公开(公告)号：US5830264A

公开(公告)日：1998-11-03

申请号：US824516

申请日：1997-03-26

申请人： Masaya Fujioka ,  Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Masaya Fujioka ,  Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： C09D11/00 ,  C09D11/02

CPC分类号： C09D11/30

摘要： An ink composition comprises a dye, water, at least one of a polyhydric alcohol and an alkyl ether of a polyhydric alcohol, and an organic weakly basic compound, and has a pH range of 8 to 10.

摘要翻译： 油墨组合物包含染料，水，多元醇和多元醇的烷基醚中的至少一种和有机弱碱性化合物，pH范围为8〜10。

公开(公告)号：US5885336A

公开(公告)日：1999-03-23

申请号：US838528

申请日：1997-04-09

申请人： Takeo Kitahara ,  Hideto Yamazaki ,  Masahito Kato ,  Masaya Fujioka ,  Shunichi Higashiyama

发明人： Takeo Kitahara ,  Hideto Yamazaki ,  Masahito Kato ,  Masaya Fujioka ,  Shunichi Higashiyama

IPC分类号： B41J2/01 ,  C09D11/00 ,  C09D11/02 ,  C09D11/033 ,  C09D11/328

CPC分类号： C09D11/38

摘要： A recording ink composition comprises pure water, a water-soluble dye, a polyvalent alcohol, and phosphoric acid. When iron is contained as an impurity in the recording ink composition, the iron and phosphoric acid form a ferric (III) phosphato complex ion represented by �Fe(HP0.sub.4)(H.sub.2 O)!.sup.+. Owing to the formation of the complex ion, the recording ink composition is prevented from discoloration which would be otherwise caused by iron ion. Further, the recording ink composition is prevented from formation and deposition of iron compounds. Therefore, the obtained ink has an excellent color tone, and the ink avoids blocking at a nozzle of a printing head or the like of an ink-jet printer.

摘要翻译： 记录油墨组合物包含纯水，水溶性染料，多元醇和磷酸。 当在记录油墨组合物中含有铁作为杂质时，铁和磷酸形成由[Fe（HPO 4）（H 2 O）] +表示的三价铁（III）磷酸盐络合物离子。 由于形成复合离子，防止记录油墨组合物变色，否则将由铁离子引起。 此外，防止记录油墨组合物形成和沉积铁化合物。 因此，所得到的油墨具有优异的色调，并且墨水避免了在喷墨打印机的打印头等的喷嘴处的堵塞。

公开(公告)号：US07252708B2

公开(公告)日：2007-08-07

申请号：US10948312

申请日：2004-09-24

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/50 ,  C09D5/22

摘要： A fluorescent water base ink for ink-jet recording contains a first fluorescent dye and a second fluorescent dye. The first fluorescent dye has a first ultraviolet absorption wavelength region in an absorption spectrum and a first fluorescence emission wavelength region in a fluorescence spectrum. The second fluorescent dye has a second ultraviolet absorption wavelength region which is different from the first ultraviolet absorption wavelength region in an absorption spectrum and a second fluorescence emission wavelength region in a fluorescence spectrum. The first fluorescent dye further has an absorption wavelength region which is different from the first ultraviolet absorption wavelength region and which overlaps at least a part of the second fluorescence emission wavelength region.

摘要翻译： 用于喷墨记录的荧光水基油墨包含第一荧光染料和第二荧光染料。 第一荧光染料在吸收光谱中具有第一紫外吸收波长区域和荧光光谱中的第一荧光发射波长区域。 第二荧光染料具有与荧光光谱中的吸收光谱中的第一紫外线吸收波长区域和第二荧光发射波长区域不同的第二紫外线吸收波长区域。 第一荧光染料还具有与第一紫外线吸收波长区域不同的吸收波长区域，并且与第二荧光发射波长区域的至少一部分重叠。

公开(公告)号：US20050284331A1

公开(公告)日：2005-12-29

申请号：US11080476

申请日：2005-03-16

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/326 ,  C09D11/328 ,  C09D11/38 ,  C09D11/40 ,  C09D11/50

CPC分类号： C09D11/50

摘要： A fluorescent water base ink for ink-jet recording includes water, a first fluorescent dye, and a second fluorescent dye. The first fluorescent dye absorbs light in a first absorption wavelength region in an ultraviolet region to emit fluorescence, and the first fluorescent dye absorbs light in a second absorption wavelength region to emit no fluorescence. The second fluorescent dye absorbs light in an absorption wavelength region in the ultraviolet region, which is different from the first absorption wavelength region of the first fluorescent dye, to emit fluorescence. A wavelength region of the fluorescence of the second fluorescent dye is not overlapped with the first absorption wavelength region of the first fluorescent dye, but at least a part of the wavelength region of the fluorescence of the second fluorescent dye is overlapped with the second absorption wavelength region. The fluorescence intensity of the ink is increased.

