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    Oxadiazine Derivatives
    11.
    发明申请
    Oxadiazine Derivatives 失效
    恶二嗪衍生物

    公开(公告)号：US20070219188A1

    公开(公告)日：2007-09-20

    申请号：US11745550

    申请日：2007-05-08

    申请人： Peter Maienfisch ,  Laurenz Gsell

    发明人： Peter Maienfisch ,  Laurenz Gsell

    IPC分类号： A61K31/5395 ,  C07D273/04

    CPC分类号： C07D413/06 ,  A01N47/40 ,  A01N51/00 ,  C07D273/00 ,  C07D273/04 ,  C07D417/06

    摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

    摘要翻译： 其中A是未取代或单 - 四取代的芳族或非芳族单环或双环杂环基的式的化合物，其中A的一个至两个取代基可以选自卤代-C C 1 -C 3烷基，环丙基，卤代环丙基，C 2 -C 3链烯基，C 2 - C 1 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3 - 炔基， 炔基，卤代C 1 -C 3烷氧基，C 1 -C 3烷基，C 1 -C 3烷基， 烷硫基，卤代-C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基 的A可以选自C 1 -C 3 -C 3烷基，C 1 -C 3 - 烷基，C 1 -C 3 - 烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 1 -C 6烷基， C 3 -C 6环烷基，C 2 -C 6链烯基或C 2 - C 6炔基; 并且X为N-NO 2 N或N-CN，并且如果合适，其互变异构体（在每种情况下为游离形式或盐形式）均可用作农业化学活性成分，并且可以制备为 本身已知的方式。

    Process for the preparation of nitroguanidine derivatives
    12.
    发明授权
    Process for the preparation of nitroguanidine derivatives 失效
    制备硝基胍衍生物的方法

    公开(公告)号：US5245040A

    公开(公告)日：1993-09-14

    申请号：US777856

    申请日：1991-10-16

    申请人： Peter Maienfisch ,  Odd Kristiansen ,  Laurenz Gsell

    发明人： Peter Maienfisch ,  Odd Kristiansen ,  Laurenz Gsell

    IPC分类号： C07C277/00 ,  C07C279/32 ,  C07C279/36 ,  C07C323/44 ,  C07D213/36 ,  C07D213/40 ,  C07D213/61 ,  C07D213/89 ,  C07D233/64 ,  C07D239/26 ,  C07D251/08 ,  C07D261/08 ,  C07D263/32 ,  C07D265/06 ,  C07D265/30 ,  C07D265/32 ,  C07D271/04 ,  C07D271/06 ,  C07D271/08 ,  C07D273/00 ,  C07D273/04 ,  C07D277/20 ,  C07D277/32 ,  C07D279/06 ,  C07D279/12 ,  C07D285/00 ,  C07D285/18 ,  C07D285/34 ,  C07D307/52 ,  C07D333/20 ,  C07D401/06 ,  C07D401/14 ,  C07D417/06 ,  C07D471/04 ,  C07D498/04 ,  C07D513/04

    CPC分类号： C07D213/40 ,  C07C279/36 ,  C07D213/61 ,  C07D213/89 ,  C07D251/08 ,  C07D277/32 ,  C07D401/06 ,  C07D401/14 ,  C07D417/06

    摘要： A process for the preparation of 1,3-disubstituted 2-nitroguanidines of the formula I ##STR1## in which R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl or a radical --CH.sub.2 B; A is an unsubstituted or mono- to tetrasubstituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, which may contain one or two substituents from the group comprising C.sub.1 -C.sub.3 haloalkyl having 1 to 7 halogen atoms, cyclopropyl, halocyclopropyl having 1 to 3 halogen atoms, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, C.sub.2 -C.sub.3 haloalkenyl and C.sub.2 -C.sub.3 haloalkynyl having 1 to 4 halogen atoms, C.sub.1 -C.sub.3 haloalkoxy having 1 to 7 halogen atoms, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkylthio having 1 to 7 halogen atoms, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro and one to four substituents from the group comprising C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; and B is optionally substituted phenyl or pyridyl, which comprises hydrolysing a compound of the formula II ##STR2## in which R.sub.3 is unsubstituted or substituted C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.6 cycloalkyl, phenyl or benzyl.The compounds of the formula I are suitable as intermediates for the preparation of pesticides.

