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11.发明授权Metal colloid-colored glass ceramic and colorless glass convertible into same 有权金属胶体色玻璃陶瓷和无色玻璃可转换为相同公开(公告)号：US08283268B2
公开(公告)日：2012-10-09
申请号：US12107905
申请日：2008-04-23
CPC分类号： C03C1/10 , C03C3/085 , C03C4/02 , C03C10/0027 , C03C10/0045 , C03C14/004 , C03C14/006 , C03C2214/20
摘要： The colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are compounds containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are compounds containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former.
摘要翻译： 通过各自的热处理可转变为无色透明玻璃陶瓷或金属胶体色玻璃陶瓷的无色透明胶体成分玻璃含有一种或多种金属胶体形成剂和一种或多种氧化还原配合物的组合。 金属胶体形成剂是含有Au，Ag，As，Bi，Nb，Cu，Fe，Pd，Pt，Sb和/或Sn的化合物。 氧化还原配体是含有As，Ce，Fe，Mn，Sb，Sn和/或W的化合物，条件是氧化还原对象必须与金属胶体形成体不同。
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12.发明申请公开(公告)号：US20150128646A9
公开(公告)日：2015-05-14
申请号：US13705577
申请日：2012-12-05
IPC分类号： C03C10/00
CPC分类号： C03C10/0027 , B32B17/10045 , B32B17/10119 , B32B17/10761 , B32B2333/12 , C03C3/085 , F41H5/0407
摘要： The process for producing a transparent lithium aluminosilicate glass ceramic plate includes ceramicizing a green glass body of the Li2O—Al2O—SiO2 system using a ceramization program, which includes heating it, for the purpose of nucleation, to a temperature of 750° C.±20° C. and maintaining the temperature for 20±15 minutes, further heating the green glass body, for the purpose of ceramization, to a temperature of 900±20° C. and maintaining the to temperature for 20±15 minutes and then cooling to room temperature. The transparent plate has a thermal expansion coefficient (CTE) from −0.15×10−6/K to +0.15×10−6/K at 30 to 700° C. and a brightness value observed at an angle of 2° of ≧80 for a 4-mm thick plate for transmitted normal light.
摘要翻译： 制造透明的铝硅酸铝玻璃陶瓷板的方法包括使用陶瓷化程序对Li 2 O-Al 2 O-SiO 2系统的生坯玻璃体进行陶瓷化，该方法包括将其加热至成核的目的，至750℃的温度。± 20℃，保持温度20±15分钟，为了陶瓷化目的，将生坯玻璃体进一步加热至900±20℃，保持温度20±15分钟，然后冷却 至室温。 透明板在30〜700℃下的热膨胀系数（CTE）为-0.15×10-6 / K〜+ 0.15×10-6 / K，在2°以上观察到的亮度值≥80 用于透射普通光的4毫米厚板。
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13.发明授权Metal colloid-colored glass ceramic and colorless glass convertible into same 失效金属胶体色玻璃陶瓷和无色玻璃可转换为相同公开(公告)号：US08609561B2
公开(公告)日：2013-12-17
申请号：US13550867
申请日：2012-07-17
CPC分类号： C03C1/10 , C03C3/085 , C03C4/02 , C03C10/0027 , C03C10/0045 , C03C14/004 , C03C14/006 , C03C2214/20
摘要： A colorless transparent colloid-former-containing glass that is convertible into a colorless transparent glass ceramic or a metal colloid-colored glass ceramic via respective heat treatments contains a combination of one or more metal colloid formers and one or more redox partners. The metal colloid formers are preferably oxides containing Au, Ag, As, Bi, Nb, Cu, Fe, Pd, Pt, Sb and/or Sn. The redox partners are preferably oxides containing As, Ce, Fe, Mn, Sb, Sn and/or W, with the proviso that the redox partner must be different from the metal colloid former. The glass advantageously contains from 0.97 to 1.9 wt. % SnO2, 0.93 to 3.0 wt. % As2O3, or 1.59 to 6.0 wt. % of Sb2O3 as redox partner.