摘要翻译： 用于喷墨记录的荧光水基油墨包括水，第一荧光染料和第二荧光染料。 第一荧光染料吸收紫外区域的第一吸收波长区域中的光以发射荧光，并且第一荧光染料吸收第二吸收波长区域中的光以不发射荧光。 第二荧光染料吸收与第一荧光染料的第一吸收波长区域不同的紫外区域的吸收波长区域中的光发射荧光。 第二荧光染料的荧光的波长区域与第一荧光染料的第一吸收波长区域不重叠，但第二荧光染料的荧光的波长区域的至少一部分与第二吸收波长重叠 地区。 油墨的荧光强度增加。

公开(公告)号：US20050039633A1

公开(公告)日：2005-02-24

申请号：US10917224

申请日：2004-08-12

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Mayuko Umemura ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Mayuko Umemura ,  Shunichi Higashiyama

IPC分类号： C09D11/00

CPC分类号： C09D11/50

摘要： A fluorescent water base ink for ink-jet recording to be used for an ink-jet printer contains water, a pigment, a compound having primary or secondary amide group, and a fluorescent dye represented by the following formula (1): wherein R1 represents OH or N(R3)R4, R2 represents hydrogen atom or halogen atom, and each of R3 and R4 represents hydrogen atom or alkyl group. A sufficient OD value and a fluorescence value are obtained while securing the vivid color development and the excellent water resistance principally in accordance with the interaction of the fluorescent dye and the compound having the amide group.

摘要翻译： 用于喷墨打印机的用于喷墨记录的荧光水基油墨包含水，颜料，具有伯或仲酰胺基的化合物和由下式（1）表示的荧光染料：其中R < 1>表示OH或N（R 3）R 4，R 2表示氢原子或卤素原子，R 3和R 4各自表示氢原子或烷基。 通过荧光染料和具有酰胺基的化合物的相互作用，可以获得充分的OD值和荧光值，同时确保生动的显色性和优异的耐水性。

公开(公告)号：US5739833A

公开(公告)日：1998-04-14

申请号：US489369

申请日：1995-06-12

申请人： Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： B41J2/01 ,  B41M5/00 ,  C09D11/00 ,  C09D11/322 ,  C09D11/324 ,  C09D11/326 ,  C09D11/38 ,  B41J2/05 ,  H04N1/034

CPC分类号： C09D11/36

摘要： An ink which is usable with an ink jetting device for jetting the ink through a nozzle so as to effect printing on a recording medium. The ink contains a pigment as a coloring agent, and a non-aqueous solvent as an ink solvent. The pigment is in the form of particles having an average particle size of X .mu.m. The ink is jetted from the ink jetting device at a rate of Y, where Y is the volume (pl) of the ink which is ejected from the nozzle each time the ink jetting device is energized. The above-indicated X and Y satisfy the following formulas: 0.05 .ltoreq.X.ltoreq.0.5, 10.ltoreq.Y.ltoreq.100X+50, and 100X-30.ltoreq.Y.

摘要翻译： 一种油墨，其可用于通过喷嘴喷射油墨以便在记录介质上进行打印的喷墨装置。 油墨含有作为着色剂的颜料和作为油墨溶剂的非水溶剂。 颜料为平均粒径为10μm的颗粒形式。 油墨以Y的速度从喷墨装置喷射，其中Y是每次喷墨装置通电时从喷嘴喷出的油墨的体积（P1）。 上述X和Y满足下列公式：0.05

公开(公告)号：US07147696B2

公开(公告)日：2006-12-12

申请号：US10917224

申请日：2004-08-12

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Mayuko Umemura ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Mayuko Umemura ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/50

摘要： A fluorescent water base ink for ink-jet recording to be used for an ink-jet printer contains water, a pigment, a compound having primary or secondary amide group, and a fluorescent dye represented by the following formula (1): wherein R1 represents OH or N(R3)R4, R2 represents hydrogen atom or halogen atom, and each of R3 and R4 represents hydrogen atom or alkyl group. A sufficient OD value and a fluorescence value are obtained while securing the vivid color development and the excellent water resistance principally in accordance with the interaction of the fluorescent dye and the compound having the amide group.

摘要翻译： 用于喷墨打印机的用于喷墨记录的荧光水基油墨包含水，颜料，具有伯或仲酰胺基的化合物和由下式（1）表示的荧光染料：其中R < SUP> 1表示OH或N（R 3）R 4，R 2表示氢原子或卤素原子，并且各自 R 3和R 4代表氢原子或烷基。 通过荧光染料和具有酰胺基的化合物的相互作用，可以获得充分的OD值和荧光值，同时确保生动的显色性和优异的耐水性。

公开(公告)号：US20050120907A1

公开(公告)日：2005-06-09

申请号：US10948312

申请日：2004-09-24

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： C09D5/22 ,  C09D11/00 ,  C09K11/06

CPC分类号： C09D11/50 ,  C09D5/22

摘要： A fluorescent water base ink for ink-jet recording contains a first fluorescent dye and a second fluorescent dye. The first fluorescent dye has a first ultraviolet absorption wavelength region in an absorption spectrum and a first fluorescence emission wavelength region in a fluorescence spectrum. The second fluorescent dye has a second ultraviolet absorption wavelength region which is different from the first ultraviolet absorption wavelength region in an absorption spectrum and a second fluorescence emission wavelength region in a fluorescence spectrum. The first fluorescent dye further has an absorption wavelength region which is different from the first ultraviolet absorption wavelength region and which overlaps at least a part of the second fluorescence emission wavelength region.

