公开(公告)号：US4005067A

公开(公告)日：1977-01-25

申请号：US583335

申请日：1975-06-02

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/01 ,  C07C119/00 ,  C07C131/00 ,  C09B45/10 ,  C09B45/20

CPC classification number: C09B45/01

Abstract: By metallization of metallizable monoazo or azomethine dyes with cobalt-donating compounds in the presence of a nitrite, especially NaNO.sub.2, 1:1 cobalt complexes containing a nitrite ion are obtained in a high degree of metallization which can be reacted with metallizable monoazo or azomethine dyes to give very homogeneous 2:1 cobalt complexes in a high degree of purity. This is particularly advantageous when asymmetrical 2:1 cobalt complexes are to be prepared. The process is particularly useful for the preparation of nitrite ion-containing 1:1 complexes of cobalt and a monoazo compound of the formula ##STR1## wherein X is --OH or --NHR,wherein R is hydrogen or a substituted or unsubstituted alkyl, cycloalkyl, phenyl or naphthyl group,Ring A is further unsubstituted or further substituted by at least one halo, nitro or optionally substituted alkyl, alkoxy or sulfamoyl substituent, andThe naphthalene ring is further unsubstituted or further substituted by at least one hydroxy, sulfamoyl or acylamino substituent.

Abstract translation: 通过在亚硝酸盐，特别是NaNO 2的存在下，可金属化的单偶氮或偶氮甲碱染料与提供钴的化合物进行金属化，可以以高度的金属化形式获得含有亚硝酸根离子的1:1钴络合物，其可与可金属化的单偶氮或偶氮甲碱染料 以高纯度得到非常均匀的2:1钴络合物。 当制备不对称的2:1钴络合物时，这是特别有利的。 该方法特别可用于制备含有亚硝酸根离子的1：1络合物的钴和下式的单偶氮化合物，其中X是-OH或-NHR，其中R是氢或取代或未取代的烷基，环烷基 苯基或萘基，环A进一步未被取代或被至少一个卤素，硝基或任选取代的烷基，烷氧基或氨磺酰基取代基进一步取代，并且由至少一个羟基，磺酰基或亚氨基取代的萘磺环进一步取代或进一步取代 替补。

公开(公告)号：US5563249A

公开(公告)日：1996-10-08

申请号：US493078

申请日：1995-06-21

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C07D277/82 ,  C09B29/00 ,  C09B29/045 ,  C09B29/28 ,  C09B29/30 ,  D06P1/39 ,  D06P3/24

CPC classification number: C09B29/28 ,  C09B29/0088 ,  Y10S8/924

Abstract: Acidic monoazo dyestuffs of formula I ##STR1## and their salts wherein the symbols R.sub.1 to R.sub.6, which possess the significances given in claim 1. These dyestuffs are suitable for dyeing or printing textile material consisting of natural or synthetic polyamides.

Abstract translation: 具有式I的酸性单偶氮染料及其盐，其中符号R1至R6具有权利要求1中给出的含义。这些染料适用于染色或印刷由天然或合成聚酰胺组成的织物材料。

公开(公告)号：US4742160A

公开(公告)日：1988-05-03

申请号：US834976

申请日：1986-02-28

Applicant: Jacky Dore ,  Reinhard Pedrazzi

Inventor： Jacky Dore ,  Reinhard Pedrazzi

IPC: C09B35/039 ,  C09B43/16 ,  C09B44/02 ,  C09B44/06 ,  C09B45/24 ,  C09B62/095 ,  D06P1/02 ,  D06P1/41 ,  D06P3/32 ,  D21H19/10 ,  D21H21/28 ,  C09B35/18 ,  C09B44/08 ,  C09B45/26

CPC classification number: D06P3/3226 ,  C09B43/16 ,  C09B44/02 ,  C09B62/095 ,  D06P1/02 ,  D21H21/28

Abstract: Metal-free compounds of the formula ##STR1## and 1:1 and 1:2 metal complexes thereof, and salts of the metal-free compounds and 1:1 and 1:2 metal complexes, whereR is hydrogen, --SO.sub.3 H or --NR.sub.5 R.sub.6 ;R.sub.a is hydrogen or --NR.sub.5 R.sub.6 ;R.sub.1 is hydrogen, halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --SO.sub.3 H;R.sub.3 is hydrogen or C.sub.1-4 alkyl;R.sub.4 is halogen, --OH, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, phenyl, --NH.sub.2, an aliphatic, cycloaliphatic or aromatic amino group, a heterocyclic amino group containing 1 to 3 hereto atoms or a hydrazino group,R.sub.5 is hydrogen or C.sub.1-4 alkyl; andR.sub.6 is an organic radical, are useful as cationic dyes for dyeing and printing fibers, threads and textile materials comprising, for example, a natural or regenerated cellulosic material such as cotton, a modified synthetic polyamide or polyester, and a homo- or co-polymer of acrylonitrile or 1,1-dicyanoethylene, bast fibers such as hemp and particularly paper and leather.

