公开(公告)号：US10793511B2

公开(公告)日：2020-10-06

申请号：US16638393

申请日：2018-08-07

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Antoon Jacob Berend Ten Kate ,  Rens Veneman ,  Michiel Jozef Thomas Raaijmakers ,  Slavisa Jovic ,  Rolf Krister Edvinsson ,  Hendrik Van Dam ,  Eike Nicolas Kantzer ,  Ina Ehlers ,  Björn Patrik Skansen ,  Michael Bertil Einar Andersson-Sarning ,  Karl Fredrik Lake ,  Stig Mikael Wernersson

IPC分类号： C07C209/00 ,  C07C213/00 ,  C07C209/62 ,  C07C213/02

摘要： A process is provided for converting cyclic alkyleneureas into their corresponding alkyleneamines. The process includes reacting a feedstock comprising cyclic alkyleneureas in the liquid phase with water in an amount of from about 0.1 to about 20 mole water per mole urea moiety, at a temperature of at least 230° C., with removal of CO2. The process may allow the efficient conversion of alkyleneureas into the corresponding alkyleneamines. In certain embodiments, the process has a high yield and low side product production.

公开(公告)号：US11919866B2

公开(公告)日：2024-03-05

申请号：US16638347

申请日：2018-08-07

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Antoon Jacob Berend Ten Kate ,  Karl Fredrik Lake ,  Michiel Jozef Thomas Raaijmakers ,  Rolf Krister Edvinsson ,  Jenny Valborg Therese Adrian Meredith ,  Rens Veneman ,  Hendrik Van Dam ,  Eike Nicolas Kantzer ,  Ina Ehlers ,  Slavisa Jovic

IPC分类号： C07D233/34

CPC分类号： C07D233/34

摘要： A process for producing a cyclic alkylene urea product of Formula I:






in which a compound of Formula II and/or Formula III is contacted in a reaction zone with a compound of Formula IV and/or Formula V and in the presence of one or more carbonyl delivering compounds;










wherein the compound of Formula II and/or the compound of Formula III are added to a reaction zone comprising compound of Formula IV and/or compound of Formula (V) continuously or semi-continuously over a period of time, or in two or more batches.

公开(公告)号：US11878954B2

公开(公告)日：2024-01-23

申请号：US17310608

申请日：2020-02-13

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Antoon Jacob Berend Ten Kate ,  Rolf Krister Edvinsson ,  Michiel Jozef Thomas Raaijmakers ,  Rens Veneman ,  Slavisa Jovic ,  Lawien Zubeir ,  Eike Nicolas Kantzer ,  Ina Ehlers ,  Hendrik Van Dam ,  Karl Fredrik Lake

IPC分类号： C07C213/08 ,  C07C213/10 ,  C07C209/16 ,  C07C209/60 ,  C07C209/62 ,  C07C209/68 ,  C07C209/86 ,  C07C213/02

CPC分类号： C07C213/10 ,  C07C209/16 ,  C07C209/60 ,  C07C209/62 ,  C07C209/68 ,  C07C209/86 ,  C07C213/02 ,  C07C213/08

摘要： Process for manufacturing ethyleneamine compounds selected from the group of ethyleneamines and hydroxyethylethyleneamines wherein the process comprises two reaction sequences.

公开(公告)号：US11339116B2

公开(公告)日：2022-05-24

申请号：US16638377

申请日：2018-08-07

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Rens Veneman ,  Antoon Jacob Berend Ten Kate ,  Karl Fredrik Lake ,  Eike Nicolas Kantzer ,  Slavisa Jovic ,  Rolf Krister Edvinsson ,  Ina Ehlers ,  Hendrik Van Dam ,  Michiel Jozef Thomas Raaijmakers

IPC分类号： C07C209/68 ,  C07C209/86

摘要： A process to convert cyclic alkylene ureas into their corresponding alkylene amines is provided. An exemplary process includes reacting the cyclic alkylene ureas with an amine compound chosen from the group of primary amines or secondary amines that have a higher boiling point than the alkylene amines formed during the process, wherein the process is a reactive separation process and the reaction mixture contains less than about 10 wt % of water on the basis of total weight of the reaction mixture.

公开(公告)号：US11292768B2

公开(公告)日：2022-04-05

申请号：US16493664

申请日：2018-03-12

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Antoon Jacob Berend Ten Kate ,  Michiel Jozef Thomas Raaijmakers ,  Rens Veneman ,  Karl Fredrik Lake ,  Robert Kristoffer Berg ,  Eike Nicolas Kantzer ,  Rolf Krister Edvinsson ,  Hendrik Van Dam ,  Ina Ehlers

IPC分类号： C07D233/34 ,  C07C209/14 ,  C07C213/08

摘要： The present disclosure pertains to a process for preparing hydroxyethylethyleneamines, ethyleneamines, or mixtures thereof, and/or ethylene urea derivatives thereof. The process includes reacting diethanolamine with an amine-functional compound that includes at least two —NH— units of which at least one is selected from the group of primary amine groups and cyclic secondary amine groups. The amine-functional compound includes at least one —NH—CH2-CH2-NH— unit wherein one or more —NH—CH2-CH2-NH— units in the amine-functional compound may be present in the form of cyclic ethylene urea moieties, piperazine moieties, or linear ethylene urea moieties, in the presence of a carbon oxide delivering agent.

