelles

Inventor： Bogdan HARBUZARU ,  Sylvie LACOMBE ,  Jacques LAVY ,  Christophe VALLEE ,  Pierre-Yves LE GOFF ,  Kevin DEBOLT

IPC: C10G35/085 ,  B01J35/10 ,  B01J21/04 ,  B01J37/02 ,  B01J37/18 ,  B01J6/00 ,  B01J23/42 ,  B01J8/02 ,  B01J35/02

Abstract: Process for fixed-bed reforming of a hydrocarbon-based feedstock comprising n-paraffinic, naphthenic and aromatic hydrocarbons, at a temperature of between 400 and 700° C., a pressure of between 0.1 and 4 MPa, and a mass flow of feedstock treated per unit mass of catalyst and per hour of between 0.1 and 10 h−1, by bringing said feedstock into contact with a catalyst comprising platinum, a promoter metal selected from the group consisting of rhenium and iridium, a halogen selected from the group consisting of fluorine, chlorine, bromine and iodine, and a porous alumina support in the form of an extrudate characterized by a length “l” of between 1 and 10 mm, a section comprising four lobes, the largest diameter “D” of the cross section of said extrudate being between 1 and 3 mm.

公开(公告)号：US20210188651A1

公开(公告)日：2021-06-24

申请号：US17057364

申请日：2019-05-16

Applicant: IFP Energies nouvelles

Inventor： Raquel MARTINEZ FRANCO ,  Bogdan HARBUZARU

IPC: C01B39/48 ,  C07D211/14

Abstract: The invention relates to a process for preparing an AFX-structure zeolite comprising at least the following steps:
i) mixing, in an aqueous medium, an FAU-structure zeolite having an SiO2 (FAU)/Al2O3 (FAU) molar ratio of between 6.00 and 200, limits included, an organic nitrogenous compound R, at least one source of at least one alkali and/or alkaline-earth metal M, the reaction mixture having the following molar composition: (SiO2 (FAU))/(Al2O3 (FAU)) between 6.00 and 200, H2O/(SiO2 (FAU)) between 1.00 and 100, R/(SiO2(FAU)) between 0.01 and 0.60, M2/nO/(SiO2(FAU)) between 0.005 and 0.45, limits included, until a homogeneous precursor gel is obtained;
ii) hydrothermal treatment of said precursor gel obtained on conclusion of step i) at a temperature of between 120° C. and 220° C., for a time of between 12 hours and 15 days.

公开(公告)号：US20200156949A1

公开(公告)日：2020-05-21

申请号：US16631910

申请日：2018-07-12

Applicant: IFP Energies nouvelles

Inventor： David BERTHOUT ,  Bogdan HARBUZARU ,  Eric LLIDO

IPC: C01B39/06 ,  C01B39/48 ,  B01J37/02 ,  B01J37/04 ,  B01J35/04 ,  B01J29/035 ,  B01J6/00 ,  B01J29/70

Abstract: The invention concerns a process for preparing a copper-comprising microporous aluminosilicate material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, a TETA or TEPA organic complexing agent and a DABCO-C4 structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with stirring in order to obtain crystallization of said copper-comprising microporous aluminosilicate material with AFX structure.