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公开(公告)号:US20180287149A1
公开(公告)日:2018-10-04
申请号:US15525034
申请日:2015-11-18
发明人: Young Pil Choi , Cheol Ho Park , Min Hyun Kim , Myeong Han Kim , Seon Kyong Kim
IPC分类号: H01M4/38 , H01M10/052
摘要: Disclosed is a negative active material, which has a small change in a volume during charge/discharge, has enhanced initial efficiency and capacity maintenance characteristics. A fine crystalline region exists on a matrix of an alloy, and lithium is more easily dispersed due to the fine crystalline region. The negative active material for a secondary battery has an improved expansion rate, and is formed by a formula below, and its expansion rate after 50 cycles is 70 to 150%, and an amorphization degree on a matrix within an alloy has a range of 25% or more, and Si has a range of 60 to 70%, Ti has a range of 9 to 14%, Fe has a range of 9 to 14%, and Al has a range larger than 1% and less than 20%. Formula: SixTiyFezAlu (x, y, z, and u are at %, x is 1−(y+z+u))
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12.
公开(公告)号:US20180190977A1
公开(公告)日:2018-07-05
申请号:US15738666
申请日:2016-05-31
发明人: Cheol Ho Park , Min Hyun Kim , Young Pil Choi , Seon Kyong Kim
IPC分类号: H01M4/36 , H01M4/38 , H01M10/052
CPC分类号: H01M4/366 , H01M4/134 , H01M4/362 , H01M4/386 , H01M4/62 , H01M10/052 , H01M2004/027
摘要: Provided are a negative electrode active material for a secondary battery, in which a silicon-based negative electrode active material is formed in a three-layer structure including an amorphous matrix, thereby suppressing a dispersal phenomenon of the negative electrode active material during charging/discharging. The negative electrode active material having a three-layer structure includes: a silicon (Si) layer; an amorphous matrix layer outside the Si layer; and a nano grain matrix layer formed on an interface between the Si layer and the amorphous matrix layer.
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13.
公开(公告)号:US20180175380A1
公开(公告)日:2018-06-21
申请号:US15738649
申请日:2016-05-31
发明人: Cheol Ho Park , Min Hyun Kim , Young Pil Choi , Seon Kyong Kim
IPC分类号: H01M4/36 , H01M4/38 , H01M10/0525 , C01B33/037
CPC分类号: H01M4/366 , C01B33/037 , C01P2002/70 , H01M4/134 , H01M4/1395 , H01M4/362 , H01M4/386 , H01M10/052 , H01M10/0525 , H01M2004/027
摘要: Provided are a negative electrode active material for a secondary battery, which suppresses a dispersal phenomenon of a negative electrode active material during charging/discharging by controlling a lattice mismatch ratio of an amorphous matrix layer to a silicon layer in a silicon-based negative electrode active material.
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