Water-soluble azo compounds and polarizing films using the compounds
    3.
    发明授权
    Water-soluble azo compounds and polarizing films using the compounds 失效
    使用该化合物的水溶性偶氮化合物和偏振膜

    公开(公告)号:US5423100A

    公开(公告)日:1995-06-13

    申请号:US95839

    申请日:1993-07-23

    CPC classification number: G02B5/3033 C09B56/04

    Abstract: Novel azo compounds having the specific structural formula (1) or (3) set out below, water-soluble dyes containing the compounds, and polarizing films containing the water-soluble dyes: ##STR1## wherein R.sub.1 represents a hydrogen or halogen atom or a hydroxyl, C.sub.1-2 alkyl, C.sub.1-2 alkoxy, C.sub.1-2 acylamino, cyano, carboxyl or sulfonic acid group; R.sub.3 and R.sub.8 individually represent a hydrogen atom or a hydroxyl, C.sub.1-2 alkyl or C.sub.1-2 alkoxy group; R.sub.2 and R.sub.4 individually represent a hydrogen atom or a hydroxyl, C.sub.1-2 alkyl, C.sub.1-2 alkoxy or C.sub.1-2 acylamino group; R.sub.5 represents a hydrogen atom or a carboxyl or C.sub.1-2 alkoxy group; R.sub.6 represents a hydrogen atom, a hydroxyl, amino, methylamino, .beta.-hydroxyethylamino or C.sub.1-2 acylamino group, or a phenylamino or benzoylamino group which the phenyl nucleus may be substituted by one or more nitro, amino, hydroxyl, C.sub.1-2 alkyl, carboxyl and/or sulfonic acid groups and/or chlorine atoms; R.sub.7 represents a hydroxyl or amino group and substitutes at o- or p-position relative to the azo group; m stands for 0 or 1; p stands for 0 or 1; q stands for 0, 1 or 2; and M represents a copper, nickel, zinc or iron atom.

    Abstract translation: 具有以下具体结构式(1)或(3)的新型偶氮化合物,含有该化合物的水溶性染料和含有水溶性染料的偏振膜:(1) 3)其中R 1表示氢或卤素原子或羟基,C 1-2烷基,C 1-2烷氧基,C 1-2酰氨基,氰基,羧基或磺酸基; R 3和R 8分别表示氢原子或羟基,C 1-2烷基或C 1-2烷氧基; R2和R4各自表示氢原子或羟基,C1-2烷基,C1-2烷氧基或C1-2酰氨基; R5表示氢原子或羧基或C1-2烷氧基; R6表示氢原子,羟基,氨基,甲基氨基,β-羟乙基氨基或C1-2酰氨基,或苯基氨基或苯甲酰基氨基,苯基可以被一个或多个硝基,氨基,羟基,C 1-2烷基取代 ,羧基和/或磺酸基和/或氯原子; R7表示羟基或氨基,并且相对于偶氮基在邻位或对位取代; m代表0或1; p代表0或1; q代表0,1或2; M表示铜,镍,锌或铁原子。

    Process for the preparation of the dyestuff direct yellow 11 in the form
of concentrated stable solutions, the solutions obtained and their
applications
    6.
    发明授权
    Process for the preparation of the dyestuff direct yellow 11 in the form of concentrated stable solutions, the solutions obtained and their applications 失效
    制备染料直接黄11的方法为浓缩稳定溶液,得到的溶液及其应用

    公开(公告)号:US4310331A

    公开(公告)日:1982-01-12

    申请号:US237566

    申请日:1981-02-23

    CPC classification number: C09B67/0073 C09B56/04 C09B69/04

    Abstract: The invention relates to a process for the preparation of the dyestuff Direct Yellow 11 directly in the form of stable concentrated solutions, in which caustic soda in aqueous solution is reacted, at a temperature from 40.degree. to 90.degree. C., with a solution containing 4-nitro-toluene-2-sulfonic acid, one or more alkanolamines, one or more alcohols containing an etheroxide function or a second alcohol function, then the caustic soda is neutralized by addition of sulfuric acid and the sodium sulfate thus formed is separated by filtration. The solutions obtained by the process according to the invention are particularly suitable for dyeing cellulosic materials and leather.

    Abstract translation: 本发明涉及直接以40℃至90℃的温度从水溶液中苛性钠反应的稳定浓缩溶液形式制备染料直接黄11的方法,该方法含有 4-硝基 - 甲苯-2-磺酸,一种或多种链烷醇胺,一种或多种含有羟基氧化物官能团或第二醇官能团的醇,然后通过加入硫酸将苛性钠中和,由此形成的硫酸钠由 过滤。 通过根据本发明的方法获得的溶液特别适用于染色纤维素材料和皮革。

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