Abstract translation: 具有式 + TR＆lt; IMAGE＆gt;和1：1和1：2金属络合物的金属化合物和无金属化合物和1：1和1：2金属络合物的盐，其中 R为氢，-SO 3 H或-NR 5 R 6; Ra是氢或-NR5R6; R 1是氢，卤素，-OH，C 1-4烷基，C 1-4烷氧基或-SO 3 H; R3是氢或C1-4烷基; R 4是卤素，-OH，C 1-4烷基，C 1-4烷氧基，苯基，-NH 2，脂族，脂环族或芳族氨基，含有1至3个原子的杂环氨基或肼基，R5是氢或C1- 4个烷基; 并且R6是有机基团，可用作染色和印刷纤维，丝线和纺织材料的阳离子染料，其包括例如天然或再生纤维素材料如棉，改性合成聚酰胺或聚酯，以及均聚物或共聚物 丙烯腈或1,1-二氰基乙烯的聚合物，诸如大麻，特别是纸和皮革的韧皮纤维。

公开(公告)号：US4051116A

公开(公告)日：1977-09-27

申请号：US533521

申请日：1974-12-17

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/20 ,  C09B45/10 ,  C09B45/30 ,  D06P1/10

CPC classification number: C09B45/20

Abstract: Complexes of the formula ##STR1## wherein R.sub.1 is hydrocarbyl or substituted hydrocarbyl, EACH OF R.sub.2 and R.sub.3 is independently hydrogen, lower alkyl or substituted lower alkyl,Each of X.sub.1 and X.sub.2 is independently halo, nitro, alkyl, substituted alkyl, alkoxy or substituted alkoxy,M.sup.+ is a cation, e.g., lithium, sodium, potassium or ammonium, andm is 0 or 1,n is 0 or 1, andp is 0 or 1,With the proviso that the sum of m, n and p is 1, and derivatives thereof wherein Ring A is substituted. These complexes are good dyes for nautral and synthetic polyamide fibers (e.g., wool, silk and Nylon) as well as for leather and light metals (e.g., aluminum)... The shades of the dyeings range from olive to yellowish-green to khaki-brown. The dyeings have notable fastness to light, wet treatments, rubbing and pressing and stability to alkalis and acids and satisfactory dischargeability. The dyes build-up on polyamides from neutral medium.

Abstract translation: 其中R 1是烃基或取代的烃基，每个R 2和R 3独立地是氢，低级烷基或取代的低级烷基，每一个X 1和X 2独立地是卤素，硝基，烷基，取代的烷基，烷氧基或取代的 烷氧基，M +是阳离子，例如锂，钠，钾或铵，M IS 0 OR 1，N IS 0或1，P为0或1，条件是M，N和P的取代基为 1，其中环A被取代的衍生物。 这些复合物是适用于天然和合成聚酰胺纤维（例如羊毛，丝绸和尼龙）以及皮革和轻金属（如铝）的良好染料...染色的色调范围从橄榄色到黄绿色至卡其色 -棕色。 染色具有明显的耐光牢度，湿润处理，摩擦和压制，对碱和酸的稳定性和令人满意的排出性。 染料从中性介质聚集在聚酰胺上。

公开(公告)号：US4017478A

公开(公告)日：1977-04-12

申请号：US503967

申请日：1974-09-06

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B31/11 ,  C09B35/033 ,  C09B29/32 ,  C09B31/10 ,  C09B35/20 ,  C09B45/28

CPC classification number: C09B35/033 ,  C09B31/115 ,  C07C2103/18 ,  Y10S8/919

Abstract: Dyes of the formula ##STR1## wherein D is a carbocyclic aryl or heterocyclic aryl diazo component radical,q is 0 to 3, andt is 0, 1 or 2,With the proviso that q + t is 1 to 5, are highlyThe dyeing, padding and printing of textile fibers and textiles of natural or regenerated cellulose and paper. The dyes build-up well, exhibit good fastness to wet treatments, alcohol, light, rubbing and dry cleaning and are resistant to acids and alkalis.

