公开(公告)号：US4766234A

公开(公告)日：1988-08-23

申请号：US930504

申请日：1986-11-12

申请人： Frank Wehowsky ,  Rolf Kleber ,  Lothar Jaeckel

发明人： Frank Wehowsky ,  Rolf Kleber ,  Lothar Jaeckel

IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C239/00 ,  C07C269/02 ,  C07C271/10 ,  C07C271/20 ,  C07C271/24 ,  C07C271/28 ,  C07C275/04 ,  C07C275/62 ,  C07C301/00 ,  C07C303/40 ,  C07C311/01 ,  C08G18/28 ,  C08G18/30 ,  C08G18/38 ,  C08G65/38 ,  C08G65/48 ,  C08G73/06 ,  D06M13/02 ,  D06M13/322 ,  D06M15/568 ,  D06M15/576 ,  C07C125/06

CPC分类号： C07C275/62 ,  C08G18/2885 ,  D06M15/576

摘要： The novel urethanes, in addition to at least one perfluoroalkyl group, also contain epichlorohydrin groups and dialcohol radicals in the molecule. They are prepared by reacting a fluorine-containing alcohol with epichlorohydrin to give the perfluoroalkyl-epichlorohydrin adduct, reacting this adduct with a di- or triisocyanate to give the perfluoroalkyl-epichlorohydrin-isocyanate adduct and by reacting this adduct with a dialcohol or a monoetherified dialcohol to give the desired urethanes having a perfluoroalkyl group and having epichlorohydrin groups and dialcohol radicals, and by reacting a suitable urethane compound of this type with a perfluoroalkyl-containing di- or triisocyanate to give the desired urethanes having a plurality of perfluoroalkyl groups and having epichlorohydrin groups and dialcoholradicals. The novel urethanes are preferably used for the oleophobic and hydrophobic finishing of textiles.

摘要翻译： 除了至少一个全氟烷基之外，新型氨基甲酸酯在分子中还含有表氯醇基和二醇基。 它们通过使含氟醇与表氯醇反应得到全氟烷基 - 表氯醇加合物，使该加合物与二异氰酸酯或三异氰酸酯反应，得到全氟烷基 - 表氯醇 - 异氰酸酯加合物，并通过使该加合物与二醇或单醚化的二醇反应 得到所需的具有全氟烷基并具有表氯醇基和二醇基团的氨基甲酸酯，并通过使这种类型的合适的氨基甲酸酯化合物与含全氟烷基的二异氰酸酯或三异氰酸酯反应，得到所需的具有多个全氟烷基并具有表氯醇的氨基甲酸酯 团体和酒吧。 新型氨基甲酸酯优选用于纺织品的疏油和疏水整理。