摘要翻译： 通过各自的热处理可转变为无色透明玻璃陶瓷或金属胶体色玻璃陶瓷的无色透明含胶体成分玻璃包含一种或多种金属胶体形成剂和一种或多种氧化还原配合物的组合。 金属胶体形成剂优选为含有Au，Ag，As，Bi，Nb，Cu，Fe，Pd，Pt，Sb和/或Sn的氧化物。 氧化还原配合物优选为含有As，Ce，Fe，Mn，Sb，Sn和/或W的氧化物，条件是氧化还原对象必须与金属胶体形成体不同。 玻璃有利地含有0.97〜1.9重量％ ％SnO 2，0.93〜3.0重量％ ％As 2 O 3，或1.59〜6.0重量％ Sb2O3作为氧化还原配体。
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公开(公告)号：US20100154622A1
公开(公告)日：2010-06-24
申请号：US12616982
申请日：2009-11-12
CPC分类号： F41H5/0407 , B32B17/10036 , B32B17/10119 , B32B17/1033 , B32B17/10761 , C03C3/083 , C03C10/0027 , Y10T428/266 , Y10T428/31507 , Y10T428/31518 , Y10T428/31601
摘要： The present invention describes a transparent plate of lithium aluminosilicate glass ceramic showing a high transmission, a process for producing same and transparent plate laminates comprising at least one plate of the lithium aluminosilicate glass ceramic of the invention and the use thereof as armored glass or bullet-proof vest.
摘要翻译： 本发明描述了一种显示高透射率的铝硅酸铝玻璃陶瓷透明板，其制造方法和透明板层叠体，其包含至少一块本发明的铝硅酸铝玻璃陶瓷板及其作为装甲玻璃或子弹 - 防伪背心。
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公开(公告)号：US09199873B2
公开(公告)日：2015-12-01
申请号：US13705577
申请日：2012-12-05
CPC分类号： C03C10/0027 , B32B17/10045 , B32B17/10119 , B32B17/10761 , B32B2333/12 , C03C3/085 , F41H5/0407
摘要： The process for producing a transparent lithium aluminosilicate glass ceramic plate includes ceramicizing a green glass body of the Li2O—Al2O—SiO2 system using a ceramization program, which includes heating it, for the purpose of nucleation, to a temperature of 750° C.±20° C. and maintaining the temperature for 20±15 minutes, further heating the green glass body, for the purpose of ceramization, to a temperature of 900±20° C. and maintaining the to temperature for 20±15 minutes and then cooling to room temperature. The transparent plate has a thermal expansion coefficient (CTE) from −0.15×10−6/K to +0.15×10−6/K at 30 to 700° C. and a brightness value observed at an angle of 2° of ≧80 for a 4-mm thick plate for transmitted normal light.
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16.发明申请公开(公告)号：US20140150500A1
公开(公告)日：2014-06-05
申请号：US13705577
申请日：2012-12-05
IPC分类号： C03C10/00
CPC分类号： C03C10/0027 , B32B17/10045 , B32B17/10119 , B32B17/10761 , B32B2333/12 , C03C3/085 , F41H5/0407
摘要： The process for producing a transparent lithium aluminosilicate glass ceramic plate includes ceramicizing a green glass body of the Li2O—Al2O—SiO2 system using a ceramization program, which includes heating it, for the purpose of nucleation, to a temperature of 750° C.±20° C. and maintaining the temperature for 20±15 minutes, further heating the green glass body, for the purpose of ceramization, to a temperature of 900±20° C. and maintaining the to temperature for 20±15 minutes and then cooling to room temperature. The transparent plate has a thermal expansion coefficient (CTE) from −0.15×10−6/K to +0.15×10−6/K at 30 to 700° C. and a brightness value observed at an angle of 2° of ≧80 for a 4-mm thick plate for transmitted normal light.
摘要翻译： 制造透明的铝硅酸铝玻璃陶瓷板的方法包括使用陶瓷化程序对Li 2 O-Al 2 O-SiO 2系统的生坯玻璃体进行陶瓷化，该方法包括将其加热至成核的目的，至750℃的温度。± 20℃，保持温度20±15分钟，为了陶瓷化目的，将生坯玻璃体进一步加热至900±20℃，保持温度20±15分钟，然后冷却 至室温。 透明板在30〜700℃下的热膨胀系数（CTE）为-0.15×10-6 / K〜+ 0.15×10-6 / K，在2°以上观察到的亮度值≥80 用于透射普通光的4毫米厚板。
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公开(公告)号：US08338318B2
公开(公告)日：2012-12-25
申请号：US12451794
申请日：2008-05-24
CPC分类号： C03C10/0027 , B32B17/06 , B32B27/04 , B32B27/06 , F41H5/0407 , F41H5/0435
摘要： Antiballistic armor is provided that includes a glass-ceramic component having 50 to 70 weight percent SiO2, 15 to 25 weight percent Al2O3, 0.5 to 5 weight percent ZrO2, 0.1 to 10 weight percent Li2O, 1 to 5 weight percent TiO2. The glass ceramic component has a main crystalline phase that comprises keatite mixed crystal in a compositional range of LiAlSi2O6 to LiAlSi4O10.