    摘要翻译： 制备式I的1,3-二取代2-硝基胍的方法，其中R 1是氢或C 1 -C 4烷基，R 2是氢，C 1 -C 6烷基，C 3 -C 6环烷基或基团-CH 2 B ; A是未取代的或单取代或四取代的芳族或非芳族单环或双环杂环基团，其可以含有一个或两个取代基，该取代基包括具有1至7个卤素原子的C 1 -C 3卤代烷基，环丙基，具有1至3个卤素的卤代环丙基 C 1 -C 3烯基，C 2 -C 3炔基，C 2 -C 3卤代烯基和具有1至4个卤素原子的C 2 -C 3卤代炔基，具有1至7个卤素原子的C 1 -C 3卤代烷氧基，C 1 -C 3烷硫基，具有1至7个卤素原子的C 1 -C 3卤代烷硫基，烯丙氧基， 炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基，包括C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; 并且B是任选取代的苯基或吡啶基，其包括水解其中R 3为未取代或取代的C 1 -C 10烷基，C 3 -C 6环烷基，苯基或苄基的式II化合物（II）。 式I的化合物适合作为制备农药的中间体。

    Pyridyl substituted guanidines useful as insecticides
    13.
    发明授权
    Pyridyl substituted guanidines useful as insecticides 失效
    吡啶基取代的胍类作为杀虫剂有用

    公开(公告)号：US5063236A

    公开(公告)日：1991-11-05

    申请号：US539297

    申请日：1990-06-18

    申请人： Laurenz Gsell

    发明人： Laurenz Gsell

    IPC分类号： C07D213/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N47/44 ,  C07D213/40 ,  C07D213/61 ,  C07D401/06

    CPC分类号： C07D213/40 ,  A01N43/50 ,  A01N43/54 ,  A01N47/44 ,  C07D401/06

    摘要： ##STR1## in which each of R
    1 and R
    3 , independently of the other, is hydrogen or C
    1 -C
    4 alkyl; R
    2 is hydrogen, C
    1 -C
    4 alkyl, benzyl or picolyl; or R
    2 and R
    3 are together a -(CH
    2 )
    4 - or -(CH
    2 )
    5 - radical; X is halogen; and n is an integer 0, 1, 2 or 3; and the salts of compounds of formula I; with the execption of N-picolyl-N'-cyanoguanidine and N-picolyl-N'-methyl-N"-cyanoguanidine. Also described are processes fot the preparation of these compounds, the corresponding starting materials and intermediates, and the use of the novel compounds in pest control, especially for controlling insects and representatives of the order Acarina, particularly insect pests in rice crops.

    N-pyridyl methyl-N-'-cyanoisothiourea compounds useful in controlling insect pests
    14.
    发明授权
    N-pyridyl methyl-N-'-cyanoisothiourea compounds useful in controlling insect pests 失效
    可用于防治害虫的N-吡啶基甲基-N'-氰基异硫脲化合物

    公开(公告)号：US4963572A

    公开(公告)日：1990-10-16

    申请号：US229209

    申请日：1988-08-08

    申请人： Laurenz Gsell

    发明人： Laurenz Gsell

    IPC分类号： A01N47/42 ,  C07D213/36 ,  C07D213/40 ,  C07D213/61

    CPC分类号： C07D213/40

    摘要： Novel substituted N-pyridylmethyl-N'-cyanoisothioureas of formula ##STR1## wherein R is C.sub.1 -C.sub.4 alkyl, cyclopropyl or benzyl; R.sub.1 is C.sub.1 -C.sub.4 alkyl or cyclopropyl; X is halogen; and n is the integer 0, 1, 2 or 3.Processes for the preparation of these compounds, the corresponding starting materials and intermediates and the use of the novel compounds in pest control, especially for controlling insects and representatives of the order Acarina, especially insect pests in rice crops, and as starting materials for the synthesis of novel pesticidal compositions are described.

