公开(公告)号：US4764175A

公开(公告)日：1988-08-16

申请号：US897445

申请日：1986-08-15

Applicant: Jacky Dore ,  Reinhard Pedrazzi

Inventor： Jacky Dore ,  Reinhard Pedrazzi

IPC: C09B29/16 ,  C09B29/30 ,  C09B31/072 ,  C09B31/08 ,  C09B43/16 ,  C09B44/08 ,  C09B45/16 ,  C09B45/18 ,  C09B45/28 ,  D06P1/41 ,  D06P1/06 ,  D06P3/32

CPC classification number: C09B44/08 ,  C09B43/16 ,  D06P1/41 ,  Y10S8/918 ,  Y10S8/919

Abstract: Metal-free compounds of the formula, ##STR1## and 1:1 copper complexes of metallizable metal-free compounds of said formula and internal and external salts of metal-free compounds of said formula and of 1:1 copper complexes of metallizable metal-free compounds of said formula, whereineach Q is independently linear or branched C.sub.2-6 alkylene; linear or branched C.sub.2-6 alkylene interrupted by --O--, --S-- or --NR.sub.4 --; linear or branched C.sub.3-6 alkylene monosubstituted or disubstituted by hydroxy or --*NHCO--CH.sub.2 --, wherein the * denotes the atom attached to the --NR.sub.4 -- radical,each R.sub.1 is independently hydrogen, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino, --SO.sub.2 NR.sub.3 R.sub.4, --CONR.sub.4 --C.sub.6 H.sub.5 or benzamido,R.sub.2 is hydrogen, hydroxy, halo, nitro, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, (C.sub.1-4 alkyl)carbonylamino or --NHCONR.sub.3 R.sub.4,X is --NR.sub.5 R.sub.6 or --N.sup..sym. R.sub.7 R.sub.8 R.sub.9 An.sup..crclbar., wherein R.sub.5 -R.sub.9 and An.sup..crclbar. are as defined in the specification, andn is 0 or 1whereineach R.sub.3 is independently hydrogen, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by hydroxy, halo, cyano or C.sub.1-4 alkoxy, andeach R.sub.4 is independently hydrogen or C.sub.1-4 alkyl, are useful, as such and in the form of solid and liquid aqueous dye preparations as direct dyes for dyeing or printing hydroxy-group or nitrogen-containing organic substrates, such as textiles consisting of or containing cellulose, leather and especially paper; they are also suitable for dyeing glass and products thereof and in inks.

Abstract translation: 所述式的金属化合物，所述式的金属化无金属化合物和所述式的金属化合物的内部和外部盐与1：1铜的金属化合物， + TR＆lt; IMAGE＆gt;和1： 所述式的可镀金属的无金属化合物的络合物，其中每个Q独立地为直链或支链的C 2-6亚烷基; 由-O - ， - S-或-NR4-间隔的直链或支链C 2-6亚烷基; 被羟基或 - * NHCO-CH2-单取代或二取代的直链或支链C 3-6亚烷基，其中*表示与-NR 4 - 基团连接的原子，每个R 1独立地为氢，卤素，硝基，C 1-4烷基，C 1-4烷氧基 ，（C 1-4烷基）羰基氨基，-SO 2 NR 3 R 4，-CONR 4 -C 6 H 5或苯甲酰氨基，R 2是氢，羟基，卤素，硝基，C 1-4烷基，C 1-4烷氧基，（C 1-4烷基）羰基氨基或-NHCONR 3 R 4，X是-NR 5 R 6 或-N（+）R 7 R 8 R 9 An（ - ），其中R 5 -R 9和An（ - ）如说明书中所定义，并且n为0或1，其中每个R 3独立地为氢，C 1-4烷基或被单个取代的C 1-4烷基 羟基，卤素，氰基或C 1-4烷氧基，并且每个R 4独立地是氢或C 1-4烷基，可以这样使用，并且是固体和液体水性染料制剂的形式，作为用于染色或印刷羟基或氮 - 包含有机基材，如由纤维素，皮革和特别是纸组成的纤维素或纺织品; 它们也适用于对玻璃及其产品和油墨进行染色。

公开(公告)号：US4742161A

公开(公告)日：1988-05-03

申请号：US735831

申请日：1985-05-20

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B35/031 ,  C09B35/378 ,  C09B43/16 ,  C09B44/08 ,  C09B35/18 ,  C09B35/20 ,  C09B35/35 ,  C09B44/02