公开(公告)号：US11236039B2

公开(公告)日：2022-02-01

申请号：US16638389

申请日：2018-08-07

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Antoon Jacob Berend Ten Kate ,  Michiel Jozef Thomas Raaijmakers ,  Karl Fredrik Lake ,  Eike Nicolas Kantzer ,  Slavisa Jovic ,  Rolf Krister Edvinsson ,  Ina Ehlers ,  Hendrik Van Dam ,  Rens Veneman

IPC分类号： C07C209/62 ,  B01D3/00 ,  C07C209/86 ,  C07C213/00

摘要： The invention pertains to a process for converting a feedstock comprising cyclic alkyleneureas into their corresponding alkyleneamines, comprising —a CO2 removal step in which cyclic alkyleneureas are converted into their corresponding alkyleneamines by reacting cyclic alkyleneureas in the liquid phase with water with removal of CO2, —an amine removal step wherein cyclic alkyleneureas are converted in a reactive separation process into their corresponding alkyleneamines by reaction with an amine compound selected from the group of primary amines or secondary amines which have a higher boiling point than the alkyleneamines formed during the process. It has been found that the combination of a CO2 removal step and an amine removal step makes it possible to convert alkyleneureas into the corresponding amines in an efficient manner in a high reaction rate.

公开(公告)号：US11214549B2

公开(公告)日：2022-01-04

申请号：US16630283

申请日：2018-07-03

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Eike Nicolas Kantzer ,  Karl Fredrik Lake ,  Antoon Jacob Berend Ten Kate ,  Michiel Jozef Thomas Raaijmakers ,  Rens Veneman ,  Rolf Krister Edvinsson ,  Ina Ehlers ,  Michael Bertil Einar Sarning ,  Robert Kristoffer Berg ,  Hendrik Van Dam

IPC分类号： C07D233/34 ,  C07C209/78

摘要： Urea derivatives, methods for preparing ethylene amines, and methods of polymer manufacturing are provided. An exemplary method for preparing ethylene amines with n ethylene units and n+1 amine groups wherein n is at least 4, or urea derivatives of said ethylene amines, includes reacting an ethanolamine-functional compound, an amine-functional compound, and a carbon oxide delivering agent, wherein the ethanolamine-functional compound is of the formula HO—(C2H4-NH-)qH, q is at least 1, the amine-functional compound is of the formula H2N—(C2H4-NH-)rH, r is at least 1, the sum q+r is at least 4 and wherein optionally one or more of the ethanol-amine functional compound or amine-functional compound are at least partly used as their cyclic carbamate derivative, or linear or cyclic urea derivative.

公开(公告)号：US10975017B2

公开(公告)日：2021-04-13

申请号：US16468514

申请日：2017-12-12

申请人： NOURYON CHEMICALS INTERNATIONAL B.V.

发明人： Eike Nicolas Kantzer ,  Karl Fredrik Lake ,  Antoon Jacob Berend Ten Kate ,  Michiel Jozef Thomas Raaijmakers ,  Rens Veneman ,  Ina Ehlers ,  Michael Bertil Einar Sarning ,  Hendrik Van Dam ,  Rolf Krister Edvinsson ,  Jenny Valborg Therese Adrian Meredith

IPC分类号： C07C209/16 ,  C07C211/14 ,  C07D233/36 ,  C07C209/62

摘要： A process for preparing polyethyleneamines of formula NH2-(CH2-CH2-NH-)pH wherein p is at least 3 and wherein one or more —NH-CH2-CH2-NH— units may be piperazine units and/or ethylene urea derivatives of these compounds, includes reacting monoethylene glycol with an amine-functional compound having at least two —NH— units, of which at least one is selected from primary amine groups and cyclic secondary amine groups, in the presence of a carbon oxide-delivering agent. The amine-functional compound includes at least one —NH-CH2-CH2-NH— unit, and one or more —NH-CH2-CH2-NH— units may be in the form of cyclic ethylene urea moieties, piperazine moieties, or linear ethylene urea moieties. The molar ratio of amine-functional compound to monoethylene glycol is above 1.2:1 and the molar ratio of carbon oxide delivering agent to —NH-CH2-CH2-NH— units is at least 0.5:1. The process makes it possible to obtain ethylene amines and derivatives thereof without using ammonia or metal-containing catalysts.