    摘要翻译： 新颖的取代的N-吡啶基甲基-N'-氰基异硫脲，其结构式为：其中R为C1-C4烷基，环丙基或苄基; R1是C1-C4烷基或环丙基; X是卤素; 并且n是整数0,1,2或3.用于制备这些化合物的方法，相应的起始原料和中间体以及新型化合物在害虫防治中的用途，特别是用于防治昆虫和蜱螨纲的代表，特别是 描述了水稻作物中的害虫，以及作为合成新型农药组合物的原料。

    Pesticidal .alpha.-allenyl-3-phenoxybenzyl-2,2-dimethyl-3-(2,2-dihalovinyl)-cyclopr opane-1-carboxylates
    16.
    发明授权
    Pesticidal .alpha.-allenyl-3-phenoxybenzyl-2,2-dimethyl-3-(2,2-dihalovinyl)-cyclopr opane-1-carboxylates 失效
    杀虫α亚甲基-3-苯氧基苄基-2,2-二甲基-3-（2,2-二卤代乙烯基） - 环丙烷-1-羧酸酯

    公开(公告)号：US4348408A

    公开(公告)日：1982-09-07

    申请号：US292080

    申请日：1981-08-12

    申请人： Peter Ackermann ,  Laurenz Gsell ,  Rudolf Wehrli

    发明人： Peter Ackermann ,  Laurenz Gsell ,  Rudolf Wehrli

    IPC分类号： A01N53/00 ,  C07C43/295 ,  C07C69/743

    CPC分类号： A01N53/00 ,  C07C43/295

    摘要： The invention describes cyclopropanecarboxylic acid .alpha.-allenyl-3-phenoxybenzyl esters of the formula ##STR1## wherein X.sub.1 is halogen and each of Y.sub.1 and Y.sub.2 is hydrogen or halogen, a process for the production of these compounds, and the use thereof for controlling a variety of pests of animals and plants. The intermediates of the formula ##STR2## wherein X is hydroxyl or halogen and each of Y.sub.1 and Y.sub.2 is hydrogen or halogen, are also described.

    摘要翻译： 本发明描述了下式的环丙烷羧酸α-亚环烷基-3-苯氧基苄基酯：其中X1是卤素，Y1和Y2各自是氢或卤素，这些化合物的制备方法及其用于控制 各种动物和植物的害虫。 还描述了其中X是羟基或卤素并且Y1和Y2中的每一个是氢或卤素的式“IMAGE”的中间体。

    Oxadiazine derivatives
    19.
    发明授权
    Oxadiazine derivatives 失效
    恶二嗪衍生物

    公开(公告)号：US06627753B1

    公开(公告)日：2003-09-30

    申请号：US09669209

    申请日：2000-09-25

    申请人： Peter Maienfisch ,  Laurenz Gsell

    发明人： Peter Maienfisch ,  Laurenz Gsell

    IPC分类号： C07D27304

    CPC分类号： C07D413/06 ,  A01N47/40 ,  A01N51/00 ,  C07D273/00 ,  C07D273/04 ,  C07D417/06

    摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

    摘要翻译： 其中A是未取代或单取代或单取代的芳香族或非芳香族单环或双环杂环基的化合物，其中A的一个至两个取代基可以选自卤代-C 1 -C 3烷基，环丙基 卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3炔基，卤代-C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤代C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯氧基，卤代烯硫基 氰基和硝基，A至1-4个取代基可以选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; R 2是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 3 -C 6环烷基， C 2 -C 6烯基或C 2 -C 6炔基; 且X是N-NO 2或N-CN，并且如果合适，其互变异构体在各种情况下以游离形式或盐形式可用作农业化学活性成分，并且可以以本身已知的方式制备。

    Oxadiazine derivatives
    20.
    发明授权
    Oxadiazine derivatives 有权

    公开(公告)号：US6022871A

    公开(公告)日：2000-02-08

    申请号：US252541

    申请日：1999-02-18

    申请人： Peter Maienfisch ,  Laurenz Gsell

    发明人： Peter Maienfisch ,  Laurenz Gsell

    IPC分类号： A01N43/88 ,  C07D273/04 ,  C07D417/06

    CPC分类号： A01N51/00 ,  A01N47/40 ,  C07D273/04 ,  C07D413/06 ,  C07D417/06

    摘要： Compounds of the formula ##STR1## in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C.sub.1 -C.sub.3 alkyl, cyclopropyl, halocyclopropyl, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, halo-C.sub.2 -C.sub.3 alkenyl, halo-C.sub.2 -C.sub.3 alkynyl, halo-C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, halo-C.sub.1 -C.sub.3 alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen;R is hydrogen, C.sub.1 -C.sub.6 alkyl, phenyl-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl; andX is N--NO.sub.2 or N--CN,and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.