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    PROCESS FOR PRODUCING POLYETHER POLYOL, PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM, AND SHEET
    3.
    发明申请
    PROCESS FOR PRODUCING POLYETHER POLYOL, PROCESS FOR PRODUCING FLEXIBLE POLYURETHANE FOAM, AND SHEET 有权
    生产聚醚多元醇的方法，生产柔性聚氨酯泡沫的方法和用途

    公开(公告)号：US20140031443A1

    公开(公告)日：2014-01-30

    申请号：US14041553

    申请日：2013-09-30

    申请人： Asahi Glass Company, Limited

    发明人： Takayuki Sasaki ,  Takashi Ito ,  Akio Horie ,  Chitoshi Suzuki ,  Takeaki Arai ,  Masahito Furumi

    IPC分类号： C08G18/48 ,  C08J9/00

    CPC分类号： C08G18/4841 ,  C08G18/4072 ,  C08G18/4845 ,  C08G18/4866 ,  C08G18/6677 ,  C08G65/2648 ,  C08G65/2663 ,  C08G2101/0008 ,  C08J9/00

    摘要： To suppress deterioration of mechanical properties of a foam, by using a polyol system solution stored. A polyol system solution is prepared by using a polyether polyol (A1) having a hydroxy value of from 5 to 45 mgKOH/g and an average number of hydroxy groups of from 2 to 8, obtainable by subjecting an alkylene oxide to ring-opening addition polymerization to an initiator, in the presence of a double metal cyanide complex catalyst, to obtain an intermediate polyol; and subjecting ethylene oxide to a ring-opening addition polymerization in an amount of from 1 to 23 mol per 1 mol of the initiator to the intermediate polyol, in the presence of an alkali metal hydroxide as a polymerization catalyst, and a flexible polyurethane foam is produced by using the polyol system solution.

    摘要翻译： 通过使用储存的多元醇系溶液来抑制发泡体的机械性能的劣化。 通过使用羟值为5〜45mgKOH / g的聚醚多元醇（A1），平均羟基数为2〜8，可以通过使环氧烷开环加成得到多元醇体系溶液 在双金属氰化物配合物催化剂的存在下，引发剂聚合，得到中间体多元醇; 并且在作为聚合催化剂的碱金属氢氧化物的存在下，使环氧乙烷以1〜23摩尔/ 1摩尔引发剂与中间体多元醇的开环加聚反应，和软质聚氨酯泡沫体 通过使用多元醇体系溶液制备。

    Process for the preparation of polyether alcohols from unsaturated starters having active hydrogen atoms
    4.
    发明授权
    Process for the preparation of polyether alcohols from unsaturated starters having active hydrogen atoms 有权
    从具有活性氢原子的不饱和起始物制备聚醚醇的方法

    公开(公告)号：US08399608B2

    公开(公告)日：2013-03-19

    申请号：US12681789

    申请日：2007-10-25

    申请人： Georg Heinrich Grosch ,  Matthias Zipplies ,  Thomas Ostrowski ,  Ulrich Annen ,  Markus Klumpe

    发明人： Georg Heinrich Grosch ,  Matthias Zipplies ,  Thomas Ostrowski ,  Ulrich Annen ,  Markus Klumpe

    IPC分类号： C08G65/10 ,  C08G65/30 ,  C08G65/34 ,  C08F8/06 ,  C08F6/08

    CPC分类号： C08G65/2609 ,  C08G65/2648 ,  C08G65/2696

    摘要： A process for the preparation of polyether alcohols by reacting at least one alkylene oxide with at least one unsaturated starter having at least one active hydrogen atom per molecule under basic catalysis, that the alkoxylation is carried out in at least two stages, in stage (I) the alkoxylation of the starter or starters being carried out with not more than 10 mol of alkylene oxide per mole of starter with a catalyst concentration of not more than 0.0085 mol of basic catalyst per mole and in stage (II) and the optionally following stages, the alkoxylated starter or starters from stage (I) being reacted with further alkylene oxide at a catalyst concentration of at least 0.01 mol of basic catalyst per mole of starter.

    摘要翻译： 通过在碱性催化下使至少一种烯化氧与至少一种具有至少一个活性氢原子的不饱和起始物在每个分子中反应来制备聚醚醇的方法，该烷氧基化在至少两个阶段中在阶段（I ）起始物或起动器的烷氧基化作用，每摩尔起始物不超过10摩尔环氧烷烃，每摩尔催化剂浓度不大于0.0085摩尔碱性催化剂和（II）阶段和任选的后续阶段 ，来自阶段（I）的烷氧基​​化起始物或起始物与另外的烯化氧反应，每摩尔起始物的催化剂浓度为至少0.01摩尔碱性催化剂。

    Vinyl alcohol-based polymer and film containing the same
    7.
    发明授权
    Vinyl alcohol-based polymer and film containing the same 有权
    乙烯基醇基聚合物和含有它的薄膜

    公开(公告)号：US08076433B2

    公开(公告)日：2011-12-13

    申请号：US12810626

    申请日：2009-08-25

    申请人： Shinsuke Nii ,  Masato Nakamae ,  Makio Tokoh

    发明人： Shinsuke Nii ,  Masato Nakamae ,  Makio Tokoh

    IPC分类号： C08F18/02 ,  C08F16/06

    CPC分类号： C08F290/062 ,  C08F8/12 ,  C08G65/2648 ,  C08G65/3322 ,  C08G65/33306 ,  C08G81/025 ,  C08J5/18 ,  C08J2371/02 ,  C08L29/04 ,  C08L71/02 ,  C08L2205/05 ,  C08F218/08 ,  C08L2666/04 ,  C08F118/08

    摘要： Provided are a polyoxyalkylene modified vinyl alcohol-based polymer, including a polyoxyalkylene group in side chain, wherein the vinyl alcohol-based polymer has a viscosity average degree of polymerization P of from 200 to 5000, has a degree of saponification of from 20 to 99.99 mol %, and has an amount S of polyoxyalkylene modification of from 0.1 to 10 mol % and a film containing the same. By way of them, a polyvinyl alcohol-based polymer that is soluble in water and also high in viscosity, and a film that is less in a decrease of tensile elastic modulus when conditioned in high humidity, is excellent in water repellency on the film surface, and exhibits water solubility are provided.