Abstract translation: 其中D是碳环芳基或杂环芳基重氮组分基团，其中Q为0至3，且为0,1或2，其中Q + T为1至5， 纺织纤维和纺织品的天然或再生纤维素和纸张的染色，包装和印花。 染料积聚良好，表现出良好的湿润处理，酒精，光照，摩擦和干洗的牢度，耐酸碱。

公开(公告)号：US3948879A

公开(公告)日：1976-04-06

申请号：US378257

申请日：1973-07-11

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B29/01 ,  C09B29/30 ,  D06P3/04 ,  C09B45/16

CPC classification number: C09B29/30 ,  C09B29/0007 ,  D06P3/046

Abstract: Compounds of the formula ##SPC1##WhereinEACH OF R and R.sub.1 independently is halo,R.sub.2 is hydrogen or halo,R.sub.3 is halo or --OR.sub.4, andR.sub.4 is alkyl or substituted alkyl,And chromium complexes thereof. The monoazo compounds are particularly useful for dyeing natural and synthetic polyamide fibers by producing a chromium complex thereof on the fiber by treating the fiber with 2 moles of the monoazo compound and simultaneously or subsequently treating the fiber with 1 to 2 moles of a chromium-donating compound.

Abstract translation: R 1和R 2各自独立地为卤素，R 2为氢或卤素，R 3为卤素或-OR 4，且R 4为烷基或取代的烷基，以及其与其的化合物。 单偶氮化合物特别适用于通过用2摩尔单偶氮化合物处理纤维而在纤维上生产其铬络合物来染色天然和合成聚酰胺纤维，同时或随后用1至2摩尔的供体金 复合。

公开(公告)号：US4499018A

公开(公告)日：1985-02-12

申请号：US434470

申请日：1982-10-15

Applicant: Jacky Dore ,  Helmut Moser

Inventor： Jacky Dore ,  Helmut Moser

IPC: C09B47/16 ,  C09B47/32 ,  C09B67/22 ,  C09B47/30

CPC classification number: C09B67/0035 ,  C09B47/16 ,  C09B47/32

Abstract: A phthalocyanine product in which at least two phthalocyanine groups which may be metallized or unmetallized are joined by a bridging group, the bridging group being attached to the phthalocyanine groups through --CH.sub.2 --X.sub.o -- linkages where X.sub.o is a basic group and the phthalocyanine groups are attached to the methylene group of the linkages. The phthalocyanine product is useful as a dyestuff.

Abstract translation: 其中至少两个可被金属化或未金属化的酞菁基团的酞菁产物通过桥连基团连接，桥连基团通过-CH 2 -X-键连接到酞菁基团上，其中Xo是碱性基团，酞菁基团是 连接到连接的亚甲基上。 酞菁类产品可用作染料。

公开(公告)号：US4396544A

公开(公告)日：1983-08-02

申请号：US188624

申请日：1980-09-19

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/02 ,  C09B45/10 ,  C09B45/16 ,  D06P3/24 ,  C07C107/00 ,  C09B45/48

CPC classification number: C09B45/10

Abstract: 1:2 Chromium complexes of the formula, ##STR1## in which R.sub.1 is hydrogen, chlorine, bromine, nitro (being meta to the first nitro group), C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.2 is hydrogen or nitro,Y is ##STR2## wherein R.sub.3 is hydrogen, chlorine, bromine, trifluoromethyl, C.sub.1-4 alkyl or C.sub.1-4 alkoxy, andR.sub.4 is hydrogen, chlorine, bromine, C.sub.1-4 alkyl or C.sub.1-4 alkoxy, andA is a ##STR3## wherein the carbon atom marked with the * is bound to the azo radical, which complexes are in free acid or salt form, and mixtures thereof, are useful for dyeing and printing nitrogen-containing organic substrates, for example, natural and synthetic polyamides such as wool, silk and nylon, polyurethanes, polyolefins modified to contain basic groups and leather, for dyeing metals such as anodized aluminum and in printing lacquers and ball-point pen inks.