CPC classification number: C09B44/08 ,  C09B35/031 ,  C09B35/378 ,  C09B43/16

Abstract: Disazo and trisazo compounds of the formula ##STR1## and salts thereof, wherein in each B is independently hydrogen; C.sub.1-4 alkyl; (C.sub.1-4 alkoxy) C.sub.1-4 alkyl; C.sub.2-4 hydroxyalkyl; C.sub.5-6 cycloalkyl; C.sub.5-6 cyloalkyl substituted by 1 to 3 C.sub.1-4 alkyls; phenyl (C.sub.1-3 alkyl); phenyl (C.sub.1-3 alkyl) the phenyl group of which is substituted by 1 to 3 substituents selected from C.sub.1-4 alkyl, C.sub.1-4 alkoxy and halo; --A--NH--R.sub.2 ; --A.sub.2 --N(R.sub.7).sub.2 ; --A.sub.N.sup..crclbar. (R.sub.8).sub.2 R.sub.9 A.sup..sym. or --N(R.sub.7).sub.2,whereinA, A.sub.1, A.sub.2 and R.sub.7 -R.sub.9 are as defined in the specification,each R is independently hydrogen; amino C.sub.1-4 alkyl; C.sub.5-6 cycloalkyl; C.sub.5-6 cycloalkyl substituted by 1 or 2 C.sub.1-4 alkyls; phenyl; benzyl; phenylethyl; or phenyl, benzyl or phenylethyl the phenyl group of which is substituted by 1 or 2 substituents selected from methyl, ethyl, methoxy and ethoxy,each R.sub.5 is independently hydrogen or C.sub.1-4 alkyl,each T is indendently hydrogen, cyano, halo, --COOR.sub.4, --CON(R.sub.5).sub.2, --SO.sub.2 N(R.sub.5).sub.2, --CH.sub.2 --NH--CO--CH.sub.2 --N(R.sub.7).sub.2, --CH.sub.2 --NH--CO--CH.sub.2 --N.sup..crclbar. (R.sub.8).sub.2 R.sub.9 A.sup..sym., ##STR2## wherein R.sub.1, R.sub.3 -R.sub.9, R.sub.13, R.sub.14 and X.sub.a are as defined in the specification,X.sub.o is a divalent or trivalent bridging radical,each a is independently 0 or 1, with the proviso that at least 2 a's are 1, andn is d or 3,wherein each A.sup..sym. is independently a non-chromophoric anion, with the provisos that (i) the total number of basic and cationic groups is at least three and equals or exceeds the number of sulfo groups and (ii) each azo radical is in the 3- or 4-positions,are useful as dyes for dyeing and printing paper and textile materials

Abstract translation: 式“IMAGE”的双偶氮和三偶氮化合物及其盐，其中每个B独立地为氢; C 1-4烷基; （C 1-4烷氧基）C 1-4烷基; C2-4羟烷基; C5-6环烷基; 被1至3个C 1-4烷基取代的C 5-6环烷基; 苯基（C 1-3烷基）; 苯基（C 1-3烷基），其苯基被1至3个选自C 1-4烷基，C 1-4烷氧基和卤素的取代基取代; -A-NH-R2; -A2-N（R7）2; -AN（ - ）（R8）2R9A（+）或-N（R7）2，其中A，A1，A2和R7-R9如说明书中所定义，各R独立地为氢; 氨基C 1-4烷基; C5-6环烷基; 被1或2个C 1-4烷基取代的C 5-6环烷基; 苯基; 苄基; 苯乙基 或苯基，苯基或苯乙基，其苯基被1或2个选自甲基，乙基，甲氧基和乙氧基的取代基取代，每个R 5独立地为氢或C 1-4烷基，每个T为氢，氰基，卤素，-COOR 4 ，-CON（R5）2，-SO2N（R5）2，-CH2-NH-CO-CH2-N（R7）2，-CH2-NH-CO-CH2-N（ - ）（R8） 其中R1，R3-R9，R13，R14和Xa如说明书中所定义，Xo是二价或三价桥连基，每个a独立地为0或1，其中 条件是至少2个a为1，n为d或3，其中每个A（+）独立地为非发色阴离子，条件是（i）碱性和阳离子基团的总数至少为3， 等于或超过磺基数，（ii）每个偶氮基在3-或4-位，可用作染色和印刷纸和纺织材料的染料

公开(公告)号：US4618673A

公开(公告)日：1986-10-21

申请号：US304621

申请日：1981-09-22

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/16 ,  C09B45/06 ,  D06P1/10

CPC classification number: C09B45/16

Abstract: Asymmetric 1:2 chromium complexes of the formula, ##STR1## in which A is a group of the formula ##STR2## in which X is halogen, nitro or methyl,Y is hydrogen or nitro,* designates the carbon atom bound to the azo group,each Z is halogen or nitro, both substituents being the same, each of R.sub.1 and R.sub.2, independently, is phenyl or phenyl substituted by a total of up to three substituents selected from halogen, C.sub.1-6 alkyl, C.sub.1-6 alkoxy, nitro and cyano (maximum of two nitro and/or cyano), andM.sup..sym. is hydrogen or an equivalent of a non-chromophoric cation, with the proviso that the sulpho group is in salt form, and mixtures of two or more of such 1:2 asymmetric complexes, which complexes and mixtures are useful for dyeing nitrogen-containing organic substrates e.g., natural and synthetic polyamides such as wool, silk and nylon, polyurethanes and leather. The dyes build-up well and the obtained dyeings exhibit notable fastness to light, wet treatments, rubbing, ironing, wool chlorination, acids and alkalis and resistance to carbonization. Some of the dyes are also useful in printing lacquers and ball-point pen inks and for dyeing metals such as anodized aluminum.