摘要翻译： 提供了抗反射装甲，其包括具有50至70重量％SiO 2，15至25重量％Al 2 O 3，0.5至5重量％ZrO 2，0.1至10重量％Li 2 O，1至5重量％TiO 2的玻璃陶瓷组分。 玻璃陶瓷组分具有包含在LiAlSi 2 O 6与LiAlSi 4 O 10的组成范围内的酮钙石混合晶体的主晶相。
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公开(公告)号：US20100263525A1
公开(公告)日：2010-10-21
申请号：US12451794
申请日：2008-12-04
CPC分类号： C03C10/0027 , B32B17/06 , B32B27/04 , B32B27/06 , F41H5/0407 , F41H5/0435
摘要： Antiballistic armor is provided that includes a glass-ceramic component having 50 to 70 weight percent SiO2, 15 to 25 weight percent Al2O3, 0.5 to 5 weight percent ZrO2, 0.1 to 10 weight percent Li2O, 1 to 5 weight percent TiO2. The glass ceramic component has a main crystalline phase that comprises keatite mixed crystal in a compositional range of LiAlSi2O6 to LiAlSi4O10.
摘要翻译： 提供了抗反射装甲，其包括具有50至70重量％SiO 2，15至25重量％Al 2 O 3，0.5至5重量％ZrO 2，0.1至10重量％Li 2 O，1至5重量％TiO 2的玻璃陶瓷组分。 玻璃陶瓷组分具有包含在LiAlSi 2 O 6与LiAlSi 4 O 10的组成范围内的酮钙石混合晶体的主晶相。
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公开(公告)号：US20050076676A1
公开(公告)日：2005-04-14
申请号：US10647966
申请日：2003-08-26
CPC分类号： C03B11/10 , C03B32/02 , C03C10/0027
摘要： The invention relates to a glass and a glass-ceramic comprising beta-quartz and/or keatite solid solutions, and to a process for their production, and to their use as substrate material for coating. Glass-ceramic comprising beta-quartz and/or keatite solid solutions with a surface roughness without polishing of Ra 85% for a 4 mm thickness, and a composition in % by weight, based on the total composition, containing: Li2O3.0-5.5 Na2O0-2.5 K2O0-2.0 Σ Na2O + K2O0.5-3.0 Σ MgO + ZnO
摘要翻译： 本发明涉及包含β-石英和/或酮钙石固溶体的玻璃和玻璃陶瓷，以及它们的生产方法以及它们作为涂层用基材的用途。 玻璃陶瓷包含具有表面粗糙度而不抛光Ra <50nm的β-石英和/或酮钙石固溶体，在20℃和300℃之间的温度范围内的热膨胀<1.2.10 <-6 > K，在1050nm的近红外区域，对于4mm厚度的透射率为> 85％，基于总组合物的重量％组成，包含：和如果合适的话至少一种澄清剂 ，如As2O3，Sb2O3，SnO2，CeO2，硫酸盐和氯化物。
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公开(公告)号：US06673729B2
公开(公告)日：2004-01-06
申请号：US10068804
申请日：2002-02-05
IPC分类号： C03C1014
CPC分类号： C03B11/10 , C03B32/02 , C03C10/0027
摘要： The invention relates to a glass and a glass-ceramic comprising beta-quartz and/or keatite solid solutions, and to a process for their production, and to their use as substrate material for coating. Glass-ceramic comprising beta-quartz and/or keatite solid solutions with a surface roughness without polishing of Ra 85% for a 4 mm thickness, and a composition in % by weight, based on the total composition, containing: Li2O 3.0-5.5 Na2O 0-2.5 K2O 0-2.0 &Sgr; Na2O + K2O 0.5-3.0 &Sgr; MgO + ZnO
摘要翻译： 本发明涉及包含β-石英和/或酮钙石固溶体的玻璃和玻璃陶瓷，以及它们的生产方法以及它们作为涂层用基材的用途。 玻璃陶瓷包含具有表面粗糙度而不抛光Ra <50nm的β-石英和/或酮钙石固溶体，在20℃和300℃之间的温度范围内的热膨胀<1.2.10 <-6 > K，在1050nm的近红外区域，对于4mm厚度的透射率为> 85％，基于总组合物的重量％组成，包含：和如果合适的话至少一种澄清剂 ，如As2O3，Sb2O3，SnO2，CeO2，硫酸盐和氯化物。
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