摘要:
The invention relates to compositions for defoaming aqueous media, comprising as defoamers urea derivatives of the formula I where R1 is a hydrocarbon radical, preferably having 4 to 30 carbon atoms or a hydrocarbon radical, preferably having 4 to 24 carbon atoms and one nitrogen atom or a hydrocarbon radical, preferably having 4 to 30 carbon atoms and one carbonyl group, R2 is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R3 is a hydrogen atom or a hydrocarbon radical, preferably having 1 to 24 carbon atoms, R4 is an organic radical, preferably having 2 to 30 carbon atoms, and n is from 0 to 5; in the form of solid particles, which are obtained by crystallization from a clear homogeneous melt dispersed in a carrier medium, and a process of preparation thereof.
摘要:
Polyoxyalkylene-polysiloxane block copolymers are disclosed which exhibit an outstanding defoaming action and have the special advantage of not causing wetting defects when dispersions defoamed therewith are applied on a 2-dimensional substrate. Dispersions of polymeric organic substances, especially dispersions of vehicles, coating agents and adhesives are defoamed by the addition of 0.01 to 2.0% by weight, based on the dispersion to be defoamed, of a polyoxyalkylene-polysiloxane block copolymer of the formula,R.sup.1 O--A--[B--A--].sub.m R.sup.1whereinA is a polyoxyalkylene block with the average formula C.sub.n H.sub.2n O--)y, in which n has a value of 2.8 to 4.0 and y a value of 15 to 100,B is a polysiloxane block of the average formula, ##STR1## wherein the R.sup.2 groups are the same or different and represent an alkyl group with 1 to 4 carbon atoms or a phenyl group, with the proviso that at least 90% of the R.sup.2 groups are methyl groups and x has a value of 10 to 100,R.sup.1 groups are the same or different and represent a hydrogen atom or an alkyl group with 1 to 4 carbon atoms andm has a value of 4 to 20.
摘要翻译:公开了具有优异的消泡作用的聚氧化烯 - 聚硅氧烷嵌段共聚物,并且具有在将其消泡的分散体施加在二维基材上时不会引起润湿缺陷的特殊优点。 聚合有机物质,特别是车辆分散体,涂层剂和粘合剂的分散体通过加入基于待消泡的分散体的0.01-2.0重量%的下式的聚氧化烯 - 聚硅氧烷嵌段共聚物,即R1O-A - [BA-] mR1其中A是平均式C n H 2n O - )y的聚氧化烯嵌段,其中n的值为2.8〜4.0,ya为15〜100,B为平均式的聚硅氧烷嵌段, IMAGE>其中R2基团相同或不同并且表示具有1至4个碳原子的烷基或苯基,条件是至少90%的R 2基团是甲基,x的值为10至 100,R 1相同或不同,表示氢原子或碳原子数为1〜4的烷基,m为4〜20的数。
摘要:
The invention relates to the polyoxyalkylene-polysiloxane block polymers of general formula (I) C—B—(AB)a—C1 (I), wherein A=a polyoxyalkylene block of the general formula —(CnH2nO)b—, B=a polysiloxane block of the general formula —(SiR2—O)c—, C, C1=the same or different alkoxypolyoxyalkylene groups of the general formula Z—O—[CH2—CH(R1)O]d—, R=the same or different C1-4 alkyl groups or phenyl groups, with the proviso that at least 90% of the groups R are methyl groups, R1=the same or different hydrogen, C1-12 alkyl groups or phenyl groups, Z=an alkyl, alkylene, aryl or alkylaryl group, a=1 to 20, preferably 2 to 10, b=an average value of 10 to 130, preferably 20 to 100, c=3 to 100, preferably 10 to 80, d=independently is in the range of C/C1 values of 2 to 20, preferably 2 to 12, with the proviso that the average value is in the range of 2 to
摘要:
The invention relates to the use of water-insoluble polyoxyalkylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble polyoxyalkylene-polysiloxane block copolymers as well as coating materials, printing inks and cooling lubricants containing the inventive defoaming compositions.
摘要:
The invention relates to the use of a water-insoluble polyoxyarylene-polysiloxane block copolymers of the general average formula wherein the variables and indices are described herein as defoaming agents for aqueous media. This invention also provides for defoaming compositions comprising said water-insoluble block copolymers.
摘要:
The invention relates to compound antifoams comprising alkoxylated partial esters--using from 3 to 60 mol of propylene oxide with or without from 1 to 10 mol of styrene oxide and/or from 1 to 10 mol of butylene oxide--of oligoglycerols, obtainable by condensation of 2 to 20 glycerol molecules, with C.sub.8 to C.sub.22 fatty acids and inorganic or organic solids for defoaming polymer dispersions and aqueous coating systems.
摘要:
A composition is disclosed which is useful for the water-repellent impregnation of porous mineral building materials. The composition is based on organosilicon compounds which contain alkoxy groups and comprises an emulsion which contains 2.5 to 25% by weight of an alkoxysilane of the formulaR.sup.1 -Si(OR.sup.2).sub.3whereinR.sup.1 is an alkyl group with 3 to 12 carbon atoms andR.sup.2 is a methyl or ethyl group, 2 to 20% by weight of an alkoxysiloxane of the formula ##STR1## wherein R.sup.3 is an alkyl group with 1 to 6 carbon atomsa is 0.8 to 1.2 andb is 0.2 to 1.2,0.01 to 5% by weight of an emulsifier, 0.01 to 0.1% by weight of fillers with an effective surface area of at least 40 m.sup.2 /g and 49.9 to 95.48% by weight of water. The composition has a long shelf life and, due to its high penetration, a high water-repellent effect on the surface, as well as deep within, all mineral building materials.