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公开(公告)号：US5329033A
公开(公告)日：1994-07-12
申请号：US142512
申请日：1993-10-25
申请人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
发明人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
IPC分类号： C07C13/465 , C07C1/24 , C07C45/28 , C07C45/46 , C07C49/67 , C07F7/00 , C07F17/00 , C08F2/06 , C08F4/60 , C08F4/625 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F4/82 , C08F10/00 , C08F110/06 , C07F7/28 , C07F9/00 , C07F11/00
CPC分类号： C07C45/46 , C07C13/465 , C07C45/28 , C07C49/67 , C07F17/00 , C08F10/00 , C07C2102/08 , C08F110/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very effective catalyst system for olefin polymerization consists of a cocatalyst, preferably an aluminoxane, and a metallocene of the formula (I) ##STR1## in which, preferably, M.sup.1 is Zr, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 to R.sup.6 are alkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a chain having one or more members, in which R.sup.7 can also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system leads to polymers of variable molecular weight and stereotacticity, depending on the substituents R.sup.3 to R.sup.6 chosen, at polymerization temperatures which are relevant in industry.
摘要翻译： 用于烯烃聚合的非常有效的催化剂体系由助催化剂，优选铝氧烷和式（I）的茂金属和R2是烷基或卤素，R3至R6是烷基， - （CR8R9）m-R7-（CR8R9） n是具有一个或多个成员的链，其中R7也可以是（取代的）杂原子，并且m + n为零或1.催化剂体系导致可变分子量和立体活性的聚合物，这取决于取代基 在工业相关的聚合温度下选择R3至R6。
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公开(公告)号：US5278264A
公开(公告)日：1994-01-11
申请号：US934573
申请日：1992-08-24
申请人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
发明人： Walter Spaleck , Jurgen Rohrmann , Martin Antberg
IPC分类号： C07C13/465 , C07C1/24 , C07C45/28 , C07C45/46 , C07C49/67 , C07F7/00 , C07F17/00 , C08F2/06 , C08F4/60 , C08F4/625 , C08F4/6392 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F4/76 , C08F4/82 , C08F10/00 , C08F110/06 , C08F4/64
CPC分类号： C07C45/46 , C07C13/465 , C07C45/28 , C07C49/67 , C07F17/00 , C08F10/00 , C07C2102/08 , C08F110/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very effective catalyst system for olefin polymerization consists of a cocatalyst, preferably an aluminoxane, and a metallocene of the formula (I) ##STR1## in which, preferably, M.sup.1 is Zr, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 to R.sup.6 are alkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a chain having one or more members, in which R.sup.7 can also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system leads to polymers of variable molecular weight and stereotacticity, depending on the substituents R.sup.3 to R.sup.6 chosen, at polymerization temperatures which are relevant in industry.
摘要翻译： 用于烯烃聚合的非常有效的催化剂体系由助催化剂，优选铝氧烷和式（I）的金属茂（*化学结构*）（I）组成，其中优选M1是Zr，R1和R2是烷基或 卤素，R3至R6是烷基， - （CR8R9）m-R7-（CR8R9）n - 是具有一个或多个成员的链，其中R7也可以是（取代的）杂原子，并且m + n为零或 根据与工业相关的聚合温度，催化剂体系导致可变分子量和立体定向性的聚合物，这取决于所选择的取代基R 3至R 6。
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公开(公告)号：US5243001A
公开(公告)日：1993-09-07
申请号：US960249
申请日：1992-10-13
IPC分类号： C08F4/659 , C08F4/6592 , C08F10/00 , C08F10/06 , C08F110/02 , C08F110/06 , C08F210/06
