Abstract:
Disclosed are a transition metal precursor for preparation of a lithium composite transition metal oxide, the transition metal precursor including a composite transition metal compound represented by Formula 1 below and a hydrocarbon compound, and a method of preparing the same: MnaMb(OH1-x)2 (1) wherein M is at least two selected from the group consisting of Ni, Co, Mn, Al, Cu, Fe, Mg, B, Cr, and second period transition metals; 0.4≦a≦1; 0≦b≦0.6; a+b≦1; and 0≦x≦0.5, in which the transition metal precursor includes a particular composite transition metal compound and a hydrocarbon compound, and thus, when a lithium composite transition metal oxide is prepared using the same, carbon may be present in lithium transition metal oxide particles and/or on surfaces thereof, whereby a secondary battery including the lithium composite transition metal oxide exhibits excellent rate characteristics and long lifespan.
Abstract:
Disclosed are a precursor for preparation of a lithium composite transition metal oxide, a method for preparing the same and a lithium composite transition metal oxide obtained from the same. More particularly, the transition metal precursor which has a composition represented by Formula 1 below and is prepared in an aqueous transition metal solution, mixed with a transition metal-containing salt, including an alkaline material, the method for preparing the same and the lithium composite transition metal oxide obtained from the same are disclosed. MnaMb(OH1-x)2-yAy (1) wherein M is at least one selected form the group consisting of Ni, Ti, Co, Al, Cu, Fe, Mg, B, Cr, Zr, Zn and Period II transition metals; A is at least one selected form the group consisting of anions of PO4, BO3, CO3, F and NO3, and 0.5≦a≦1.0; 0≦b≦0.5; a+b=1; 0
Abstract translation:公开了锂复合过渡金属氧化物的制备前体,其制备方法以及由其制备的锂复合过渡金属氧化物。 更具体地说,具有下述式1所示的组成的过渡金属前体,其与含有过渡金属的盐(包括碱性物质)混合的过渡金属水溶液,其制备方法和锂复合物 公开了从其获得的过渡金属氧化物。 MnaMb(OH1-x)2-yAy(1)其中M是选自Ni,Ti,Co,Al,Cu,Fe,Mg,B,Cr,Zr,Zn和II族过渡金属中的至少一种 ; A是至少一种选自PO4,BO3,CO3,F和NO3的阴离子的组,以及0.5和nlE; a≦̸ 1.0; 0≦̸ b≦̸ 0.5; a + b = 1; 0
Abstract:
Disclosed is a cathode active material in which lithium cobalt oxide particles and manganese (Mn) or titanium (Ti)-containing lithium transition metal oxide particles co-exist and a method of preparing the same.
Abstract:
A positive electrode active material for a secondary battery includes a lithium composite transition metal oxide including nickel (Ni), cobalt (Co), and manganese (Mn), and a glassy coating layer formed on surfaces of particles of the lithium composite transition metal oxide, wherein, in the lithium composite transition metal oxide, an amount of the nickel (Ni) in a total amount of transition metals is 60 mol % or more, and an amount of the manganese (Mn) is greater than an amount of the cobalt (Co), and the glassy coating layer includes a glassy compound represented by Formula 1.
LiaM1bOc [Formula 1]
wherein, M1 is at least one selected from the group consisting of boron (B), aluminum (Al), silicon (Si), titanium (Ti), and phosphorus (P), and 1≤a≤4, 1≤b≤8, and 1≤c≤20.
Abstract:
Disclosed is a lithium-cobalt based complex oxide represented by Formula 1 below including lithium, cobalt and manganese wherein the lithium-cobalt based complex oxide maintains a crystal structure of a single O3 phase at a state of charge (SOC) of 50% or more based on a theoretical amount: LixCo1-y-zMnyAzO2 (1) wherein 0.95≤x≤1.15, 0
Abstract:
A positive electrode active material includes a core and a coating layer disposed on the core, wherein the core includes Li1+xMO2+y, wherein M is at least one element selected from the group consisting of nickel (Ni), cobalt (Co), and copper (Cu), and 1≤x≤5 and 0≤y≤2, and the coating layer includes carbon-based particles, wherein the carbon-based particle includes a structure in which a plurality of graphene sheets are connected, the carbon-based particle has an oxygen content of 1 wt % or more in the carbon-based particle, and the carbon-based particle has a D/G peak ratio of 1.55 or less during Raman spectrum measurement. A method of preparing the positive electrode active material, a positive electrode including the positive electrode active material, and a secondary battery including the positive electrode are also provided.
Abstract:
Provided are various embodiments of a positive electrode for a secondary battery, which in one embodiment includes a first positive electrode material mixture layer formed on a positive electrode collector, and a second positive electrode material mixture layer formed on the first positive electrode material mixture layer, wherein the first positive electrode material mixture layer has an operating voltage of 4.25 V to 6.0 V and includes an active material for overcharge which generates lithium and gas during charge; a method of preparing such a positive electrode for a secondary battery; and a lithium secondary battery including such a positive electrode.
Abstract:
Disclosed is a cathode active material in which lithium cobalt oxide particles and manganese (Mn) or titanium (Ti)-containing lithium transition metal oxide particles co-exist and a method of preparing the same.
Abstract:
Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2 (1) wherein M is represented by MnaM′1-b, M′ is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95≤x≤1.5, and 0.5≤a≤1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.
Abstract:
Provided is a cathode active material including a complex coating layer, which includes M below, formed on a surface of the cathode active material through reaction of a lithium transition metal oxide represented by Formula 1 below with a coating precursor: LixMO2 (1) wherein M is represented by MnaM′1-b, M′ is at least one selected from the group consisting of Al, Mg, Ni, Co, Cr, V, Fe, Cu, Zn, Ti and B, 0.95≤x≤51.5, and 0.5≤a≤1. The lithium secondary battery including the cathode active material exhibits improved lifespan and rate characteristics due to superior stability.