Abstract translation: 1：2下式的铬络合物，其中R1是氢，氯，溴，硝基（与第一硝基相当），C 1-4烷基或C 1-4烷氧基，R 2是氢或硝基，Y是 其中R 3是氢，氯，溴，三氟甲基，C 1-4烷基或C 1-4烷氧基，R 4是氢，氯，溴，C 1-4烷基或C 1-4烷氧基，A是一个< 标记为*与偶氮基团结合，该复合物具有游离酸或盐形式及其混合物，可用于染色和印刷含氮有机基材，例如天然和合成的聚酰胺如羊毛，丝绸和 尼龙，聚氨酯，改性成含有碱性基团和皮革的聚烯烃，用于染色金属如阳极氧化铝和印刷漆和圆珠笔墨水。

公开(公告)号：US4159983A

公开(公告)日：1979-07-03

申请号：US869480

申请日：1978-01-16

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B45/20 ,  C09B45/34 ,  D06P1/10 ,  C09B45/48

CPC classification number: D06P1/10 ,  C09B45/20 ,  C09B45/34

Abstract: Pure and substantially pure asymmetric 1:2 cobalt complexes of the formula, ##STR1## and mixtures of such complexes, in which X is hydrogen or nitro, either, R.sub.1 and R.sub.2, independently, are hydrogen, (C.sub.1-4)-alkyl, (C.sub.1-4)alkoxy, chlorine, bromine or nitro or R.sub.1 is hydrogen, chlorine or nitro, and R.sub.2 is -SO.sub.2 NR.sub.3 R.sub.4, in which R.sub.1 and R.sub.2 occupy the 4- and 5-positions, either R.sub.3 is hydrogen or unsubstituted or substituted (C.sub.1-4)alkyl, and R.sub.4 is hydrogen or unsubstituted or substituted (C.sub.1-4)alkyl, (C.sub.5-7)cycloalkyl or phenyl, or R.sub.3 and R.sub.4 or together with the nitrogen atom to which they are bound, form a non-aromatic 5- or 6- membered heterocyclic ring which contains one or two hetero atoms,B is a divalent radical of a coupling component of the 1- or 2-hydroxynaphthalene series which is coupled in the 2- or 1- position ortho to the hydroxy group and is bound to the cobalt atom through the oxygen atom,D is a divalent radical of a coupling component of the 2-naphthylamine series which is coupled in the 1- position ortho to the amino group or a divalent radical of the 5-aminopyrazole series which is coupled to the carbon atom next to that carrying the amino group, whereby the divalent radical D is bound to the cobalt atom through the amino group, andM.sup..sym. is hydrogen or an equivalent of a non-chromophoric cation, with the provisos that the molecule (i) contains a single sulpho group, which sulpho group is in salt form, (ii) contains at maximum a single sulphonamide group, which group is in radical D or is R.sub.2, and (iii) is free from ##STR2## groups, which complexes and mixtures are useful for dyeing or printing nitrogen-containing organic substrates, for example natural and synthetic polyamides such as wool, silk and nylon, polyurethanes and leather.

Abstract translation: 纯的和基本上纯的不对称1:2钴络合物，其中X是氢或硝基，R 1和R 2独立地是氢，（C 1-4） - 烷基， （C 1-4）烷氧基，氯，溴或硝基或R 1为氢，氯或硝基，R 2为-SO 2 NR 3 R 4，其中R 1和R 2占据4-和5-位，R 3为氢或未取代或取代的（ C 1-4烷基，R 4为氢或未取代或取代的（C 1-4）烷基，（C 5-7）环烷基或苯基，或R 3和R 4或与它们所连接的氮原子一起形成非 - 含有一个或两个杂原子的芳族5-或6-元杂环，B是1-羟基萘系列的偶联组分的二价基团，其与羟基邻位的2-位或1-位相连接 并且通过氧原子与钴原子结合，D是连接在一起的2-萘胺系列的偶联组分的二价基团 n是氨基的1-位或与氨基相邻的碳原子连接的5-氨基吡唑系的二价基团，由此二价基团D通过氨基与钴原子结合 ，并且M（+）是氢或非发色阳离子的当量，条件是分子（i）含有单个磺基，该磺酸基为盐形式，（ii）最多含有单个磺酰胺 基团，其为基团D或为R2，和（iii）不含基团，该复合物和混合物可用于染色或印刷含氮有机基材，例如天然和合成聚酰胺如羊毛， 丝绸和尼龙，聚氨酯和皮革。