CPC分类号： C08F110/06 , C08F10/00 , C08F10/06 , C08F110/02 , C08F210/06 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization is composed of an aluminoxane and a metallocene of the formula I ##STR1## wherein preferably M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen, R.sup.5 and R.sup.6 are alkyl or haloalkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.m --is a single-membered or multimembered chain in which R.sup.7 may also be a (substituted) hetero atom, and m+n is zero or 1. The catalyst system gives polymers having a high molecular weight and high stereospecificity.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系由铝氧烷和式I的茂金属组成（I），其中优选M1是Zr或Hf，R1和R2是烷基或卤素，R3和R4是氢，R5和 R6是烷基或卤代烷基， - （CR8R9）m-R7-（CR8R9）m-是单元或多元链，其中R7也可以是（取代的）杂原子，并且m + n为零或1. 催化剂体系提供具有高分子量和高立体定向性的聚合物。
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公开(公告)号：US5132381A
公开(公告)日：1992-07-21
申请号：US490833
申请日：1990-03-08
IPC分类号： C07F17/00 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F110/06
CPC分类号： C08F110/06 , C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A syndiotactic polyolefin is obtained in a high yield by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst consisting of a metallocene of the formula I ##STR1## and an aluminoxane. This polyolefin has a very high syndiotactic index. At a low polymerization temperature, a polyolefin having a low average molecular weight and narrow molecular weight distribution is obtained, and at a high polymerization temperature a polymer having a high average molecular weight and a wide molecular weight distribution is obtained.Shaped articles produced from the polymers are distinguished by a high transparency, flexibility, tear strength and excellent surface gloss.
摘要翻译： 在由式I（I）的茂金属和铝氧烷组成的催化剂的存在下，通过式R a -CH = CH-R b的烯烃的聚合或共聚，可以高产率获得间同立构聚烯烃。 该聚烯烃具有非常高的间同立构指数。 在低聚合温度下，获得具有低平均分子量和窄分子量分布的聚烯烃，并且在高聚合温度下获得具有高平均分子量和宽分子量分布的聚合物。 由聚合物制成的成型品通过高透明度，柔韧性，撕裂强度和优异的表面光泽来区分。
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公开(公告)号：US5086134A
公开(公告)日：1992-02-04
申请号：US424116
申请日：1989-10-19
IPC分类号： C08F4/642 , C07F17/00 , C08F2/02 , C08F4/58 , C08F4/60 , C08F4/602 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/02 , C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65922 , Y10S526/902 , Y10S526/909 , Y10S526/943
摘要： The invention relates to a process for the preparation of a predominantly crystalline ethylene/propylene copolymer having less than 15 mol % of propylene units, which can be carried out in liquid propylene as the suspending agent, if metallocene catalyst components of the formulae I, II or III are employed and the partial pressures of ethylene and propylene have a specific ratio. ##STR1## By means of this process, it is possible to increase the possible uses of polymerization plants which work with liquid propylene.
摘要翻译： 本发明涉及一种制备主要结晶的乙烯/丙烯共聚物的方法，其具有小于15mol％的丙烯单元，其可以在作为悬浮剂的液态丙烯中进行，如果式I，II的茂金属催化剂组分 或III，并且乙烯和丙烯的分压具有特定的比例。 （Ⅰ）<图像>（II）<图像>（III）通过该方法，可以增加与液体丙烯一起使用的聚合装置的可能用途。
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公开(公告)号：US06063880A
公开(公告)日：2000-05-16
申请号：US464458
申请日：1995-06-05
IPC分类号： C08F10/00 , C07F17/00 , C08F4/60 , C08F4/622 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F4/6592 , C08F110/06
CPC分类号： C08F110/06 , C07F17/00 , C08F4/63912 , C08F4/63927 , Y10S585/946
摘要： If a catalyst consisting of an aluminoxane and a metallocene of the formula I ##STR1## in particular R.sup.5 R.sup.6 C (Ind).sub.2 or R.sup.5 R.sup.6 C (Ind).sub.2 Zr(CH.sub.3).sub.2, is employed for the polymerization of olefins of the formulaR.sup.9 CH.dbd.CHR.sup.10(R.sup.9, R.sup.10 =H or C.sub.1 -C.sub.28 alkyl), the isotacticity of the polymer wax and hence the hardness and melting point can be varied simply by changing the polymerization temperature, without the molecular weight of the polymer being noticeably changed at the same time.
