公开(公告)号：US11767483B2

公开(公告)日：2023-09-26

申请号：US17274466

申请日：2019-08-28

Applicant: SHOWA DENKO K.K.

Inventor： Daisuke Yagyu ,  Naoya Fukumoto ,  Tsuyoshi Kato ,  Katsumi Murofushi

IPC: C10M107/38 ,  G11B5/725 ,  C08G65/22 ,  C08G65/331 ,  G11B5/72 ,  C10N40/18 ,  C10N50/08

CPC classification number: C10M107/38 ,  C08G65/226 ,  C08G65/331 ,  G11B5/7257 ,  G11B5/7266 ,  C10M2213/043 ,  C10N2040/18 ,  C10N2050/08

Abstract: The fluorine-containing ether compound is represented by the following formula (1): R1—R2—CH2—R3—CH2—R4. In the formula (1), R1 is represented by the following formula (2), R2 is represented by the following formula (3), R3 is a perfluoropolyether chain, and R4 is an organic end group different from R1—R2— and contains two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to one another via a linking group containing a carbon atom to which the polar group is not bonded. In the formula (2), R5 is an alkoxy group selected from the group consisting of a methoxy, an ethoxy and a propoxy group. In the formula (3), w is 2 or 3.

公开(公告)号：US11514945B2

公开(公告)日：2022-11-29

申请号：US16489919

申请日：2018-02-20

Applicant: SHOWA DENKO K.K.

Inventor： Hiroyuki Tomita ,  Hiroko Hattori ,  Naoya Fukumoto ,  Ryuuta Miyasaka ,  Naoko Ito ,  Ichiro Ota ,  Katsumi Murofushi

IPC: G11B5/84 ,  G11B5/72 ,  C08G65/332 ,  C08G65/333 ,  C10M107/38 ,  G11B5/725

Abstract: A lubricant for a magnetic recording medium capable of forming a lubricant layer having excellent adhesion to a protective layer is provided. A lubricant for a magnetic recording medium contains a fluorine-containing ether compound in which a group having an ethylenic carbon-carbon double bond is disposed at one or both terminals of a perfluoroalkyl polyether chain. It is preferable that the group having the ethylenic carbon-carbon double bond is disposed at one terminal of the perfluoroalkyl polyether chain, and a hydroxyl group is disposed at other terminal. It is preferable that the lubricant for a magnetic recording medium contains a compound in which one or more functional groups selected from a hydroxyl group, an amino group, an amido group and a carboxyl group is disposed at one or both terminals of a perfluoroalkyl polyether chain.

公开(公告)号：US11225624B2

公开(公告)日：2022-01-18

申请号：US16643989

申请日：2018-08-07

Applicant: SHOWA DENKO K.K.

Inventor： Tsuyoshi Kato ,  Daisuke Yagyu ,  Naoya Fukumoto ,  Yuta Yamaguchi

IPC: C10M105/54 ,  G11B5/725 ,  C10M107/38 ,  G11B5/82 ,  C10N40/18 ,  C10N50/00 ,  C10N20/04 ,  C10N50/02 ,  C10N30/06

Abstract: A fluorine-containing ether compound represented by Formula (1) is provided, R1—R2—CH2—R3—CH2—R4  (1) (In Formula (1), R1 is an alkyl group that may have a substituent, R2 is a divalent linking group bonded to R1 via an ethereal oxygen, R3 is a perfluoropolyether chain, and R4 is an end group which is different from R1-R2 and includes two or three polar groups, in which each of the polar groups is bonded to a different carbon atom, and the carbon atoms bonded to the polar groups are bonded to each other via a linking group containing a carbon atom not bonded to the polar groups.).

公开(公告)号：US11011200B2

公开(公告)日：2021-05-18

申请号：US15640729

申请日：2017-07-03

Applicant: SHOWA DENKO K.K.

