公开(公告)号：US07629085B2

公开(公告)日：2009-12-08

申请号：US11597652

申请日：2005-05-30

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40 ,  H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0567 ,  H01M2300/004

摘要： A nonaqueous electrolytic solution for a lithium secondary battery, in which 0.01 to 10 wt. % of a sulfur-containing acid ester and 0.01 to 10 wt. % of a triple bond-containing compound are dissolved in a nonaqueous solvent, and a lithium secondary battery employing the nonaqueous electrolytic solution.

摘要翻译： 一种锂二次电池用非水电解液，其中，0.01〜10重量％ ％的含硫酸酯和0.01〜10wt。 将含三价键的化合物的％溶解在非水溶剂中，使用该非水电解液的锂二次电池。

公开(公告)号：US08163427B2

公开(公告)日：2012-04-24

申请号：US10564852

申请日：2004-07-16

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。

公开(公告)号：US20060177742A1

公开(公告)日：2006-08-10

申请号：US10564852

申请日：2004-07-16

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M4/661 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/4235 ,  H01M2004/021 ,  H01M2300/0025 ,  H01M2300/0091

摘要： A non-aqueous electrolytic solution is advantageously used in preparation of a lithium secondary battery excellent in cycle characteristics. In the non-aqueous electrolytic solution for a lithium secondary battery, an electrolyte salt is dissolved in a non-aqueous solvent. The non-aqueous electrolytic solution further contains a vinylene carbonate compound in an amount of 0.01 to 10 wt. %, and an alkyne compound in an amount of 0.01 to 10 wt. %.

摘要翻译： 非水电解液有利地用于制备循环特性优异的锂二次电池。 在锂二次电池用非水电解液中，将电解质盐溶解在非水溶剂中。 非水电解液还含有碳酸亚乙烯酯化合物，其量为0.01〜10重量％。 ％，炔化合物的量为0.01〜10重量％。 ％。

公开(公告)号：US20070231707A1

公开(公告)日：2007-10-04

申请号：US11597652

申请日：2005-05-30

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0567 ,  H01M2300/004

摘要： A nonaqueous electrolytic solution for a lithium secondary battery, in which 0.01 to 10 wt. % of a sulfur-containing acid ester and 0.01 to 10 wt. % of a triple bond-containing compound are dissolved in a nonaqueous solvent, and a lithium secondary battery employing the nonaqueous electrolytic solution.

摘要翻译： 一种锂二次电池用非水电解液，其中，0.01〜10重量％ ％的含硫酸酯和0.01〜10wt。 将含三价键的化合物的％溶解在非水溶剂中，使用该非水电解液的锂二次电池。

公开(公告)号：US20070207389A1

公开(公告)日：2007-09-06

申请号：US11699327

申请日：2007-01-30

申请人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

发明人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

IPC分类号： H01M10/40

CPC分类号： H01M10/0567 ,  H01M4/137 ,  H01M4/405 ,  H01M4/485 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/021 ,  H01M2004/027 ,  H01M2300/0037

摘要： A non-aqueous electrolyte comprising (i) a non-aqueous solvent, especially mainly composed of a cyclic carbonate and a cyclic ester and optionally a linear carbonate, and (ii) an electrolyte salt, especially LiBF4, dissolved therein and (iii) a vinyl sulfone derivative having the formula (I): wherein R indicates a C1 to C12 alkyl group, C2 to C12 alkenyl group, or C3 to C6 cycloalkyl, and also a lithium secondary battery using the same are disclosed.

摘要翻译： 一种非水电解质，其包含（i）非水溶剂，特别是主要由环状碳酸酯和环状酯和任选的直链碳酸酯组成的非水溶剂，和（ii）电解质盐，特别是LiBF 4 ，和（iii）具有式（I）的乙烯基砜衍生物：其中R表示C 1至C 12烷基的C 1〜C 12， / C 1〜C 12链烯基或C 3〜C 6环烷基，并且还公开了使用其的锂二次电池。

公开(公告)号：US20070082271A1

公开(公告)日：2007-04-12

申请号：US10579249

申请日：2004-11-11

申请人： Koji Abe ,  Takashi Hattori ,  Yasuo Matsumori

发明人： Koji Abe ,  Takashi Hattori ,  Yasuo Matsumori

IPC分类号： H01M10/40 ,  H01M10/44

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0042

摘要： The present invention provides a lithium secondary battery which is improved in cycle characteristics and storage stability at an elevated temperature as well as protection from overcharge. In the battery, generation of a gas is also inhibited to prevent the battery from expansion. A non-aqueous electrolytic solution for the lithium secondary battery has an electrolyte in a non-aqueous solvent. The non-aqueous solvent is composed of a cyclic carbonate compound, a linear carbonate compound and a cyclohexylbenzene compound having a benzene ring to which one or two halogen atoms are attached. A volume ratio of the cyclic carbonate compound and the linear carbonate compound in the non-aqueous solvent is in the range of 20:80 to 40:60, or the non-aqueous solvent further contains a small amount of a branched alkylbenzene compound.