Abstract translation: 不对称1：2的下式的铬配合物，其中A是式（ⅩⅩⅥ）基团，其中X是卤素，硝基或甲基，Y是氢或硝基，*表示与偶氮键合的碳原子 基团，每个Z是卤素或硝基，两个取代基相同，R 1和R 2各自独立地是苯基或被总数最多三个选自卤素，C 1-6烷基，C 1-6烷氧基，硝基的取代基取代的苯基或 氰基（最多两个硝基和/或氰基），M（+）​​是氢或非发色阳离子的当量，条件是磺基是盐形式，并且两个或更多个这样的1 ：2种不对称配合物，其复合物和混合物可用于染色含氮有机基材，例如天然和合成聚酰胺如羊毛，丝绸和尼龙，聚氨酯和皮革。 染料积聚良好，得到的染色剂具有显着的耐光牢度，湿润处理，摩擦，熨烫，羊毛氯化，酸和碱，耐碳化。 一些染料也可用于印刷漆和圆珠笔墨水和用于染色金属如阳极氧化铝。

公开(公告)号：US4155903A

公开(公告)日：1979-05-22

申请号：US681966

申请日：1976-04-30

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C07F15/06 ,  C07C67/00 ,  C07C301/00 ,  C07C309/47 ,  C09B45/02 ,  C09B45/20 ,  C09B45/48 ,  D06P1/10

CPC classification number: C09B45/20 ,  C09B45/487 ,  D06P1/10

Abstract: Disclosed are homogeneous complexes of the formula ##STR1## wherein R.sub.1 is hydrogen, alkyl, phenyl or substituted phenyl, ##STR2## WHEREIN ONE Q is hydrogen and the other is sulfo, and N IS 0 OR 1 (THE SULFO GROUP BEING IN THE 5- OR 6-POSITION WHEN N IS 1),R.sub.4 is hydrogen, alkyl, alkoxy, chloro, bromo or nitro,R.sub.5 is hydrogen, alkyl, alkoxy, chloro, bromo, nitro or sulfo,With the proviso that when one of R.sub.4 and R.sub.5 is hydrogen, the other is other than hydrogen and is in the 4- or 5-position and when both are other than hydrogen, one is in the 4-position and the other is in the 5- or 6-position,One of R.sub.6 and R.sub.7 is hydrogen, chloro or nitro and the other is hydrogen, sulfamoyl or substituted sulfamoyl, and ##STR3## wherein one of R.sub.10 and R.sub.11 is hydrogen and the other is hydrogen, chloro, alkyl, alkoxy or trifluoromethyl,R.sub.12 is hydrogen or methyl,R.sub.13 is methyl, chloro or bromo, with the proviso that R.sub.12 is hydrogen when R.sub.13 is chloro or bromo,Y.sub.1 is hydrogen or acylamino,Y.sub.2 is hydrogen, alkyl, alkoxy, chloro or bromo,Y.sub.3 is hydrogen or 5- or 6-sulfamoyl, alkylsulfamoyl or hydroxyalkylsulfamoyl, andM.sup..sym. is hydrogen or a non-chromophoric cation,wherein the asterisks indicate the carbon atom attached to the azo group,with the proviso that the complex contains a single sulfamoyl or substituted sulfamoyl group and a single sulfo group which is in salt form,and mixtures of such complexes. The complexes and mixtures are useful for dyeing and printing nitrogen-containing organic substrates, for example, polyamides such as wool, silk and nylon, polyurethanes and leather.

Abstract translation: 公开了下式的均匀络合物，其中R1是氢，烷基，苯基或取代的苯基，其中一个Q是氢，另一个是磺基，N是0或1（苏联组在5 - 当N为1时，OR 6位，R 4为氢，烷基，烷氧基，氯，溴或硝基，R 5为氢，烷基，烷氧基，氯，溴，硝基或磺基， R5是氢，另一个不是氢并且在4-或5-位，当两者都不是氢时，一个在4-位，另一个在5-或6-位，其中一个 R 6和R 7是氢，氯或硝基，另一个是氢，氨磺酰基或取代的氨磺酰基，其中R 10和R 11之一是氢，另一个是氢，氯，烷基，烷氧基 或三氟甲基，R 12是氢或甲基，R 13是甲基，氯或溴，条件是当R 13是氯或溴时，R 12是氢，Y1是氢或酰基 不是，Y 2是氢，烷基，烷氧基，氯或溴，Y + HD 3是氢或5-或6-氨磺酰基，烷基氨磺酰基或羟烷基氨磺酰基，M（+）​​是氢或非发色阳离子，其中星号表示 附着于偶氮基团的碳原子，条件是络合物含有单个氨磺酰基或取代的氨磺酰基和盐形式的单个磺基，以及这些络合物的混合物。 复合物和混合物可用于染色和印刷含氮有机基材，例如聚酰胺如羊毛，丝绸和尼龙，聚氨酯和皮革。