摘要翻译： 如果由式I的特别是R5R6C（Ind）2或R5R6C（Ind）2Zr（CH3）2的铝氧烷和茂金属组成的催化剂用于式R 9 CH = CHR 10的烯烃的聚合（R9，R10 = H或C 1 -C 28烷基），聚合物蜡的全同立构规整度，因此硬度和熔点可以通过改变聚合温度来简单地改变，同时聚合物的分子量同时显着改变。
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17.再颁专利
公开(公告)号：USRE36103E
公开(公告)日：1999-02-16
申请号：US278504
申请日：1994-07-21
IPC分类号： C07F17/00 , C08F4/60 , C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F8/00 , C08F10/00 , C08F110/06
CPC分类号： C08F110/06 , C07F17/00 , C08F10/00 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A syndiotactic polyolefin is obtained in a high yield by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b in the presence of a catalyst consisting of a metallocene of the formula I ##STR1## and an aluminoxane. This polyolefin has a very high syndiotactic index. At a low polymerization temperature, a polyolefin having a low average molecular weight and narrow molecular weight distribution is obtained, and at a high polymerization temperature a polymer having a high average molecular weight and a wide molecular weight distribution is obtained.Shaped articles produced from the polymers are distinguished by a high transparency, flexibility, tear strength and excellent surface gloss.
摘要翻译： 在由式I（I）的茂金属和铝氧烷组成的催化剂的存在下，通过式R a -CH = CH-R b的烯烃的聚合或共聚，可以高产率获得间同立构聚烯烃。 该聚烯烃具有非常高的间同立构指数。 在低聚合温度下，获得具有低平均分子量和窄分子量分布的聚烯烃，并且在高聚合温度下获得具有高平均分子量和宽分子量分布的聚合物。 由聚合物制成的成型品通过高透明度，柔韧性，撕裂强度和优异的表面光泽来区分。
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公开(公告)号：US5672668A
公开(公告)日：1997-09-30
申请号：US107187
申请日：1993-08-16
申请人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
发明人： Andreas Winter , Martin Antberg , Bernd Bachmann , Volker Dolle , Frank Kuber , Jurgen Rohrmann , Walter Spaleck
IPC分类号： C07F17/00 , C08F4/44 , C08F4/60 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/642 , C08F10/00 , C08F110/06 , C08F297/08
CPC分类号： C08F297/083 , C07F17/00 , C08F10/00 , C08F110/06 , C08F4/63912 , C08F4/63916 , C08F4/63927 , Y10S526/943
摘要： A process for the preparation of an olefin polymer by polymerization or copolymerization of an olefin of the formula R.sup.a --CH.dbd.CH--R.sup.b, in which R.sup.a and R.sup.b are identical or different and are a hydrogen atom or a hydrocarbon radical having 1 to 14 carbon atoms, or R.sup.a and R.sup.b, together with the atoms connecting them, can form a ring, at a temperature of from -60.degree. to 200.degree. C., at a pressure of from 0.5 to 100 bar, in solution, in suspension or in the gas phase, in the presence of a catalyst formed from a metallocene in the meso-form or a meso:rac mixture, with meso:rac>1:99, as transition-metal compound and a cocatalyst, wherein the metallocene is a compound of the formula I, ##STR1## in which M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are identical or different and are methyl or chlorine, R.sup.3 and R.sup.6 are identical or different and are methyl, isopropyl, phenyl, ethyl or trifluoromethyl, R.sup.4 and R.sup.5 are hydrogen or as defined for R.sup.3 and R.sup.6, or R.sup.4 forms an aliphatic or aromatic ring with R.sup.6, or adjacent radicals R.sup.4 form a ring of this type, and R.sup.7 is a ##STR2## radical, and m plus n is zero or 1.