    摘要翻译： 本发明提供一种聚侧亚烷基改性乙烯醇系聚合物，其包含侧链中的聚氧化烯基，其中乙烯醇系聚合物的粘均聚合度P为200〜5000，皂化度为20〜99.99 mol％，聚氧亚烷基改性量S为0.1〜10mol％，含有该聚氧化烯改性的膜。 通过它们，可溶于水并且粘度高的聚乙烯醇类聚合物和在高湿度条件下拉伸弹性模量降低时较小的膜在膜表面上的防水性优异 ，并提供水溶性。

    PROCESS FOR PREPARING POLYOLS USING BASE CATALYSIS
    9.
    发明申请
    PROCESS FOR PREPARING POLYOLS USING BASE CATALYSIS 审中-公开
    使用基础催化制备多元醇的方法

    公开(公告)号：US20110224397A1

    公开(公告)日：2011-09-15

    申请号：US13042781

    申请日：2011-03-08

    申请人： Thomas OSTROWSKI ,  Anne-Kathrin Merten ,  Achim Löffler ,  Hermann Graf

    发明人： Thomas OSTROWSKI ,  Anne-Kathrin Merten ,  Achim Löffler ,  Hermann Graf

    IPC分类号： C08G18/48 ,  C07C41/26 ,  C07C43/03

    CPC分类号： C07C41/03 ,  C08G18/4829 ,  C08G65/2609 ,  C08G65/2648 ,  C08G65/2696 ,  C07C43/11

    摘要： The present invention relates to a process for preparing polyetherols in the presence of basic catalysts, wherein propylene oxide (PO) and/or ethylene oxide (EO) whose summated contents of aldehydes, expressed by the contents determined by gas chromatography or titrimetrically using the bisulfite method and calculated for propionaldehyde, do not exceed the value of 300 ppm and of allyl alcohol determined by gas chromatography do not exceed the value of 2500 ppm and of water determined by Karl-Fischer titration do not exceed the value of 1700 ppm and of acid, expressed by the contents determined by acid-base titration and calculated for acetic acid, do not exceed the value of 100 ppm and of carbon dioxide determined by KOH titration do not exceed the value of 500 ppm are used.

    摘要翻译： 本发明涉及一种在碱性催化剂存在下制备聚醚的方法，其中由醛的含量表示的环氧丙烷（PO）和/或环氧乙烷（EO）通过气相色谱法或滴定法使用亚硫酸氢盐 方法并计算丙醛，不超过300ppm，由气相色谱法测定的烯丙醇不超过2500ppm，由卡尔费休滴定测定的水不超过1700ppm的酸和酸 由酸碱滴定测定的含量表示，乙酸计算值不超过100ppm，通过KOH滴定测定的二氧化碳的值不超过500ppm。

    VINYL ALCOHOL-BASED POLYMER AND FILM CONTAINING THE SAME
    10.
    发明申请
    VINYL ALCOHOL-BASED POLYMER AND FILM CONTAINING THE SAME 有权
    基于乙烯醇的聚合物和包含其的膜

    公开(公告)号：US20100280202A1

    公开(公告)日：2010-11-04

    申请号：US12810626

    申请日：2009-08-25

    申请人： Shinsuke Nii ,  Masato Nakamae ,  Makio Tokoh

    发明人： Shinsuke Nii ,  Masato Nakamae ,  Makio Tokoh

    IPC分类号： C08F20/58 ,  C08F18/04

    CPC分类号： C08F290/062 ,  C08F8/12 ,  C08G65/2648 ,  C08G65/3322 ,  C08G65/33306 ,  C08G81/025 ,  C08J5/18 ,  C08J2371/02 ,  C08L29/04 ,  C08L71/02 ,  C08L2205/05 ,  C08F218/08 ,  C08L2666/04 ,  C08F118/08

    摘要： Provided are a polyoxyalkylene modified vinyl alcohol-based polymer, including a polyoxyalkylene group in side chain, wherein the vinyl alcohol-based polymer has a viscosity average degree of polymerization P of from 200 to 5000, has a degree of saponification of from 20 to 99.99 mol %, and has an amount S of polyoxyalkylene modification of from 0.1 to 10 mol % and a film containing the same. By way of them, a polyvinyl alcohol-based polymer that is soluble in water and also high in viscosity, and a film that is less in a decrease of tensile elastic modulus when conditioned in high humidity, is excellent in water repellency on the film surface, and exhibits water solubility are provided.

    摘要翻译： 本发明提供一种聚侧亚烷基改性乙烯醇系聚合物，其包含侧链中的聚氧化烯基，其中乙烯醇系聚合物的粘均聚合度P为200〜5000，皂化度为20〜99.99 mol％，聚氧亚烷基改性量S为0.1〜10mol％，含有该聚氧化烯改性的膜。 通过它们，可溶于水并且粘度高的聚乙烯醇类聚合物和在高湿度条件下拉伸弹性模量降低时较小的膜在膜表面上的防水性优异 ，并提供水溶性。