Inventor： Shoko Uetake ,  Naoya Fukumoto ,  Daisuke Yagyu ,  Yuta Yamaguchi ,  Naoko Ito ,  Hiroyuki Tomita ,  Ryuta Miyasaka ,  Katsumi Murofushi

IPC: G11B5/725 ,  C10M107/38 ,  C07C43/13 ,  C07C43/23 ,  C10M105/54 ,  C10N30/06 ,  C10N40/18 ,  C10N50/00 ,  C07D303/28

Abstract: This fluorine-containing ether compound is represented by Formula (1). R1—R2—CH2—R3—CH2—R4—R5  (1) (in Formula (1), R1 is an aryl group or an aralkyl group, R2 is a divalent linking group having 0 or 1 polar group, R3 is a perfluoropolyether chain, R4 is a divalent linking group having 2 or 3 polar groups, and R5 is an aryl group or an aralkyl group.)

公开(公告)号：US11639330B2

公开(公告)日：2023-05-02

申请号：US16640132

申请日：2018-07-30

Applicant: SHOWA DENKO K.K.

Inventor： Masaki Nanko ,  Naoya Fukumoto ,  Daisuke Yagyu ,  Yuta Yamaguchi ,  Tsuyoshi Kato ,  Hiroyuki Tomita ,  Katsumi Murofushi ,  Shohei Nishizawa

IPC: C07C255/13 ,  G11B5/725 ,  C07C43/205 ,  C07C255/17 ,  C07C255/19 ,  C07C255/50 ,  C07D333/16 ,  C08G65/08 ,  C10M107/38 ,  C10N40/18

Abstract: Provided is a fluorine-containing ether compound that can be suitably used as a material for a lubricant for a magnetic recording medium, capable of forming a lubricant layer having excellent chemical substance resistance and wear resistance even when the thickness is small. A fluorine-containing ether compound represented by the following formula (1): R1—R2—CH2—R3—CH2—R4—R5  (1) In the formula (1), R3 is a perfluoropolyether chain. R2 and R4 are divalent linkage groups having a polar group, and may be the same or different. R1 and R5 are terminal groups bonded to R2 or R4, which may be the same or different, and at least one of R1 and R5 is an organic group having 1 to 8 carbon atoms wherein one or more hydrogen atoms of the organic group is substituted with a cyano group.

公开(公告)号：US11292979B2

公开(公告)日：2022-04-05

申请号：US15999837

申请日：2017-02-20

Applicant: SHOWA DENKO K.K.

Inventor： Yuta Yamaguchi ,  Naoya Fukumoto ,  Naoko Ito ,  Hiroyuki Tomita ,  Ichiro Ota ,  Katsumi Murofushi

IPC: C10M105/54 ,  C07C43/13 ,  G11B5/725 ,  C10N40/18

Abstract: A fluorine-containing ether compound represented by a formula (1) shown below. R4—CH2—R3—CH2—R2—CH2—R1—CH2—R2—CH2—R3—CH2—R5  (1) In formula (1), R1 and R3 represent the same or different perfluoropolyether chains, R2 represents a linking group containing at least one polar group, one or both of R4 and R5 represent a terminal group containing two or more polar groups, and R4 and R5 are different.

公开(公告)号：US11261394B2

公开(公告)日：2022-03-01

申请号：US16644586

申请日：2018-08-23

Applicant: SHOWA DENKO K.K.

Inventor： Tsuyoshi Kato ,  Daisuke Yagyu ,  Naoya Fukumoto ,  Masaki Nanko ,  Masumi Kuritani ,  Katsumi Murofushi

IPC: C10M105/54 ,  G11B5/73 ,  C07C43/23 ,  C07D333/16 ,  C10N40/18

Abstract: A fluorine-containing ether compound represented by R1—R2—CH2—R3—CH2—R4—R5 is provided. (R3 is a perfluoropolyether chain; R1 and R5 are each independently any one of an alkyl group that may have a substituent, an organic group having at least one double bond or at least one triple bond, and a hydrogen atom; and —R2—CH2—R3 is represented by Formula (2), and R3—CH2—R4— is represented by Formula (3)) -[A]-[B]—O—CH2—R3  (2) R3—CH2—O—[C]-[D]-  (3) ([A] is represented by Formula (4), [B] is represented by Formula (5), [C] is represented by Formula (6), [D] is represented by Formula (7), and in the formula, a and b are integers of 0 to 2, c is an integer of 2 to 5, d and f are integers of 0 to 2, and e is an integer of 2 to 5, and at least one of b and d in the formula is 1 or more)