摘要翻译： 用于喷墨记录的荧光水基油墨包含第一荧光染料和第二荧光染料。 第一荧光染料在吸收光谱中具有第一紫外吸收波长区域和荧光光谱中的第一荧光发射波长区域。 第二荧光染料具有与荧光光谱中的吸收光谱中的第一紫外线吸收波长区域和第二荧光发射波长区域不同的第二紫外线吸收波长区域。 第一荧光染料还具有与第一紫外线吸收波长区域不同的吸收波长区域，并且与第二荧光发射波长区域的至少一部分重叠。

公开(公告)号：US07364613B2

公开(公告)日：2008-04-29

申请号：US11080476

申请日：2005-03-16

申请人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

发明人： Michiko Aoyama ,  Masashi Tsuda ,  Hiromitsu Sago ,  Mayuko Umemura ,  Hideto Yamazaki ,  Shunichi Higashiyama

IPC分类号： C09D11/00 ,  C09D11/02

CPC分类号： C09D11/50

摘要： A fluorescent water base ink for ink-jet recording includes water, a first fluorescent dye, and a second fluorescent dye. The first fluorescent dye absorbs light in a first absorption wavelength region in an ultraviolet region to emit fluorescence, and the first fluorescent dye absorbs light in a second absorption wavelength region to emit no fluorescence. The second fluorescent dye absorbs light in an absorption wavelength region in the ultraviolet region, which is different from the first absorption wavelength region of the first fluorescent dye, to emit fluorescence. A wavelength region of the fluorescence of the second fluorescent dye is not overlapped with the first absorption wavelength region of the first fluorescent dye, but at least a part of the wavelength region of the fluorescence of the second fluorescent dye is overlapped with the second absorption wavelength region. The fluorescence intensity of the ink is increased.

摘要翻译： 用于喷墨记录的荧光水基油墨包括水，第一荧光染料和第二荧光染料。 第一荧光染料吸收紫外区域的第一吸收波长区域中的光以发射荧光，并且第一荧光染料吸收第二吸收波长区域中的光以不发射荧光。 第二荧光染料吸收与第一荧光染料的第一吸收波长区域不同的紫外区域的吸收波长区域中的光发射荧光。 第二荧光染料的荧光的波长区域与第一荧光染料的第一吸收波长区域不重叠，但第二荧光染料的荧光的波长区域的至少一部分与第二吸收波长重叠 地区。 油墨的荧光强度增加。

公开(公告)号：US07192476B2

公开(公告)日：2007-03-20

申请号：US10968893

申请日：2004-10-21

申请人： Mayuko Umemura ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Michiko Aoyama ,  Shunichi Higashiyama

发明人： Mayuko Umemura ,  Masashi Tsuda ,  Hideto Yamazaki ,  Hiromitsu Sago ,  Michiko Aoyama ,  Shunichi Higashiyama

IPC分类号： C09D11/02

CPC分类号： C09D11/32 ,  C09D11/50

摘要： A fluorescent water base ink for ink-jet recording contains a fluorescent dye having a xanthene skeleton, and a glycol. In the fluorescent dye, the difference in hydrophilic index log P is not less than 2.6 between a substituent bonded to C-9 carbon atom of the xanthene skeleton and other portion of the fluorescent dye than the substituent bonded to the C-9 carbon atom. The glycol has a distance between hydroxyl groups substantially equivalent to or longer than an interatomic distance between atoms directly bonded to C-3 and C-6 carbon atoms of the xanthene skeleton of the fluorescent dye, respectively. It is assumed that the glycol is coordinated with the xanthene skeleton in a bridge form to increase the fluorescence intensity by increasing the electron density of the xanthene skeleton. The ink having high fluorescence intensity and in which the fluorescence intensity is not lowered in a time-dependent manner is provided.

摘要翻译： 用于喷墨记录的荧光水基油墨包含具有呫吨骨架的荧光染料和二醇。 在荧光染料中，与结合到C-9碳原子的取代基相比，在呫吨骨架的C-9碳原子的取代基和荧光染料的其它部分之间，亲水指数log P的差异不小于2.6。 乙二醇的荧光染料的呫吨骨架的直接与C-3和C-6碳原子直接键合的原子之间的原子间距离基本上等于或大于等于或更长的羟基之间的距离。 假设二元醇以桥形式与呫吨骨架配位，通过增加呫吨骨架的电子密度来提高荧光强度。 提供了具有高荧光强度且荧光强度不以时间依赖性降低的油墨。