Mixtures of a 1:1 copper or nickel complex of a stilbene-azo or
stilbene-azoxy compound having two 4,4'-(2,2'-disulfostilbenylene)
radicals and a 1:1 copper or nickel complex of a stilbene-azo or
stilbene-azoxy compound having one such radical
    12.
    发明授权
    Mixtures of a 1:1 copper or nickel complex of a stilbene-azo or stilbene-azoxy compound having two 4,4'-(2,2'-disulfostilbenylene) radicals and a 1:1 copper or nickel complex of a stilbene-azo or stilbene-azoxy compound having one such radical 失效
    具有2个4,4' - (2,2'-二磺基亚磺酰亚基)基团的1,2-二苯乙烯 - 偶氮苯乙烯 - 偶氮苯氧基化合物的1:1铜或镍配合物与1,2-二苯乙烯偶氮铜或镍络合物的混合物 或具有一个这样的基团的芪 - 囟氧化合物

    公开(公告)号:US4954133A

    公开(公告)日:1990-09-04

    申请号:US828934

    申请日:1986-02-12

    Applicant: Max Oppliger

    Inventor: Max Oppliger

    CPC classification number: C09B45/00 C09B35/00 C09B56/06 D06P5/08 Y10S534/01

    Abstract: Compounds of the formula ##STR1## wherein each A, independently, is a ##STR2## wherein R.sub.1 is hydrogen, halo, C.sub.1-4 alkyl or C.sub.1-4 alkoxy,R.sub.2 is hydrogen, halo, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, --NHCONH.sub.2 or --NHCOC.sub.1-4 alkyl,R.sub.3 is hydrogen or methoxy, andm is 0, 1 or 2,each B, independently, is a radical of a diazo or coupling component, and a and each b, independently, are 0 or 1,and metal complexes thereof, which compounds or complexes are in free acid or salt form, and mixtures thereof with a compound of the formula ##STR3## or a metal complex thereof, wherein A and b are as defined above and D is a radical of a diazo or coupling component of the benzene or 1-naphthalene series are useful for dyeing and printing hydroxy group- or nitrogen-containing organic substrates, especially cellulose fibre-containing textiles (e.g., cotton), paper and leather. The fastness properties of the obtained dyeings and prints may be further improved by after-treating the dyed or printed substrate with a special fixing agent.

    Abstract translation: 其中每个A独立地是其中R 1是氢,卤素,C 1-4烷基或C 1-4烷氧基,R 2是氢,卤素,C 1-4烷基,C 1-4烷氧基,-NHCONH 2或 -NHCOC 1-4烷基,R 3是氢或甲氧基,m是0,1或2,每个B独立地是重氮或偶合组分的基团,并且各个b独立地是0或1,金属 其化合物或络合物为游离酸或盐形式,以及其与下式化合物或其金属络合物的混合物,其中A和b如上所定义,D为重氮基团或 苯或1-萘系的偶联组分可用于染色和印刷羟基或含氮有机基材,特别是含纤维素纤维的纺织品(如棉花),纸和皮革。 通过用特殊固定剂对染色或印刷的基材进行后处理,可以进一步提高所得染色和印花的牢度性能。

    Metal-free azo compounds containing a vinylsulfonyl group and at least
one basic group and 1:1 and 1:2 metal complexes thereof
    13.
    发明授权
    Metal-free azo compounds containing a vinylsulfonyl group and at least one basic group and 1:1 and 1:2 metal complexes thereof 失效
    含有乙烯基磺酰基和至少一个碱性基团和其1:1和1:2的金属络合物的无金属偶氮化合物

    公开(公告)号:US4820806A

    公开(公告)日:1989-04-11

    申请号:US847405

    申请日:1986-02-28

    CPC classification number: C09B62/507

    Abstract: Metal-free monoazo and disazo compounds of the formulaCH.sub.2 .dbd.CH--SO.sub.2 --W.sub.1 --D--N.dbd.N--K--(W.sub.2 --Z).sub.n,1:1 and 1:2 metal complexes of such metallizable metal-free compounds and acid addition salts of such metal-free compounds and 1:1 and 1:2 metal complexes, whereinD is the radical of a diazo component of the benzene, naphthalene or tetrahydronaphthalene series,K is the radical of a coupling component of the benzene, naphthalene, pyrazol-5-one, pyridine, pyridone, barbituric acid, quinoline, isoquinoline, benzeneazobenzene, benzeneazonaphthalene, naphthaleneazobenzene, naphthaleneazonaphthalene, tetrahydronaphthaleneazobenzene, tetrahydronaphthaleneazonaphthalene or acetoacetamide series,W.sub.1 is a direct bond or a divalent bridging radical,each W.sub.2 is independently a divalent bridging radical,each Z is independently a water-solubilizing protonatable amino group, a quaternary ammonium group, a hydrazinium group or a ternary sulfonium group, andn is 1, 2, 3 or 4,are useful for dyeing and printing fibers, threads and textile materials, particularly those containing or consisting of natural or synthetic polyamide, cotton, polyacrylonitrile, leather or fiber blends such as cotton-polyester, polyester-wool and polyacrylonitrile-wool.

    Abstract translation: PCT No.PCT / EP85 / 00305 Sec。 371日期1986年2月28日 102(e)日期1986年2月28日PCT提交1985年6月25日PCT公布。 出版物WO86 / 00632 日期:1986年1月30日。这种可金属化的金属络合物的金属络合物为CH 2 = CH-SO 2 -W 1-DN = NK-(W2-Z)n,1:1和1:2的金属单偶氮和双偶氮化合物, 这种无金属化合物和1:1和1:2金属络合物的游离化合物和酸加成盐,其中D是苯,萘或四氢化萘系的重氮组分的基团,K是偶联组分的基团 苯,萘,吡唑-5-酮,吡啶,吡啶酮,巴比妥酸,喹啉,异喹啉,苯偶氮苯,苯偶氮萘,萘偶氮苯,萘氮萘,四氢萘基偶氮苯,四氢萘萘或乙酰乙酰胺系列,W1为直接键或二价桥连基, 独立地是二价桥连基团,每个Z独立地是可溶于水的可质子化氨基,季铵基团,肼基团或三元锍基团,并且n为1,2,3或4,可用于染料 特别是含有或由天然或合成聚酰胺,棉花,聚丙烯腈,皮革或纤维混合物如棉 - 聚酯,聚酯 - 羊毛和聚丙烯腈 - 羊毛组成的纤维,线和纺织材料。

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