摘要翻译： 通过聚合或共聚式Ra-CH = CH-Rb的烯烃制备烯烃聚合物的方法，其中Ra和Rb相同或不同，并且是氢原子或具有1至14碳原子的烃基 原子或R a和R b与连接它们的原子一起在-60至200℃的温度下，在0.5至100巴的压力下，在溶液中，悬浮液中或在 在由外消旋混合物中内消旋金属茂或内消旋混合物形成的催化剂的存在下，作为过渡金属化合物和助催化剂，其中金属茂是化合物 其中M1是Zr或Hf，R1和R2是相同或不同的，是甲基或氯的式I，其中R 3和R 6相同或不同，是甲基，异丙基，苯基，乙基或三氟甲基 ，R 4和R 5是氢或如对R 3和R 6所定义，或者R 4与R 6或相邻的镭形成脂族或芳族环 ls R4形成这种类型的环，而R7是a
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公开(公告)号：US5663268A
公开(公告)日：1997-09-02
申请号：US473131
申请日：1995-06-07
IPC分类号： C08F4/42 , C08F4/60 , C08F4/602 , C08F4/639 , C08F4/6392 , C08F4/64 , C08F4/642 , C08F4/646 , C08F4/659 , C08F4/6592 , C08F4/68 , C08F8/00 , C08F210/06 , C08J5/00 , C08J5/18
CPC分类号： C08F210/06 , C08F4/63912 , C08F4/63927 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A syndiotactic propylene copolymer is obtained in high yields by copolymerization of propylene with small amounts of other olefins in the presence of a catalyst comprising a metallocene of the formula I ##STR1## in which M.sup.1 is titanium, zirconium, hafnium, vanadium, niobium or tantalum and an aluminoxane. This copolymer has a very high molecular weight, a very narrow molecular weight distribution, very high syndiotaxicity, advantageously low melting points and rubber-like behavior. Molded articles produced from the polymer are distinguished by high transparency, flexibility and tear strength. Their main areas of application are packagings of any type.
摘要翻译： 在含有式I的金属茂（I）的催化剂的存在下，丙烯与少量的其它烯烃的共聚合，可以高收率获得间同立构丙烯共聚物，其中M1是钛，锆，铪，钒， 铌或钽和铝氧烷。 该共聚物具有非常高的分子量，非常窄的分子量分布，非常高的间同立构性，有利地低熔点和橡胶状行为。 由聚合物制成的模制品具有高透明度，柔韧性和撕裂强度。 它们的主要应用领域是任何类型的包装。
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公开(公告)号：US5239022A
公开(公告)日：1993-08-24
申请号：US962032
申请日：1992-10-15
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06
CPC分类号： C08F10/00 , C08F110/02 , C08F110/06 , C08F210/06 , C08F4/65908 , C08F4/65912 , C08F4/65927 , Y10S526/943
摘要： A very active catalyst system for olefin polymerization is composed of an aluminoxane and a metallocene of the formula I ##STR1## in which, preferably, M.sup.1 is Zr or Hf, R.sup.1 and R.sup.2 are alkyl or halogen, R.sup.3 and R.sup.4 are hydrogen, R.sup.5 and R.sup.6 are alkyl or haloalkyl, --(CR.sup.8 R.sup.9).sub.m --R.sup.7 --(CR.sup.8 R.sup.9).sub.n -- is a single-membered or multimembered chain in which R.sup.7 may furthermore be a (substituted) hetero atom, m+n is zero or 1 and R.sup.10 is hydrogen. The catalyst system gives polymers having high stereospecificity and a high melting point.
摘要翻译： 用于烯烃聚合的非常活泼的催化剂体系由铝氧烷和式I（I）的茂金属组成，其中优选地，M1是Zr或Hf，R1和R2是烷基或卤素，R3和R4是氢 ，R 5和R 6是烷基或卤代烷基， - （CR 8 R 9）m -R 7 - （CR 8 R 9）n - 是单元或多元链，其中R 7还可以是（取代的）杂原子，m + n是0或1 R 10为氢。 催化剂体系提供具有高立体定向性和高熔点的聚合物。
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