公开(公告)号：US5092905A

公开(公告)日：1992-03-03

申请号：US592943

申请日：1990-10-04

Applicant: Jacky Dore

Inventor： Jacky Dore

IPC: C09B67/22 ,  D06P3/24 ,  D06P3/87

CPC classification number: C09B67/0041 ,  D06P3/241 ,  Y10S8/917 ,  Y10S8/924

Abstract: Dye mixtures comprising(i) as a yellow component, at least one compound of the formula ##STR1## or a salt thereof, wherein R.sub.1 is hydrogen, C.sub.1-4 alkoxy, C.sub.1-4 alkyl or C.sub.1-4 alkyl monosubstituted by halo,R.sub.2 is C.sub.1-4 alkyl or --COR.sub.6,wherein R.sub.6 is C.sub.1-6 alkyl, C.sub.1-6 alkoxy or --NR.sub.7 R.sub.8,wherein each of R.sub.7 and R.sub.8 is independently hydrogen, C.sub.1-6 -alkyl or C.sub.2-6 alkyl mono-substituted by hydroxy,R.sub.4 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --NR.sub.3 R.sub.9,R.sub.5 is c.sub.1-4 alkyl or C.sub.2-6 alkyl monosubstituted by hydroxy,R.sub.10 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy or --NR.sub.3 R.sub.9, andR.sub.11 is hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy, whereineach R.sub.3 is independently hydrogen or C.sub.1-4 alkyl, andeach R.sub.9 is independently (C.sub.1-6 alkyl)carbonyl or (C.sub.1-6 alkoxy)carbonyl,(ii) as a red component, at least one compound of the formula ##STR2## or a salt thereof, wherein R.sub.21 is hydrogen, halo or (C.sub.1-4 alkyl)carbonylamino, andR.sub.22 is trifluoromethyl, --SO.sub.2 Z.sub.1 or --SO.sub.2 Z.sub.2, whereinZ.sub.1 is phenyl, phenoxy or --NR.sub.19 R.sub.20, whereinR.sub.19 is methyl or ethyl, andR.sub.20 is phenyl or cyclohexyl, andZ.sub.2 is --N(C.sub.4 H.sub.9).sub.2 or ##STR3## (iii) as a blue component, at least one compound of the formula ##STR4## or a salt thereof, wherein R.sub.23 is hydrogen or methyl, andone of R.sub.24 and R.sub.25 is C.sub.2-4 hydroxyalkylsulfamoyl or --NR.sub.26 --COC.sub.1-4 alkyl and the other is hydrogen or methyl, wherein R.sub.26 is hydrogen, methyl or ethyl,useful for dyeing and printing nitrogen-containing organic substrates, especially natural and synthetic polyamides.

Abstract translation: 包含（i）黄色成分的至少一种下式的化合物或其盐，其中R1是氢，C1-4烷氧基，C1-4烷基或被卤素单取代的C1-4烷基，R2是C1- 4烷基或-COR 6，其中R 6是C 1-6烷基，C 1-6烷氧基或-NR 7 R 8，其中R 7和R 8各自独立地是氢，C 1-6 - 烷基或被羟基单取代的C 2-6烷基，R 4是氢， C 1-4烷基，C 1-4烷氧基或-NR 3 R 9，R 5是C 1-4烷基或被羟基单取代的C 2-6烷基，R 10是氢，卤素，C 1-4烷基，C 1-4烷氧基或-NR 3 R 9，R 11是氢， 4-烷基或C 1-4烷氧基，其中每个R 3独立地是氢或C 1-4烷基，并且每个R 9独立地为（C 1-6烷基）羰基或（C 1-6烷氧基）羰基，（ii）作为红色组分， 其中R 21是氢，卤素或（C 1-4烷基）羰基氨基，R 22是三氟甲基，-SO 2 Z 1或-SO 2 Z 2，其中Z 1是苯基，苯氧基或-NR 19 R 20，其中R 19是甲基或乙基 ，和 R 20为苯基或环己基，Z 2为-N（C 4 H 9）2或（iii）为蓝色成分，至少一种下式化合物或其盐，其中R 23为氢或甲基，以及 R24和R25之一是C2-4羟基烷基氨磺酰基或-NR26-COC1-4烷基，另一个是氢或甲基，其中R26是氢，甲基或乙基，可用于染色和印刷含氮有机基材，特别是天然和合成聚酰胺。