摘要翻译： 本发明提供一种锂二次电池，其在高温下的循环特性和储存稳定性得到改善，并且防止过充电。 在电池中，也抑制气体的产生，防止电池膨胀。 用于锂二次电池的非水电解液在非水溶剂中具有电解质。 非水溶剂由环状碳酸酯化合物，直链状碳酸酯化合物和具有一个或两个卤素原子的苯环的环己基苯化合物组成。 环状碳酸酯化合物和直链碳酸酯化合物在非水溶剂中的体积比在20:80〜40:60的范围内，或者非水溶剂还含有少量的支链烷基苯化合物。

公开(公告)号：US06866966B2

公开(公告)日：2005-03-15

申请号：US10021130

申请日：2001-10-22

申请人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori ,  Akira Ueki

发明人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori ,  Akira Ueki

IPC分类号： H01M4/587 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/08

CPC分类号： H01M10/052 ,  H01M4/587 ,  H01M10/0567 ,  H01M2300/0025

摘要： A discharge capacity retention of a non-aqueous secondary battery is enhanced by incorporating into its non-aqueous electrolytic solution a small amount of a substituted diphenyldisulfide derivative in which each of the diphenyl groups has a substituent such as alkoxy, alkenyloxy, alkynyloxy, cycloalkyloxy, aryloxy, acyloxy, alkanesulfonyloxy, arylsulfonyloxy, alkoxycarbonyloxy, aryloxycarbonyloxy, halogen, CF3, CCl3, or CBr3. Preferably, a small amount of methyl 2-propylcarbonate, 2-propynyl methanesulfonate, 1,3-propanesultone, divinylsulfone, 1,4-butanediol dimethanesulfonate or cyclohexylbenzene is further incorporated.

摘要翻译： 通过在其非水电解液中加入少量二苯基中具有取代基的取代二苯基二硫化物衍生物，例如烷氧基，烯氧基，炔氧基，环烷氧基， 芳氧基，酰氧基，烷磺酰氧基，芳基磺酰氧基，烷氧基羰基氧基，芳氧基羰基氧基，卤素，CF 3，CCl 3或CBr 3。 优选少量的碳酸2-丙酯，2-丙炔基甲磺酸酯，1,3-丙磺酸内酯，二乙烯基砜，1,4-丁二醇二甲磺酸酯或环己基苯。

公开(公告)号：US06699998B2

公开(公告)日：2004-03-02

申请号：US10109943

申请日：2002-03-29

申请人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

发明人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

IPC分类号： C07D31712

CPC分类号： H01M10/052 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037

摘要： A non-aqueous electrolyte comprising a non-aqueous solvent and a lithium salt dissolved therein, and a cyclic carbonate, linear carbonate, and vinylene carbonate having a chlorine content of 100 ppm or less, and a lithium secondary battery using the same.

摘要翻译： 包含溶解在其中的非水溶剂和锂盐的非水电解质和氯含量为100ppm以下的环状碳酸酯，直链碳酸酯和碳酸亚乙烯酯，以及使用该非水电解质的锂二次电池。

公开(公告)号：US07794885B2

公开(公告)日：2010-09-14

申请号：US10579249

申请日：2004-11-11

申请人： Koji Abe ,  Takashi Hattori ,  Yasuo Matsumori

发明人： Koji Abe ,  Takashi Hattori ,  Yasuo Matsumori

IPC分类号： H01M6/16

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0042

摘要： The present invention provides a lithium secondary battery which is improved in cycle characteristics and storage stability at an elevated temperature as well as protection from overcharge. In the battery, generation of a gas is also inhibited to prevent the battery from expansion. A non-aqueous electrolytic solution for the lithium secondary battery has an electrolyte in a non-aqueous solvent. The non-aqueous solvent is composed of a cyclic carbonate compound, a linear carbonate compound and a cyclohexylbenzene compound having a benzene ring to which one or two halogen atoms are attached. A volume ratio of the cyclic carbonate compound and the linear carbonate compound in the non-aqueous solvent is in the range of 20:80 to 40:60, or the non-aqueous solvent further contains a small amount of a branched alkylbenzene compound.

摘要翻译： 本发明提供一种锂二次电池，其在高温下的循环特性和储存稳定性得到改善，并且防止过充电。 在电池中，也抑制气体的产生，防止电池膨胀。 用于锂二次电池的非水电解液在非水溶剂中具有电解质。 非水溶剂由环状碳酸酯化合物，直链状碳酸酯化合物和具有一个或两个卤素原子的苯环的环己基苯化合物组成。 环状碳酸酯化合物和直链碳酸酯化合物在非水溶剂中的体积比在20:80〜40:60的范围内，或者非水溶剂还含有少量的支链烷基苯化合物。

公开(公告)号：US07691539B2

公开(公告)日：2010-04-06

申请号：US10383790

申请日：2003-03-06

申请人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

发明人： Toshikazu Hamamoto ,  Koji Abe ,  Tsutomu Takai ,  Yasuo Matsumori

IPC分类号： H01M6/16

CPC分类号： H01M10/0567 ,  H01M10/052 ,  H01M2300/0025 ,  H01M2300/0037

摘要： A method of increasing the discharge capacity retention of a non-aqueous lithium ion secondary battery having a positive electrode active material, a combination of a lithium element and a complex metal oxide, a negative electrode, and a non-aqueous electrolytic solution comprising an electrolyte dissolved in a non-aqueous solvent which is a combination of a cyclic carbonate and a linear carbonate by incorporating a disulfide derivative having the formula: R1—S—S—R2 wherein each of R1 and R2 independently represents a phenyl group, a benzyl group, a tolyl group, a pyridyl group, a pyrimidyl group, an alkyl group having 1 to 12 carbon atom, or a cycloalkyl group having 3 to 6 carbon atoms, in which each group has no substituent groups or has one or more alkyl groups into the non-aqueous electrolytic solution.

摘要翻译： 提高具有正极活性物质，锂元素和复合金属氧化物的组合的非水性锂离子二次电池的放电容量保持性的方法，负极和包含电解质的非水电解液 溶解在环状碳酸酯和直链碳酸酯的组合的非水溶剂中，加入具有下式的二硫化物衍生物：R1-S-S-R2，其中R1和R2各自独立地表示苯基，苄基 ，甲苯基，吡啶基，嘧啶基，碳原子数1〜12的烷基或碳原子数3〜6的环烷基，各基团不具有取代基或具有一个以上的烷基 非水电解液。